Reconstruction of liquid free slosh modes by curved quiet free surface was investigated in the case of small Bond number by means of modal part analysis method in this paper. It is shown that the curved liquid quiet f...Reconstruction of liquid free slosh modes by curved quiet free surface was investigated in the case of small Bond number by means of modal part analysis method in this paper. It is shown that the curved liquid quiet free surface would couple the modes to form new eigen-modes while the orthogonality of the modes which participate the liquid slosh are given only by their Bessel modal parts and it would change their eigen-frequencies respectively while the orthogonality are given by their triangle function modal parts. By studying the laterally forced slosh of the liquid in a cylindrical container based on the new eigen-modes, a characteristic of modes-choosing was found.展开更多
The systematic method for constructing Lewis representations is a method for representing chemical bonds between atoms in a molecule. It uses symbols to represent the valence electrons of the atoms involved in the bon...The systematic method for constructing Lewis representations is a method for representing chemical bonds between atoms in a molecule. It uses symbols to represent the valence electrons of the atoms involved in the bond. Using a number of rules in a defined order, it is often better suited to complicated cases than the Lewis representation of atoms. This method allows us to determine the formal charge and oxidation number of each atom in the edifice more efficiently than other methods.展开更多
By using the Lagrange's intermediate value theorem,it is derived mathematically that the structur-al distortion of a coordination polyhedron may lead to an increase in bond-valence sum of the cen-tral atom of ion ...By using the Lagrange's intermediate value theorem,it is derived mathematically that the structur-al distortion of a coordination polyhedron may lead to an increase in bond-valence sum of the cen-tral atom of ion .The applicabilities of the bond-valence model are discussed in the following two cases:the modeling of crystal structure ,and the indication of distortion degree of a coordination polyhedron.Also it is shown that a distorted polyhedron should be in favor of a longer average bond length or a smaller coordination number.展开更多
A systematic series of experiments are designed and performed including inteffacial tension （IFT） measurements concomitant with Bond （BN, the ratio of gravity forces to capillary forces） and swelling/extraction me...A systematic series of experiments are designed and performed including inteffacial tension （IFT） measurements concomitant with Bond （BN, the ratio of gravity forces to capillary forces） and swelling/extraction measurements. Dynamic IFT, BN and swelling/extraction are measured as a function of pressure at temperatures of 30, 50 and 80 ℃. In addition, in the light of measured IFT the minimum miscibility pressure （MMP） of CO2 and light crude oil is determined based on a method called vanishing inteffacial tension （VIT）. The obtained results interestingly revealed that equilibrium IFT decreases linearly with pressure in two distinct pressure intervals while equilibrium BN shows an increasing trend as a function of pressure for all of the studied cases while no obvious trend is observed for swell- ing of crude oil and extraction of light-components regarding time, temperature and pressure.展开更多
文摘Reconstruction of liquid free slosh modes by curved quiet free surface was investigated in the case of small Bond number by means of modal part analysis method in this paper. It is shown that the curved liquid quiet free surface would couple the modes to form new eigen-modes while the orthogonality of the modes which participate the liquid slosh are given only by their Bessel modal parts and it would change their eigen-frequencies respectively while the orthogonality are given by their triangle function modal parts. By studying the laterally forced slosh of the liquid in a cylindrical container based on the new eigen-modes, a characteristic of modes-choosing was found.
文摘The systematic method for constructing Lewis representations is a method for representing chemical bonds between atoms in a molecule. It uses symbols to represent the valence electrons of the atoms involved in the bond. Using a number of rules in a defined order, it is often better suited to complicated cases than the Lewis representation of atoms. This method allows us to determine the formal charge and oxidation number of each atom in the edifice more efficiently than other methods.
文摘By using the Lagrange's intermediate value theorem,it is derived mathematically that the structur-al distortion of a coordination polyhedron may lead to an increase in bond-valence sum of the cen-tral atom of ion .The applicabilities of the bond-valence model are discussed in the following two cases:the modeling of crystal structure ,and the indication of distortion degree of a coordination polyhedron.Also it is shown that a distorted polyhedron should be in favor of a longer average bond length or a smaller coordination number.
文摘A systematic series of experiments are designed and performed including inteffacial tension （IFT） measurements concomitant with Bond （BN, the ratio of gravity forces to capillary forces） and swelling/extraction measurements. Dynamic IFT, BN and swelling/extraction are measured as a function of pressure at temperatures of 30, 50 and 80 ℃. In addition, in the light of measured IFT the minimum miscibility pressure （MMP） of CO2 and light crude oil is determined based on a method called vanishing inteffacial tension （VIT）. The obtained results interestingly revealed that equilibrium IFT decreases linearly with pressure in two distinct pressure intervals while equilibrium BN shows an increasing trend as a function of pressure for all of the studied cases while no obvious trend is observed for swell- ing of crude oil and extraction of light-components regarding time, temperature and pressure.
