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Influence of fly ash and sewage sludge application on wheat biomass production,nutrients availability,and soil properties 被引量:8
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作者 Christos Tsadilas Vasilios Samaras +1 位作者 E.Evangelou Sabry M.Shaheen 《International Journal of Coal Science & Technology》 EI CAS 2014年第2期221-226,共6页
The influence of fly ash(FA)applied alone and/or with sewage sludge(SS)on wheat(Triticum vulgare)grain yield,biomass production and soil properties was studied in a field experiment.The results showed that both FA and... The influence of fly ash(FA)applied alone and/or with sewage sludge(SS)on wheat(Triticum vulgare)grain yield,biomass production and soil properties was studied in a field experiment.The results showed that both FA and SS significantly increased grain yield and plant biomass.FA applied alone increased significantly soil pH and EC while FA applied together with SS did not significantly affect them compared to mono FA treatment.Soil pH and EC values increased with time in FA and FA-SS treatments.SS increased soil organic matter and total N content and SS applied together with FA increased also available soil B.From the plant nutrients tested only tissue N concentration was increased significantly in all treatments compared to control.Copper,Zn,Mn,Ni,and Pb at both available and total concentrations are significantly affected. 展开更多
关键词 Fly ash Sewage sludge By-product of coal combustion Wheat biomass product Soil property
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Chemical composition and properties of ashes from combustion plants using Miscanthus as fuel
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作者 Christof Lanzerstorfer 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2017年第4期178-183,共6页
Miscanthus giganteus is one of the energy crops considered to show potential for a substantial contribution to sustainable energy production. In the literature there is little data available about the chemical composi... Miscanthus giganteus is one of the energy crops considered to show potential for a substantial contribution to sustainable energy production. In the literature there is little data available about the chemical composition of ashes from the combustion of Miscanthus and practically no data about their physical properties. However, for handling, treatment and utilization of the ashes this information is important. In this study ashes from two biomass combustion plants using Miscanthus as fuel were investigated. The density of the ashes was 2230 ± 35 kg/m;, which was similar to the density of ashes from straw combustion. Also the bulk densities were close to those reported for straw ashes. The flowability of the ashes was a little worse than the flowability of ashes from wood combustion. The measured heavy metal concentrations were below the usual limits for utilization of the ashes as soil conditioner. The concentrations in the bottom ash were similar to those reported for ash from forest residue combustion plants. In comparison with cyclone fly ashes from forest residue combustion the measured heavy metal concentrations in the cyclone fly ash were considerably lower. Cl-, S and Zn were enriched in the cyclone fly ash which is also known for ashes from wood combustion. In comparison with literature data obtained from Miscanthus plant material the concentrations of K, Cl-and S were lower.This can be attributed to the fact that the finest fly ash is not collected by the cyclone de-dusting system of the Miscanthus combustion plants. 展开更多
关键词 biomass combustion miscanthus ash composition ash properties
