Research progress on the water vapor channel within the Yarlung Zsangbo Grand Canyon, China

The Second Tibetan Plateau Scientific Expedition and Research Program tasked a research team with the“Investigation of the water vapor channel of the Yarlung Zsangbo Grand Canyon(INVC)”in the southeastern Tibetan Plateau(TP).This paper summarizes the scientific achievements obtained from the data collected by the INVC observation network and highlights the progress in investigating the development of heavy rainfall events associated with water vapor changes.The rain gauge network of the INVC can represent the impacts of the Yarlung Zsangbo Grand Canyon(YGC)topography on precipitation at the hourly scale.The microphysical characteristics of the precipitation in the YGC are different than those in the lowland area.The GPM-IMERG(Integrated MultisatellitE Retrievals for Global Precipitation Measurement)satellite precipitation data for the YGC region should be calibrated before they are used.The meridional water vapor flux through the YGC is more important than the zonal flux for the precipitation over the southeastern TP.The decreased precipitation around the YGC region is partly due to the decreased meridional water vapor flux passing through the YGC.High-resolution numerical models can benefit precipitation forecasting in this region by using a combination of specific schemes that capture the valley wind and water vapor flux along the valley floor.

Analysis of the effect of the 2021 Semeru eruption on water vapor content and atmospheric particles using GNSS and remote sensing

Mount Semeru,an active volcano in East Java,Indonesia,erupted on December 4,2021,following extreme rainfall that caused an avalanche of hot pyroclastic flows and lava.The tropospheric conditions and dominant particle components in the atmosphere can be monitored using Global Navigation Satellite System(GNSS)technology and remote sensing satellites.GNSS signal propagation delay in Precise Point Positioning(PPP)processing can be used to determine Zenith Tropospheric Delay(ZTD)and Precipitable Water Vapor(PWV)variables so that atmospheric conditions can be generated.In addition,by using remote sensing satellite data,it is possible to obtain rainfall data with high temporal resolution as well as the dominant particle and gas content values during eruptions.During the eruption period,the high value of PWV was dominated by the high intensity of precipitation during the rainy season.High rainfall before the eruption caused activity inside the mountain to increase,which occurred in avalanche type eruption.Apart from that,the atmosphere around Semeru was also dominated by SO_(2)content,which spreaded for tens of kilometers.SO_(2)content began to be detected significantly by remote sensing sensors on December 7,2021.In this study,deformation and atmospheric monitoring were also carried out using low-cost GNSS at the Semeru Monitoring Station on September 9-15,2022.The results of the ZTD and ZWD values show the dominance of the wet component,which is directly proportional to rainfall activity in this period.

Linkage between precipitation isotopes and water vapor sources in the monsoon margin:Evidence from arid areas of Northwest China

The isotope composition in precipitation has been widely considered as a tracer of monsoon activity.Compared with the coastal region,the monsoon margin usually has limited precipitation with large fluctuation and is usually sensitive to climate change.The water resource management in the monsoon margin should be better planned by understanding the composition of precipitation isotope and its influencing factors.In this study,the precipitation samples were collected at five sampling sites(Baiyin City,Kongtong District,Maqu County,Wudu District,and Yinchuan City)of the monsoon margin in the northwest of China in 2022 to analyze the characteristics of stable hydrogen(δD)and oxygen(δ18O)isotopes.We analyzed the impact of meteorological factors(temperature,precipitation,and relative humidity)on the composition of precipitation isotope at daily level by regression analysis,utilized the Hybrid Single-Particle Lagrangian Integrated Trajectory(HYSPLIT)-based backward trajectory model to simulate the air mass trajectory of precipitation events,and adopted the potential source contribution function(PSCF)and concentration weighted trajectory(CWT)to analyze the water vapor sources.The results showed that compared with the global meteoric water line(GMWL),the slope of the local meteoric water line(LMWL;δD=7.34δ^(18)O-1.16)was lower,indicating the existence of strong regional evaporation in the study area.Temperature significantly contributed toδ18O value,while relative humidity had a significant negative effect onδ18O value.Through the backward trajectory analysis,we found eight primary locations that were responsible for the water vapor sources of precipitation in the study area,of which moisture from the Indian Ocean to South China Sea(ITSC)and the western continental(CW)had the greatest influence on precipitation in the study area.The hydrogen and oxygen isotopes in precipitation are significantly influenced by the sources and transportation paths of air mass.In addition,the results of PSCF and CWT analysis showed that the water vapor source areas were primarily distributed in the south and northwest direction of the study area.

