Fabrication of branch-like Aph@LDH-MgO material through organic-inorganic hybrid conjugation for excellent anti-corrosion performance

Layered double hydroxides(LDH)frameworks have shown significant enhancement in stability and reusability,and their tailorable architecture brings new insight into the development of the next generation of hybrid materials,which attracted considerable attention in many fields over the years.One of the factors contributing to the widespread applicability of layered double hydroxides is their adaptable composition,which can accommodate a wide spectrum of potential anionic guests.This exceptional property makes the LDH system simple to adjust for various applications.However,most LDH systems are synthesized in situ in an autoclave at high temperatures and pressures that severely restrict the industrial use of such coating systems.In this study,LDH was directly synthesized on a magnesium alloy that had undergone plasma electrolytic oxidation(PEO)treatment in the presence of ethylenediaminetetraacetic acid,thereby avoiding the use of hydrothermal autoclave conditions.This LDH system was compared with a hybrid architecture consisting of organic-inorganic self-assembly.An organic layer was fabricated on top of the LDH film using 4-Aminophenol(Aph)compound,resulting in a smart hierarchical structure that can provide a robust Aph@LDH film with excellent anti-corrosion performance.At the molecular level,the conjugation characteristics and adsorption mechanism of Aph molecule were studied using two levels of theory as follows.First,Localized orbit locator(LOL)-πisosurface,electrostatic potential(ESP)distribution,and average local ionization energy(ALIE)on the molecular surface were used to highlight localization region,reveal the favorable electrophilic and nucleophilic attacks,and clearly explore the type of interactions that occurred around interesting regions.Second,first-principles based on density functional theory(DFT)was applied to study the hybrid mechanism of Aph on LDH system and elucidate their mutual interactions.The experimental and computational analyses suggest that the highπ-electron density and delocalization characteristics of the functional groups and benzene ring in the Aph molecule played a leading role in the synergistic effects arising from the combination of organic and inorganic coatings.This work provides a promising approach to design advanced hybrid materials with exceptional electrochemical performance.

Synthesis and characterization of hybrid organic-inorganic materials based on EA-MAn-APTES and silica

Poly (EA-MAn-APTES)/silica hybrid materials were successfully prepared fromEthyl acrylate (EA), maleic anhydride (MAn) and tetraethoxysilane (TEOS) in the presence of acoupling agent 3-aminopropyltriethoxysilane (APTES),by free-radical solution polymerization and insitu sol-gel process. The mass fraction of TEOS varied from 0 to 25%. The hybrid materials werecharacterized by the methods of FT-IR spectra, solvent extraction, scanning electron microscope (SEM), transmission electron microscope (TEM), differential scanning calorimetry (DSC) andthermogravimetric analysis (TGA) measuring apparatus to get their structures, gel contents,morphologies, particle sizes and thermal performances. The results show that the covalent bonds arebetween organic and inorganic phases, gel contents in the hybrid materials are much higher, theSiO_2 phase is well dispersed in the polymer matrix, silicon dioxide exist at nanoscale in thecomposites and have excellent thermal stability.

A Three-dimensional Organic-inorganic Hybrid Material Supported by Decavanadate Clusters and Na-O Chains: Synthesis and Crystal Structure of [Na_6(H_2O)_(16)(dod)_4V_(10)O_(28)]

A new organic-inorganic hybrid material [Na6(H2O)16(dod)2V10O28] (dod = 1,4- diazoniabicyclo[2,2,2]octane-1,4-diacetate) has been synthesized and X-ray single-crystal structural analysis reveals it crystallizes in triclinic, space group P with a = 11.533(7), b = 12.031(7), c = 12.187(4) ? a = 72.47(1), b = 73.16(1), g = 68.21(1)o, C20H64N4Na6O52V10, V = 1467(1) ?, Z = 1, Mr = 1840.1, Dc = 2.083 g/cm3, MoKa, l = 0.71073 ? m = 1.686, F(000) = 924, S = 1.027, the final R = 0.0538 and wR = 0.1272 for 4398 observed reflections. The compound has a three-dimensional frame- work constructed from decavanadate clusters, NaO chains and dod ligands. A variety of OH…O and CH…O hydrogen bonds play an important role in stabilizing the framework.

Thermal Studies and Analytical Applications of a Newly Synthesized Composite Material “Polyaniline Stannic Molybdate”

Polyaniline stannic molybdate—an organic-inorganic composite material, was prepared via sol-gel mixing of organic polymer polyaniline into matrices of inorganic precipitate of stannicmolybdate. The composite material synthesized at pH 1.2 showed an ion exchange capacity 1.8 meq/g for Na+?ions. Ion exchange capacity, pH titration and distribution studies were carried out to determine the preliminary ion exchange properties of the material. The distribution studies showed the selectivity of Hg(II) ions by this material. The effect of temperature on the ion exchange capacity of the material at different temperatures had been studied. The sorption behavior of metal ions was also explored in different surfactant media.