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Chemical composition and physical properties of filter fly ashes from eight grate-fired biomass combustion plants 被引量:4
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作者 Christof Lanzerstorfer 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2015年第4期191-197,共7页
For the handling, treatment and utilization of fly ash from biomass combustion its chemical composition and physical properties are important. In this study eight filter fly ashes from different grate-fired biomass co... For the handling, treatment and utilization of fly ash from biomass combustion its chemical composition and physical properties are important. In this study eight filter fly ashes from different grate-fired biomass combustion plants were investigated. In fly ash from straw combustion high concentrations of(K) were found, whereas in the fly ash from wood combustion the concentrations of Ca and Mg were higher. The average concentration of PO3-4was similar in both types of fly ashes. In all wood fly ashes some measured heavy metal concentrations were above the limits for utilization. The straw fly ashes were much less contaminated and can be utilized. For wood fly ash most parameters showed little variation, except from one fly ash where the dust pre-separator is in poor condition. The average values were: mass median diameter 4.3 ± 0.8 μm, spread of particle size distribution19 ± 11, particle density 2620 ± 80 kg/m^3 and angle of repose 50°± 1°. The density of the straw fly ashes is lower(2260 ± 80 kg/m^3) and the spread of the size distribution is higher(72 ± 24).For one straw combustion fly ash the values of the mass median diameter and the angle of repose were similar to the values of wood combustion fly ash, for the other straw fly ash the values differed considerably. While the particle size of this fly ash was much smaller,surprisingly the angle of repose was also lower. This can be attributed to the formation of small agglomerates in this fly ash, which were not disintegrated without a certain stress. 展开更多
关键词 biomass combustion Filter fly ash Chemical analysis Physical properties
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Characteristics of biomass ashes from different materials and their ameliorative effects on acid soils 被引量:5
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作者 Renyong Shi Jiuyu Li +4 位作者 Jun Jiang Khalid Mehmood Yuan Liu Renkou Xu Wei Qian 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2017年第5期294-302,共9页
The chemical characteristics,element contents,mineral compositions,and the ameliorative effects on acid soils of five biomass ashes from different materials were analyzed. The chemical properties of the ashes varied d... The chemical characteristics,element contents,mineral compositions,and the ameliorative effects on acid soils of five biomass ashes from different materials were analyzed. The chemical properties of the ashes varied depending on the source biomass material. An increase in the concrete shuttering contents in the biomass materials led to higher alkalinity,and higher Ca and Mg levels in biomass ashes,which made them particularly good at ameliorating effects on soil acidity. However,heavy metal contents,such as Cr,Cu,and Zn in the ashes,were relatively high. The incorporation of all ashes increased soil p H,exchangeable base cations,and available phosphorus,but decreased soil exchangeable acidity. The application of the ashes from biomass materials with a high concrete shuttering content increased the soil available heavy metal contents. Therefore,the biomass ashes from wood and crop residues with low concrete contents were the better acid soil amendments. 展开更多