Consistency of Tropospheric Water Vapor between Reanalyses and Himawari-8/AHI Measurements over East Asia

High spatiotemporal resolution radiances from the advanced imagers onboard the new generation of geostationary weather satellites provide a unique opportunity to evaluate the abilities of various reanalysis datasets to depict multilayer tropospheric water vapor(WV),thereby enhancing our understanding of the deficiencies of WV in reanalysis datasets.Based on daily measurements from the Advanced Himawari Imager(AHI)onboard the Himawari-8 satellite in 2016,the bias features of multilayer WV from six reanalysis datasets over East Asia are thoroughly evaluated.The assessments show that wet biases exist in the upper troposphere in all six reanalysis datasets;in particular,these biases are much larger in summer.Overall,we find better depictions of WV in the middle troposphere than in the upper troposphere.The accuracy of WV in the ERA5 dataset is the highest,in terms of the bias magnitude,dispersion,and pattern similarity.The characteristics of the WV bias over the Tibetan Plateau are significantly different from those over other parts of East Asia.In addition,the reanalysis datasets all capture the shift of the subtropical high very well,with ERA5 performing better overall.

Evaluation of surface temperature and pressure derived from MERRA-2 and ERA5 reanalysis datasets and their applications in hourly GNSS precipitable water vapor retrieval over China

Temperature and pressure play key roles in Global Navigation Satellite System(GNSS) precipitable water vapor(PWV) retrieval. The National Aeronautics and Space Administration(NASA) and European Center for Medium-Range Weather Forecasts(ECMWF) have released their latest reanalysis product: the modern-era retrospective analysis for research and applications, version 2(MERRA-2) and the fifthgeneration ECMWF reanalysis(ERA5), respectively. Based on the reanalysis data, we evaluate and analyze the accuracy of the surface temperature and pressure products in China using the the measured temperature and pressure data from 609 ground meteorological stations in 2017 as reference values.Then the accuracy of the two datasets and their performances in estimating GNSS PWV are analyzed. The PWV derived from the pressure and temperature products of ERA5 and MERRA-2 has high accuracy. The annual average biases of pressure and temperature for ERA5 are-0.07 hPa and 0.45 K, with the root mean square error(RMSE) of 0.95 hPa and 2.04 K, respectively. The annual average biases of pressure and temperature for MERRA-2 are-0.01 hPa and 0.38 K, with the RMSE of 1.08 h Pa and 2.66 K, respectively.The accuracy of ERA5 is slightly higher than that of MERRA-2. The two reanalysis data show negative biases in most regions of China, with the highest to lowest accuracy in the following order: the south,north, northwest, and Tibet Plateau. Comparing the GNSS PWV calculated using MERRA-2(GNSS MERRA-2 PWV) and ERA5(GNSS ERA5 PWV) with the radiosonde-derived PWV from 48 co-located GNSS stations and the measured PWV of the co-location radiosonde stations, it is found that the accuracy of GNSS ERA5 PWV is better than that of GNSS MERRA-2 PWV. These results show the different applicability of surface temperature and pressure products from MERRA-2 and ERA5 data, indicating that both have important applications in meteorological research and GNSS water vapor monitoring in China.