Enhancement of superconductivity in organic-inorganic hybrid topological materials

Inducing or enhancing superconductivity in topological materials is an important route toward topological superconductivity.Reducing the thickness of transition metal dichalcogenides(e.g.WTe2 and MoTe2)has provided an important pathway to engineer superconductivity in topological matters.However,such monolayer sample is difficult to obtain,unstable in air,and with extremely low Tc.Here we report an experimentally convenient approach to control the interlayer coupling to achieve tailored topological properties,enhanced superconductivity and good sample stability through organic-cation intercalation of the Weyl semimetals MoTe2 and WTe2.The as-formed organic-inorganic hybrid crystals are weak topological insulators with enhanced Tc of 7.0 K for intercalated MoTe2(0.25 K for pristine crystal)and2.3 K for intercalated WTe2(2.8 times compared to monolayer WTe2).Such organic-cation intercalation method can be readily applied to many other layered crystals,providing a new pathway for manipulating their electronic,topological and superconducting properties.

Organic-inorganic Hybrid Materials Based on Molybdophosphate and Organic Polyammonium

A new organic-inorganic hybrid compound （dienHs）2（P2Mo5O23） （1） [dien=NH（CH2CH2NH2）2] has been hydrothermally synthesized and characterized by elemental analyses, IR spectrum, thermogravimetric analysis, and the single crystal X-ray diffraction technique. Compound 1 crystallizes in the triclinic system with space group P1 and a=0.9790（2） nm, b=0.9922（2） nm, c= 1.4644（3） nm, α=95.510（10）°, β=98.860（10）°, γ=95.700（10）°, V=1.3895（5） nm^3, Z=2, R=0.0465. The results show that the compound consists of dienH3^3＋＋ and P2Mo5O23^6-, and the heteropoly anion P2Mo5O23^6- is connected to a 1-D chain structure with the protonated dien by hydrogen bonds.

Functional-template directed self-assembly(FTDSA) of mesostructured organic-inorganic hybrid materials

Since the discovery of a surfactant directed self-assembly approach for the fabrication of mesoporous silica in 1992,increasing attention has been focused on the design and synthesis of mesostructured functional materials.Organic functionalization is becoming a major topic in this research field,since highly ordered mesostructured organic-inorganic hybrids offer novel functionalities and enhanced performance over their individual components.We begin with a brief overview of the three fundamental methods(post-synthetic grafting technique,co-condensation method,and preparation of periodic mesoporous organosilicas) for the preparation of organically functionalized mesostructured silica,and focus on one of the most promising approaches,which herein was named as functional-template directed self-assembly(FTDSA) approach,and in the eyes of the authors it has a special position in the preparation of this class of hybrid materials.A comprehensive overview of the state of research in the area of FTDSA and its potential applications will be given.

Enhanced photocatalytic hydrogen production under visible light of an organic-inorganic hybrid material based on enzo[1,2-b:4,5-b']dithiophene polymer and TiO_(2)

Titanium dioxide(TiO_(2))has been limited in photocatalysis due to its wide band gap(3.2 eV)and limited absorption in the ultraviolet range.Therefore,organic components have been introduced to hybrid with TiO_(2) for enhanced photocatalytic efficiency under visible light.Here,we report that benzo[1,2-b:4,5-b']dithiophene polymer was an ideal organic material for the preparation of a hybrid material with TiO_(2).The energy band gap of the resulting hybrid material decreased to 2.9 eV and the photocatalytic hydrogen production performance reached 745.0μmol g^(-1) h^(-1) under visible light irradiation.Meanwhile,the material still maintained the stability of hydrogen production performance after 40 h of photocatalytic cycles.The analysis of the transient current response and electrochemical impedance revealed that the main reasons for the enhanced water splitting of the hybrid materials were the faster separation of electron hole pairs and the lower recombination of photocarrier ions.Our findings suggest that polythiophene is a promising organic material for exploring hybrid materials with enhanced photocatalytic hydrogen production.

Fabrication of 2×2 Thermo-Optic Switches with Organic-Inorganic Hybrid Materials Prepared by Sol-Gel Technique

2×2 Mach-Zehnder interferometric thermo-optic switch was fabricated with organic/inorganic hybrid materials by sol-gel technique and direct UV patterning. The switching time of device was measured to be 4.2 ms and switching power 9.3 mW.