关键词 biomass ashes Raw materials Element composition Chemical properties Amelioration of acidic soils Available heavy metals
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混合生物质颗粒燃料的燃烧特性 被引量:12
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作者 矫振伟 赵武子 +1 位作者 王瀚平 苏俊林 《可再生能源》 CAS 北大核心 2012年第6期77-81,共5页
从生物质燃料的灰熔融性和热值两个关键性的特性指标着手,以玉米秸秆和水稻稻壳作为主要原料,用试验优化设计和分析的方法 ,寻求混合生物质颗粒燃料的优化配方,提高混合生物质颗粒的软化温度ST>1 400℃,有效地解决了玉米秸秆颗粒结... 从生物质燃料的灰熔融性和热值两个关键性的特性指标着手,以玉米秸秆和水稻稻壳作为主要原料,用试验优化设计和分析的方法 ,寻求混合生物质颗粒燃料的优化配方,提高混合生物质颗粒的软化温度ST>1 400℃,有效地解决了玉米秸秆颗粒结渣问题。对混合生物质颗粒进行了热重试验研究和燃烧机理、动力学特性分析,结果表明:混合生物质颗粒具有易着火和单峰值热解特性,燃烧性能良好。此研究为改善单一成分生物质燃料的燃烧性能,推广利用生物质能提供指导性建议。 展开更多
关键词 可再生能源 混合生物质颗粒 燃烧特性 灰熔融性
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秸秆类生物质燃烧特性的研究 被引量:42
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作者 乐园 李龙生 《能源工程》 2006年第4期30-33,共4页
利用热重分析仪对江苏宿迁地区的玉米秆、稻秆和麦秆三种生物质的燃烧特性进行了分析,测定了生物质的灰熔点和灰组成,用XRD和TEM表征了生物质灰的物相结构和形貌。研究结果表明,三种生物质的燃烧规律基本一致,燃烧过程可分为四个阶段:... 利用热重分析仪对江苏宿迁地区的玉米秆、稻秆和麦秆三种生物质的燃烧特性进行了分析,测定了生物质的灰熔点和灰组成,用XRD和TEM表征了生物质灰的物相结构和形貌。研究结果表明,三种生物质的燃烧规律基本一致,燃烧过程可分为四个阶段:干燥过程,热解过程,晶型转变过程和熔融过程;三种生物质中,玉米秆灰熔点最高,灰量最少且碱金属含量最低;生物质灰为形态各异的纳米颗粒。 展开更多
关键词 生物质 燃烧特性 生物质灰 灰分性质
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生物质循环流化床飞灰烧失特性研究 被引量:1
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作者 苏新凯 黄兴强 +1 位作者 岳松 余春江 《太阳能学报》 EI CAS CSCD 北大核心 2022年第11期325-330,共6页
选取2家典型生物质电厂除尘器处的飞灰,通过热重-傅里叶红外光谱联用(TG-FTIR)、X射线荧光光谱(XRF)、能谱(EDS)和X射线衍射(XRD)等分析手段,对飞灰的成分及其在高温下的失重特性进行研究。研究发现,生物质飞灰的高温失重机理较为复杂,... 选取2家典型生物质电厂除尘器处的飞灰,通过热重-傅里叶红外光谱联用(TG-FTIR)、X射线荧光光谱(XRF)、能谱(EDS)和X射线衍射(XRD)等分析手段,对飞灰的成分及其在高温下的失重特性进行研究。研究发现,生物质飞灰的高温失重机理较为复杂,在空气中加热时,碱金属氯盐的蒸发从380℃开始缓慢进行,600℃以下主要进行未燃碳的燃尽与碳酸镁的分解;600~750℃主要进行碳酸钙的分解;750℃后蒸发速度迅速上升,直至950℃完全蒸发;950℃以上发生矿物质的玻璃化反应和碱金属硫酸盐的蒸发。鉴于目前电力行业和ATSM对生物质飞灰含碳量的测试结果均不准确,该根据生物质飞灰的烧失机理,提出更加精确的氮气和空气气氛下600℃烧失量之差含碳量测试方法。 展开更多
关键词 生物质能 直接燃烧发电 飞灰 成分 烧失
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烘焙生物质-煤混烧条件下灰的腐蚀行为
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作者 韩京昆 王津汉 +4 位作者 于敦喜 王绍壮 喻鑫 吴建群 徐明厚 《洁净煤技术》 CAS 北大核心 2022年第3期41-48,共8页
生物质经烘焙后物化特性显著改善,可大规模替代煤炭进行燃烧发电,降低CO_(2)排放。然而,燃烧过程中灰沉积、腐蚀等问题亟需解决,烘焙过程对生物质燃烧中腐蚀行为的影响尚缺乏系统的研究。鉴于此,选取玉米秆、麦草2种典型生物质,在固定... 生物质经烘焙后物化特性显著改善,可大规模替代煤炭进行燃烧发电,降低CO_(2)排放。然而,燃烧过程中灰沉积、腐蚀等问题亟需解决,烘焙过程对生物质燃烧中腐蚀行为的影响尚缺乏系统的研究。鉴于此,选取玉米秆、麦草2种典型生物质,在固定床反应器上制备其烘焙样,通过逐级提取结合ICP-MS、IC测试,探究烘焙对生物质中关键成灰元素的赋存形态及含量的影响。在沉降炉系统进行烘焙前后生物质、2种动力用煤单烧以及各生物质样品与煤混烧试验,并收集其总灰。选取12CrMoVG钢为腐蚀试验金属材料,使用基于水平管式炉的腐蚀试验系统,探究了550℃时,HCl存在的模拟烟气气氛下,单烧灰负载的腐蚀情况,以及HCl、SO_(2)共同存在的模拟烟气气氛下混烧灰负载的腐蚀情况,称重获得各工况下腐蚀增重,并通过SEM-EDS分析了腐蚀后样品形貌及成分特征。最后,通过不同HCl浓度下的腐蚀试验,揭示了烘焙对生物质-煤混烧的腐蚀倾向影响。结果表明,玉米秆和麦草中Cl和K含量较高。经过270℃烘焙,玉米秆和麦草中Cl分别释放了17.84%和38.76%;S分别释放了7.78%、20.98%;Na、Mg、K、Ca、Fe总量基本不变,少量水溶态K转化为离子交换态,部分水溶态的Mg、Ca向盐酸溶态转化。相同气氛条件下,由于烘焙生物质灰中AAEM(碱及碱土金属)含量略升高,其腐蚀增重相较于原生物质呈增加趋势。混烧工况的腐蚀增重显著低于单烧工况,主要是由于气氛中SO_(2)的存在导致了硫酸盐化反应,减轻了腐蚀程度。烘焙对生物质单烧和混烧的灰成分影响较小,因此对腐蚀程度的影响有限;但腐蚀气氛中Cl的增加能显著促进腐蚀行为,由于烘焙能够脱除生物质中部分Cl,因此烘焙有减轻生物质燃烧腐蚀倾向的潜质。 展开更多
关键词 烘焙生物质 煤混烧 腐蚀行为 灰沉积 灰成分
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生物质复合燃料焚烧灰制备陶粒及其对Pb(Ⅱ)的吸附特性研究
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作者 王力 薛永杰 《武汉理工大学学报》 CAS 北大核心 2019年第4期79-84,共6页
以生物质复合燃料焚烧灰为原料制备陶粒并应用于处置含铅废水。结果表明,混烧灰、原污泥与高岭土掺配比例为70%∶20%∶10%时,1050℃烧制的陶粒性能较好。陶粒内部结构主要由气孔和孔间壁组成。陶粒对100mg/L的Pb(Ⅱ)的吸附平衡时间约为1... 以生物质复合燃料焚烧灰为原料制备陶粒并应用于处置含铅废水。结果表明,混烧灰、原污泥与高岭土掺配比例为70%∶20%∶10%时,1050℃烧制的陶粒性能较好。陶粒内部结构主要由气孔和孔间壁组成。陶粒对100mg/L的Pb(Ⅱ)的吸附平衡时间约为13h,吸附去除率超过99.9%。随着吸附质初始浓度的增大,陶粒吸附剂对Pb(Ⅱ)的吸附能力增幅逐渐平缓。吸附剂的量大于5g/L时,Pb(Ⅱ)的吸附去除率趋于平衡,且当吸附剂粒径小于2.36mm或者溶液pH值大于6时,陶粒吸附剂对100mg/L的Pb(Ⅱ)的吸附去除率普遍可以达到99%。等温吸附研究表明陶粒对Pb(Ⅱ)的吸附更符合Langmuir模型;准一级模型适合用于描述其吸附动力学行为。升高温度有利于增加陶粒对pb(Ⅱ)的吸附能力,并且有利于吸附过程的自发进行。 展开更多
关键词 生物质复合燃料 焚烧灰 陶粒 吸附热力学 动力学
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