Decadal trends in precipitable water vapor over the Indus River Basin using ERA5 reanalysis data

Precipitable Water Vapor(PWV)constitutes a pivotal parameter within the domains of atmospheric science,and remote sensing due to its profound influence on Earth’s climate dynamics and weather patterns.It exerts a significant impact on atmospheric stability absorption and emission of radiation,thus engendering alterations in the Earth’s radiative equilibrium.As such,precise quantification of PWV holds the potential to enhance weather prognostication and fortify preparedness against severe meteorological phenomena.This study aimed to elucidate the spatial and temporal changes in seasonal and annual PWV across the Indus River Basin and its sub-basins using ERA5 reanalysis datasets.The present study used ERA5 PWV(entire atmospheric column),air temperature at 2 m(t2m)and 500 hPa(T_500hPa),evapotranspiration,and total cloud cover data from 1960 to 2021.Theil Sen slope estimator and Mann-Kendall test were used for trend analysis.Correlation and multiple regression methods were used to understand the association of PWV with other factors.The findings have unveiled the highest increase in mean PWV during the monsoon(0.40 mm/decade),followed by premonsoon(0.37 mm/decade),post-monsoon(0.27 mm/decade),and winter(0.19 mm/decade)throughout the study period.Additionally,the mean PWV exhibited the most pronounced positive trend in the sub-basin Lower Indus(LI),followed by Panjnad(P),Kabul(K),and Upper Indus(UI)across all seasons,except winter.Annual PWV has also risen in the Indus basin and its sub-basins over the last six decades.PWV exhibits a consistent upward trend up to an elevation of 3500 m within the basin which is most pronounced during the monsoon season,followed by the pre-monsoon.The escalating PWV within the basin is reasonably ascribed to increasing air temperatures,augmented evapotranspiration,and heightened cloud cover.These findings hold potential utility for pertinent authorities engaged in water resource management and planning.

Influence of water vapor on the separation of volatile organic compound/nitrogen mixture by polydimethylsiloxane membrane

In the industrial treatment of waste volatile organic compound(VOC)streams by membrane technology,a third impurity,generally,water vapor,coexists in the mixture of VOC and nitrogen or air,and can affect membrane performance and the design of the industrial process.This study focused on the investigation of the effect of water vapor on the separation performance of the separation of VOC/water/nitrogen mixtures by a polydimethylsiloxane(PDMS)membrane.Three types of VOCs:water-miscible ethanol,water-semi-miscible butanol,and water-immiscible cyclohexane,were selected for the study.Different operating parameters including,concentration of the feed VOC,feed temperature,and concentration of the feed water were compared for the separation of binary and ternary VOC/nitrogen mixtures.The interaction between the VOC and water was analyzed to explain the transportation mechanism after analyzing the difference in the membrane performance for the separation of binary and ternary mixtures.The results indicated that the interaction between the VOC(or nitrogen)and water is the key factor affecting membrane performance.Water can promote the permeation of hydrophilic VOC but prevent hydrophobic VOC through the membrane for the separation of ternary VOC/water/nitrogen mixtures.These results will provide fundamental insights for the design of the recovery application process for industrial membrane-based VOCs,and also guidance for the investigation of the separation mechanism in vapor permeation.

Rising trends of global precipitable water vapor and its correlation with flood frequency