结构参数对CFRP三螺栓胶螺混合接头连接性能的影响研究

通过实验和数值模拟研究了不同结构参数对三螺栓的碳纤维增强复合材料(CFRP)胶螺混合接头连接性能的影响机制。建立了基于三维Hashin失效准则的有限元模型,并借助超景深设备Keyence VHX-6000对接头的失效区域进行观测,探究了搭接长度、螺栓孔间距和间隙配合关系对接头连接性能的影响。结果表明:增加搭接长度能够使接头的受力分布由接头边缘向中间转移,使接头性能提升了29.9%;减小螺栓孔间距能够提高接头两端胶接区域的连接性能,使接头性能提升了15%;由于三螺栓受力不均,因此两端螺栓孔为间隙配合时,能够增加中间螺栓的受力,使接头性能提升了6.9%。接头的连接性能随着搭接长度的增加而增加,但是增速逐渐减小至零;随着螺栓孔间距的增加,接头的连接强度先缓慢增大后快速减小,最佳螺栓孔间距为15 mm;两端的螺栓为间隙配合时能够增加接头的连接性能,最佳螺栓孔直径为5.2 mm。

An Organic–Inorganic Hybrid Material Based on Benzo[ghi]perylenetri-imide and Cyclic Titanium-Oxo Cluster for Efficient Perovskite and Organic Solar Cells

Perovskite and organic solar cells usually require electron-transport interlayers to efficiently transport electrons from the photoactive layer to the metal electrode.In general,pure organic or inorganic materials are applied into the interlayers,but organic–inorganic hybrid materials have been rarely reported for this application.In this work,we report using the first titanium-oxo cluster-based organic–inorganic hybrid as the interlayer material by introducing largeπ-conjugated benzo[ghi]perylenetriimides as an organic part via a simple ligand-exchange reaction.This new hybrid material showed excellent solubility,well-aligned energy levels,and excellent electron mobilities,enabling its great potential application as an interlayer in solar cells such as perovskite and organic solar cells,providing high power conversion efficiencies of>20%and 16%,respectively.Therefore,we claim that our present work introduces a new class of cluster-based organic–inorganic hybrid interlayer materials that exhibit promising application in organic electronics.

Lateral organic-inorganic hybrid Vis-NIR photodetectors based on GaN nanowires promoting photogenerated carriers transfer

The narrow bandgap of the low-energy near-infrared(NIR)polymer would lead to overlap between adjacent energy levels,which is a major barrier to the preparation of Vis-NIR polymer bulk hetero-junction(BHJ)photodetectors with small responsivity and photocurrent.In this study,a high-performance lateral inorganic-organic hybrid photodetector was constructed to eliminate this barrier by combining GaN nanowires(GaN-NWs)with PDPP3T:PC61BM-based BHJ.In stage one,high-quality GaN-NWs were synthesized by the catalyst-free CVD method.The mechanism for controlling GaN-NWs morphology by adjusting the NH3 flow rate was revealed.In stage two,the GaN-NWs with large electron mobility were used to accelerate the transfer of photogenerated carriers in the BHJ layer.Finally,compared with the BHJ device,the BHJ/GaN device demonstrated obvious improvements in responsivity and photocurrent at the wavelength between 400 and 1000 nm.The responsivity and photocurrent increased over 20-fold at the NIR band of 800e900 nm.Besides,owing to the energy level gradient effect,the BHJ/GaN device has a response speed of 7.8/<5.0 ms,which increases over three orders of magnitude than that of the GaN-NWs-based device(tr/tf:7.1/10.9 s).Therefore,the novel device structure proposed in this work holds great potential for preparing high-performance Vis-NIR photodetectors.

胶铆混合连接复合材料层合板结构的弹性分析

基于MSC.Patran/Nastran软件隐式非线性模块,建立复合材料层合板的铆接、胶接及胶铆混合连接三维有限元模型,计算得到不同连接方式下的应力场及位移场,通过对所得数据的对比,分析不同连接方式可能发生的破坏形式及其破坏最有可能出现的位置,得到胶铆混合连接的适用性。

钢铝板材压-胶复合连接性能

为提高钢铝混合轻量化车身结构中钢和铝异种材料的连接性能,对钢铝板材的压-胶复合连接技术进行仿真与实验研究.以A5052铝合金板和Q235钢板为被连接件,环氧树脂为胶粘剂,采用内聚力模型模拟胶层的失效行为,建立压-胶复合连接的剪切和剥离仿真模型.在实验验证仿真模型有效性的基础上,基于响应面近似模型对连接工艺参数进行多目标优化,得到关于剪切强度和剥离强度的Pareto前沿解集以及各参数的优化组合.结果表明:优化解集中的多个工艺方案均能保证连接点剪切强度在9 400 N以上,而剥离强度均在700 N以上.实验证明钢铝板材压-胶复合连接强度比无胶单独的压力连接提高一倍以上,且可以达到同条件下钢板焊接拉伸强度的80%左右.

