Carb on nanospheres(XC-72R)were functionalized by boron-oxygen(B-O)through coannealing with boric acid,to which highly dispersed palladium nanoparticles(Pd NPs)(-1.7 nm)were immobilized by a wet chemical reduction for...Carb on nanospheres(XC-72R)were functionalized by boron-oxygen(B-O)through coannealing with boric acid,to which highly dispersed palladium nanoparticles(Pd NPs)(-1.7 nm)were immobilized by a wet chemical reduction for the first time.The resultant Pd/OB-C catalystexhibits significantly improved activity for the dehydrogenation from formic acid(FA)compared to pristine XC-72R supported Pd NPs(Pd/C).Impressively,by adding melamine precursor,the B-0 and nitrogen(N)-functionalized product OB-C-N displays an extremely high B content,ca.34 times higher than OB-C.The Pd/OB-C-N catalyst with an ultrafine Pd particle size of-1.4 nm shows a superb activity,with a turnoverfrequency(TOF)as high as 5,354 h^-1 at 323 K,owing to the uniform ultrafine Pd NPs and the effect from B-0 and N functionalities.展开更多
文摘Carb on nanospheres(XC-72R)were functionalized by boron-oxygen(B-O)through coannealing with boric acid,to which highly dispersed palladium nanoparticles(Pd NPs)(-1.7 nm)were immobilized by a wet chemical reduction for the first time.The resultant Pd/OB-C catalystexhibits significantly improved activity for the dehydrogenation from formic acid(FA)compared to pristine XC-72R supported Pd NPs(Pd/C).Impressively,by adding melamine precursor,the B-0 and nitrogen(N)-functionalized product OB-C-N displays an extremely high B content,ca.34 times higher than OB-C.The Pd/OB-C-N catalyst with an ultrafine Pd particle size of-1.4 nm shows a superb activity,with a turnoverfrequency(TOF)as high as 5,354 h^-1 at 323 K,owing to the uniform ultrafine Pd NPs and the effect from B-0 and N functionalities.