Using 4 global reanalysis data sets, significant upward trends of precipitable water vapor(PWV) were found in the 3 time periods of 1958-2020, 1979-2020, and 2000-2020. During 1958-2020, the global PWV trends obtained using the ERA5 and JRA55 data sets are 0.19 ± 0.01 mm per decade(1.15 ± 0.31%)and 0.23 ± 0.01 mm per decade(1.45 ± 0.32%), respectively. The PWV trends obtained using the ERA5,JRA55, NCEP-NCAR, and NCEP-DOE data sets are 0.22 ± 0.01 mm per decade(1.18 ± 0.54%),0.21 ± 0.00 mm per decade(1.76 ± 0.56%), 0.27 ± 0.01 mm per decade(2.20 ± 0.70%) and 0.28 ± 0.01 mm per decade(2.19 ± 0.70%) for the period 1979-2020. During 2000-2020, the PWV trends obtained using ERA5, JRA55, NCEP-DOE, and NCEP-NCAR data sets are 0.40 ± 0.25 mm per decade(2.66 ± 1.51%),0.37 ± 0.24 mm per decade(2.19 ± 1.54%), 0.40 ± 0.26 mm per decade(1.96 ± 1.53%) and 0.36 ± 0.25 mm per decade(2.47 ± 1.72%), respectively. Rising PWV has a positive impact on changes in precipitation,increasing the probability of extreme precipitation and then changing the frequency of flood disasters.Therefore, exploring the relationship between PWV(derived from ERA5 and JRA55) change and flood disaster frequency from 1958 to 2020 revealed a significant positive correlation between them, with correlation coefficients of 0.68 and 0.79, respectively, which explains the effect of climate change on the increase in flood disaster frequency to a certain extent. The study can provide a reference for assessing the evolution of flood disasters and predicting their frequency trends.

Seasonal Difference of the Spatio-Temporal Variation of Precipitable Water Vapor in China

This study analyzes the spatial and temporal distribution characteristics of seasonal precipitable water vapor (PWV) in China between 1979 and 2008. To achieve this, the observed temperature dew point difference and atmospheric pressure at various altitudes of 102 radiosonde stations were utilized. The analysis involved calculating and examining the PWV variations across the different seasons in the study period. The results are illustrated as follows: 1) The annual mean and seasonal mean PWV over China is characterized by decreasing from southeast to northwest. The PWV has obvious seasonal features. It is the least in winter, which is mainly affected by latitude and altitude, and the most in summer, which is mainly affected by the monsoon. It is the medium in spring and autumn, with more in autumn than in spring. 2) The spatial distribution pattern of four seasonal PWV is approximately opposite to its variation coefficient distribution pattern, that is, the monsoon (non-monsoon) areas with more (less) PWV have a smaller (larger) variation amplitude. 3) The distribution pattern of four seasonal PWV shows a consistent distribution pattern in the whole region and the winter characteristics are the most significant. The abnormal variation of PWV shows consistent interdecadal oscillation, and it exhibits an obvious phase transition around 2002 when the PWV has an increasing shift in winter, spring, and summer, while it is more complicated in autumn.

Emphysematous sloughed floating ball after prostate water vaporization Rezum:A case report

BACKGROUND Rezūm™water vapor therapy is a new minimally invasive endoscopic technology for the management and treatment of benign prostatic hyperplasia.CASE SUMMARY A 63-year-old male presented to our department with severe dysuria,frequency,urgency,and interrupted stream 2 mo after receiving Rezūm™therapy.The symptoms were caused by a retained floating emphysematous necrotic sloughed tissue.We also discovered a persistent bacterial infection that was resistant to parenteral antimicrobial therapy.The treatment of the patient included surgical removal of the necrotic tissue.CONCLUSION Despite the good safety profile and minimal adverse events related to Rezūm™therapy,major complications can still occur.

Engineering of Self-Supported Electrocatalysts on a Three-Dimensional Nickel Foam Platform for Efficient Water Electrolysis

Economical water electrolysis requires highly active non-noble electrocatalysts to overcome the sluggish kinetics of the two half-cell reactions,oxygen evolution reaction,and hydrogen evolution reaction.Although intensive efforts have been committed to achieve a hydrogen economy,the expensive noble metal-based catalysts remain under consideration.Therefore,the engineering of self-supported electrocatalysts prepared using a direct growth strategy on three-dimensional(3D)nickel foam(NF)as a conductive substrate has garnered significant interest.This is due to the large active surface area and 3D porous network offered by these electrocatalysts,which can enhance the synergistic eff ect between the catalyst and the substrate,as well as improve electrocatalytic performance.Hydrothermal-assisted growth,microwave heating,electrodeposition,and other physical methods(i.e.,chemical vapor deposition and plasma treatment)have been applied to NF to fabricate competitive electrocatalysts with low overpotential and high stability.In this review,recent advancements in the development of self-supported electrocatalysts on 3D NF are described.Finally,we provide future perspectives of self-supported electrode platforms in electrochemical water splitting.