键合型有机/无机杂化材料加载条形波导电光调制器

相对于普通的有机/无机杂化材料,侧链键合型有机/无机杂化材料能提高生色团的掺杂浓度,避免出现结晶、相分离等现象,同时生色团极化有序性的弛豫因生色团运动受阻而降低,具有较高的热稳定性.本文采用溶胶凝胶法合成了一种性能优良、稳定的侧链键合型有机/无机杂化材料,并将这种材料应用于电光调制器的电光层,利用传统的半导体工艺,采用加载条形波导结构,成功制备了马赫-曾德尔(Mach-Zehnder,M-Z)型电光调制器.测试得到电光调制器在1 550 nm波长下10 kHz的响应信号,为键合型杂化材料应用于光电器件的进一步研究打下了基础.

溶胶-凝胶法合成有机无机杂化材料进展——2组分间以次价力作用的有机无机杂化材料

介绍了溶胶 凝胶法 (Sol gelprocess)制备组分间以次价力作用的有机 无机杂化材料的基本情况 ,根据合成方法进行分类 ,并指出其发展趋势。

复合材料双钉胶-螺混合连接结构参数对失效载荷的影响

在试验验证仿真模型可行性的基础上,通过数值模拟的方法探究了复合材料的铺层顺序,混合连接结构的宽径比、端径比、孔径比等参数对钛合金-复合材料双钉胶-螺混合连接结构承载能力的影响。研究结果表明:在常用的铺层顺序中,铺层顺序为[45°/0°/-45°/90°]_(3s)时,混合连接结构的承载能力最好;增加宽径比,连接结构的失效载荷会逐渐上升,但是连接强度却逐渐下降;在一定范围内,适当增加端径比或孔径比可以提高连接结构的承载能力,当超过这个范围时,连接结构的承载能力会下降。

拉挤工艺成型连续纤维增强热塑性FRP的性能与应用研究

目前,混凝土结构加固普遍采用纤维增强热固性复合材料,它不仅整体柔韧性较差,破坏没有预兆,界面粘结性能差,而且污染环境.选择国产高性能热塑性工程树脂和高强芳纶纤维、碳纤维及混杂纤维,采用连续在线熔融浸渍技术和连续拉挤成型工艺,分别制备了热塑性树脂基CFRP,AFRP,HFRP片材试件,并对其进行相关力学性能分析,得出热塑性复合片材达到现有加固材料指标.

一种基于吡啶-吡嗪酰胺配体的Keggin型多酸基化合物的组装及光催化性能

设计合成一种新的吡啶-吡嗪酰胺配体(pdya=N-(吡啶-3-基)吡嗪酰胺),并将其与Keggin型多酸H_3(PMo_(12)O_(40))·6H_2O在水热条件下反应合成了一种新的多酸基化合物杂化材料{H[(Hpdya)_2(PMo_(12)O_(40))]}_n,并通过元素分析、红外光谱、热重和单晶X-射线衍射对化合物的结构进行了表征.标题化合物分子式是C_(20)H_(19)PMo_(12)N_8O_(42),三斜晶系,P 21/n空间群,Mr=2225.68,V=2.6536(2)nm^3,a=1.23920(6)nm,b=1.53750(7)nm,c=1.40440(7)nm,β=97.3830(10)°,Z=2,Dc=2.784 g/cm^3,μ=2.877 mm^(-1),F(000)=2098,Rint=0.0401,R=0.0749,wR=0.2187.标题化合物的结构单元中包含游离的质子化的有机吡啶-吡嗪酰胺配体Hpdya和无机Keggin型[PMo_(12)O_(40)]3-多阴离子,并通过吡啶-吡嗪酰胺配体和[PMo_(12)O_(40)]3-多酸阴离子间存在的氢键作用拓展成一维超分子链结构.标题化合物作为一种新的无机-有机杂化材料不仅有较好的热稳定性,而且其在紫外光照射下可以有效的催化降解有机染料分子.

硅灰增强混杂纤维水泥基灌浆料与老混凝土粘结强度研究

通过四因素四水平正交试验进行硅灰增强混杂纤维水泥基灌浆料与老混凝土粘结强度的研究,选取硅灰掺量、钢纤维类型、钢纤维掺量和PVA纤维掺量作为研究因素,设定相应的水平。对粘结试块进行双面剪切试验和劈裂抗拉试验,运用极差分析上述因素和相应水平对粘结强度的影响。结果表明,当硅灰掺量为9%、长度35 mm端钩型钢纤维掺量为1.2%、PVA纤维掺量为0.5%时,粘结强度显著。基于正交试验结果,通过四组对比试验,研究了纤维对水泥基灌浆料与老混凝土粘结的界面剪切特性和劈拉破坏形态的影响。结果表明,当长度35 mm端钩型钢纤维与PVA纤维掺量分别为1.2%和0.5%混杂时,粘结试块的剪切变形性能和劈裂抗拉强度显著提高,表现出较强的粘结性能。