Validation of the Relationship between Precipitable Water and Surface Vapor Pressure by Means of Reanalysis Data

By means of ERA-40, JRA-25, NCEP/NCAR and NCEP/DOE reanalysis data, empirical relations between precipitable water and surface vapor pressure in spatial and temporal scale were calculated. The reliabilities of precipitable water from reanalysis data were validated based on comparing different W-e empirical relations of various reanalysis data, in order to provide basis and reference for reasonable application. The results showed that W-e empirical relation of ERA-40 was closest to that of sounding data in China, and precipitable water from ERA-40 was the most credible. The worldwide comparison among W-e empirical relations of four reanalysis data showed that there was little difference in annual mean W-e empirical relations in the middle latitudes and great differences in low and high latitudes. Seasonal mean W-e empirical relations in the middle latitudes of the northern Hemisphere had little difference in spring, autumn and winter, but great difference in summer. Therefore, the reliabilities of precipitable water from reanalysis data in spring, autumn and winter in the middle latitudes of the northern hemisphere were higher than other areas and seasons. W-e empirical relations of NCEP/NCAR and NCEP/DOE had good stability in different years, while there was poor stability in ERA-40 and JRA-25.

Relations of Water Vapor Transport from Indian Monsoon with That over East Asia and the Summer Rainfall in China

A diagnostic study is made to investigate the relationship between water vapor transport from Indian monsoon and that over East Asia in Northern summer. It is found that water vapor transport from Indian monsoon is inverse to that over East Asia. More (less) Indian monsoon water vapor transport corresponds to less (more) water vapor transport over East Asia and less (more) rainfall in the middle and lower reaches of the Yangtze River valley. The Indian summer monsoon water vapor transport is closely related to the intensity of the western Pacific subtropical high in its southwestern part. The stronger (weaker) the Indian summer monsoon water vapor transport, the weaker (stronger) the western Pacific subtropical high in its southwestern part, which leads to less (more) water vapor transport to East Asia, and thus less (more) rainfall in the middle and lower reaches of the Yangtze River valley. Analysis of the out-going longwave radiation anomalies suggests that the convective heating anomalies over the Indian Ocean may have significant impact not only on the Indian monsoon, but also on the East Asian monsoon.

The Recent Interdecadal and Interannual Variation of Water Vapor Transport over Eastern China

The climatological characteristics and interdecadal variability of the water vapor transport and budget over the Yellow River-Huaihe River valleys （YH1） and the Yangtze River-Huaihe River valleys （YH2） of East China were investigated in this study,using the NCEP/NCAR monthly mean reanalysis datasets from 1979 to 2009.Changes in the water vapor transport pattern occurred during the late 1990s over YH1 （YH2） that corresponded with the recent interdecadal changes in the eastern China summer precipitation pattern.The net moisture influx in the YH1 increased and the net moisture influx in the YH2 decreased during 2000-2009 in comparison to 1979-1999.Detailed features in the moisture flux and transport changes across the four boundaries were explored.The altered water vapor transport over the two domains can be principally attributed to the additive effects of the changes in the confluent southwesterly moisture flow by the Indian summer monsoon and East Asian summer monsoon （related with the eastward recession of the western Pacific subtropical high）.The altered water vapor transport over YH1 was also partly caused by the weakened midlatitude westerlies.

Preliminary Results of 4-D Water Vapor Tomography in the Troposphere Using GPS

Slant-path water vapor amounts （SWV） from a station to all the GPS （Global Positioning System） satellites in view can be estimated by using a ground-based GPS receiver. In this paper, a tomographic method was utilized to retrieve the local horizontal and vertical structure of water vapor over a local GPS receiver network using SWV amounts as observables in the tomography. The method of obtaining SWV using ground-based GPS is described first, and then the theory of tomography using GPS is presented. A water vapor tomography experiment was made using a small GPS network in the Beijing region. The tomographic results were analyzed in two ways： （1） a pure GPS method, i.e., only using GPS observables as input to the tomography, （2） combining GPS observables with vertical constraints or a priori information, which come from average radiosonde measurements over three days. It is shown that the vertical structure of water vapor is well resolved with a priori information. Comparisons of profiles between radiosondes and GPS show that the RMS error of the tomography is about 1-2 mm. It is demonstrated that the tomography can monitor the evolution of tropospheric water vapor in space and time. The vertical resolution of the tomography is tested with layer thicknesses of 600 m, 800 m and 1000 m. Comparisons with radiosondes show that the result from a resolution of 800 m is slightly better than results from the other two resolutions in the experiment. Water vapor amounts recreated from the tomography field agree well with precipitable water vapor （PWV） calculated using GPS delays. Hourly tomographic results are also shown using the resolution of 800 m. Water vapor characteristics under the background of heavy rainfall development are analyzed using these tomographic results. The water vapor spatio-temporal structures derived from the GPS network show a great potential in the investigation of weather disasters.

The Water Vapor Transport Model at the Regional Boundaryduring the Meiyu Period

The water vapor transport model at the regional boundary in the Meiyu period is put forward through diagnostic analysis. The numerical simulation on the water vapor transport at the boundary of China in the heavy rainfall period during June–July 1998 shows that the feature of water vapor transport in June is different from that in July. The main body of the water cycle that forms the torrential rain in the Yangtze River Valley is made up of water vapor transport at the western and southern boundaries of the China region in June, whereas the water vapor flow at the western boundary in middle Tibet turns out to be the main body of water vapor sources in July. The water vapor transport at the western boundary of the Tibetan Plateau and the southern boundary of China plays an important role in the torrential rain in the Yangtze River Valley. The temporal and spatial distribution characteristics of water vapor flow at the regional boundary and their theoretical model would provide the scientific proof for the heavy rain forecasts in the Yangtze River Valley.

Characteristics of the Mean Water Vapor Transport over Monsoon Asia

Based on ECMWF monthly mean data from January 1980 to December 1989,characterishcs of the three-dimensional structure of the mean water vapor transport over Monsoon Asia are described,and the more forportant features of the different regional water vapor transport in the indian Monsoon region and the East AsianMonsoon region are analyzed.It is found that there is a moist tongue extending from the equator POleWard to the Asian Monsoon region.The three-dimensional distributions of the mean water vapor transport fields over the entire globe renect clearly the asymmetry of the Asian Monsoon system,and the existence of a counterrHadley monsoon circulation.The moisture conver-gened(divergence) area in Asia coincides with the connuellt(diffiuent) zone of the monsoon cjrculahon.Furthermore,the moist featllres of the tWo sub-regions of the Asian Monsoon area are different both in their magnitudes and in their seasonal variations.

Water Vapor Transport and Cross-Equatorial Flow over the Asian-Australia Monsoon Region Simulated by CMIP5 Climate Models

The summer mean water vapor transport （WVT） and cross-equatorial flow （CEF） over the Asian- Australian monsoon region simulated by 22 coupled atmospheric-oceanic general circulation models （AOGCMs） from the World Climate Research Programme＇s Coupled Model Intercomparison Project Phase 5 （CMIP5） were evaluated. Based on climatology of the twentieth-century simulations, most of models have a reason- ably realistic representation of summer monsoon WVT characterized by southeast water vapor conveyor belt over the South Indian Ocean and southwest belt from the Arabian Sea to the East Asian. The correlation coefficients between NCEP reanalysis and simulations of BCC-CSMI-1, BNU-ESM, CanESM2, FGOALS-s2, MIROC4h and MPI-ESM-LR are up to 0.8. The simulated CEF depicted by the meridional wind along the equator includes the Somali jet and eastern CEF in low atmosphere and the reverse circulation in upper atmosphere, which were generally consistent with NCEP reanalysis. Multi-model ensemble means （MME） can reproduce more reasonable climatological features in spatial distribution both of WVT and CEF. Ten models with more reasonable WVT simulations were selected for future projection studies, including BCC- CSMI-1, BNU-ESM, CanESM2, CCSM4, FGOALS-s2, FIO-ESM, GFDL-ESM2G, MRIOCS, MPI-ESM-LR and NorESM-1M. Analysis based on the future projection experiments in RCP （Representative Concentra- tion Pathway） 2.6, RCP4.5, RCP6 and RCP8.5 show that the global warming forced by different RCP scenarios will results in enhanced WVT over the Indian area and the west Pacific and weaken WVT in the low latitudes of tropical Indian Ocean.

Impact of Increasing Stratospheric Water Vapor on Ozone Depletion and Temperature Change

Using a detailed, fully coupled chemistry climate model （CCM）, the effect of increasing stratospheric H20 on ozone and temperature is investigated. Different CCM time-slice runs have been performed to investigate the chemical and radiative impacts of an assumed 2 ppmv increase in H20. The chemical effects of this H20 increase lead to an overall decrease of the total column ozone （TCO） by ～1% in the tropics and by a maximum of 12% at southern high latitudes. At northern high latitudes, the TCO is increased by only up to 5% due to stronger transport in the Arctic. A 2-ppmv H2O increase in the model＇s radiation scheme causes a cooling of the tropical stratosphere of no more than 2 K, but a cooling of more than 4 K at high latitudes. Consequently, the TCO is increased by about 2%-6%. Increasing stratospheric H2O, therefore, cools the stratosphere both directly and indirectly, except in the polar regions where the temperature responds differently due to feedbacks between ozone and H2O changes. The combined chemical and radiative effects of increasing H2O may give rise to more cooling in the tropics and middle latitudes but less cooling in the polar stratosphere. The combined effects of H2O increases on ozone tend to offset each other, except in the Arctic stratosphere where both the radiative and chemical impacts give rise to increased ozone. The chemical and radiative effects of increasing H2O cause dynamical responses in the stratosphere with an evident hemispheric asymmetry. In terms of ozone recovery, increasing the stratospheric H2O is likely to accelerate the recovery in the northern high latitudes and delay it in the southern high latitudes. The modeled ozone recovery is more significant between 2000 ～2050 than between 2050～2100, driven mainly by the larger relative change in chlorine in the earlier period.

Temperature Dependency of Water Vapor Permeability of Shape Memory Polyurethane

Solution-cast films of shape memory polyurethane have been investigated.Differential scanning calorimetry, DMA, tensile test, water vapor permeability and the shape memory effect were carried out to characterize these polyurethane membranes. Samples cast at higher temperatures contained more hard segment in the crystalline state than a sample cast at lower temperature. The change in the water vapor permeability (WVP) of SMPU films with respect to the temperature follows an S-shaped curve, and increases abruptly at T m of the soft segment for the fractional free volume (FFV, the ratio of free volume and specific volume in polymers) increased linearly with temperature. The water vapor permeability dependency of the temperature and humidity contribute to the result of the change of diffusion and solubility with the surrounding air condition. The diffusion coefficient (D) are the function of temperature and show good fit the Arrhenius form but show different parameter values when above and below T g. The crystalline state hard-segment is necessary for the good shape memory