We analyze the frequencies of three known roAp stars,TIC 96315731,TIC 72392575,and TIC 318007796,using the light curves from the Transiting Exoplanet Survey Satellite.For TIC 96315731,the rotational and pulsational fr...We analyze the frequencies of three known roAp stars,TIC 96315731,TIC 72392575,and TIC 318007796,using the light curves from the Transiting Exoplanet Survey Satellite.For TIC 96315731,the rotational and pulsational frequencies are 0.1498360 day^(-1)and 165.2609 day^(-1),respectively.In the case of TIC 72392575,the rotational frequency is 0.25551 day^(-1).We detect a quintuplet of pulsation frequencies with a center frequency of135.9233 day^(-1),along with two signals within the second pair of rotational sidelobes of the quintuplet separated by the rotation frequency.These two signals may correspond to the frequencies of a dipole mode.In TIC318007796,the rotational and pulsational frequencies are 0.2475021 day^(-1),192.73995 day^(-1),and196.33065 day^(-1),respectively.Based on the oblique pulsator model,we calculate the rotation inclination(i)and magnetic obliquity angle(b)for the stars,which provide the geometry of the pulsation modes.Combining the phases of the frequency quintuplets,the pulsation amplitude and phase modulation curves,and the results of spherical harmonic decomposition,we conclude that the pulsation modes of frequency quintuplets in TIC96315731,TIC 72392575,and TIC 318007796 correspond to distorted dipole mode,distorted quadrupole mode,and distorted dipole mode,respectively.展开更多
A novel kinetic method for determination of trace amounts of cobalt ion was proposed and validated. The method is based on adding malic acid into classical Belousov-Zhabotinskii （B-Z） oscillating chemical system to ...A novel kinetic method for determination of trace amounts of cobalt ion was proposed and validated. The method is based on adding malic acid into classical Belousov-Zhabotinskii （B-Z） oscillating chemical system to form a double substrate one. The results showed that when the concentration of cobalt ion was in the range of 5.27× 10^-8 to 5.37 × 10^-12 mol L^-1, the change of the oscillating period was directly proportional to the negative logarithm of cobalt ion concentration. The sensitivity and precision of the developed method were quite satisfactory. The limit of detection was down to 5.20 × 10^-13 mol L^-1 which was a highest sensitivity found for determination of metal ions using oscillating chemical reaction so far. Some factors influencing the determination were also examined. The method has been successfully used to determine cobalt ion in vitamin B12 injection.展开更多
A novel oscillating chemical reaction using ninhydrin as a single organic substrate was represented in this paper. It distinguished from the classically catalyzed BZ oscillating chemical reaction due to there was no a...A novel oscillating chemical reaction using ninhydrin as a single organic substrate was represented in this paper. It distinguished from the classically catalyzed BZ oscillating chemical reaction due to there was no active methene （CH2=） and/or enol structure in the ninhydrin molecule, which served as single organic substrate. This suggested that the substrates used in catalyzed BZ reaction were not always the organic compounds containing active methene （CH2=） and/or enol structure and bromination process in this kind of catalyzed chemical oscillating reaction was not also necessary.展开更多
The oscillation behavior of a two-dimension lattice-gas Brusselator model was investigated. We have adopted a coarse-grained kinetic Monte Carlo （CG-KMC） procedure, where m×m microscopic lattice sites are group...The oscillation behavior of a two-dimension lattice-gas Brusselator model was investigated. We have adopted a coarse-grained kinetic Monte Carlo （CG-KMC） procedure, where m×m microscopic lattice sites are grouped together to form a CG cell, upon which CG processes take place with well-defined CG rates. Such a CG approach almost fails if the CG rates are obtained by a simple local mean field （s-LMF） approximation, due to the ignorance of correlation among adjcent cells resulting fl＇om the trimolecular reaction in this nonlinear system. By proper incorporating such boundary effects, thus introduce the so-cMled b-LMF CG approach. Extensive numerical simulations demonstrate that the b-LMF method can reproduce the oscillation behavior of the system quite well, given that the diffusion constant is not too small. In addition, the deviation from the KMC results reaches a nearly zero minimum level at an intermediate cell size, which lies in between the effective diffusion length and the minimal size required to sustain a well-defined temporal oscillation.展开更多
A new chemical oscillating reaction system involving the manganese(II)-catalyzed reaction among potassium bromate, acetone and tyrosine in acidic medium was described in this paper. The apparent activation energy of ...A new chemical oscillating reaction system involving the manganese(II)-catalyzed reaction among potassium bromate, acetone and tyrosine in acidic medium was described in this paper. The apparent activation energy of the induction period (Ein) and that of oscillation period (Ep) were calculated, Ein=110.61KJ/mol, Ep=159.41KJ/mol. The optimum concentration of each reactant was investigated and a steady chemical oscillating system was obtained.展开更多
Abstract: This work studies the active control of chemical oscillations governed by a forced modified Van der Pol-Duffing oscillator. We considered the dynamics of nonlinear chemical systems subjected to an external s...Abstract: This work studies the active control of chemical oscillations governed by a forced modified Van der Pol-Duffing oscillator. We considered the dynamics of nonlinear chemical systems subjected to an external sinusoidal excitation. The approximative solution to the first order of the modified Van der Pol-Duffing oscillator is found using the Lindstedt’s perturbation method. The harmonic balance method is used to find the amplitudes of the oscillatory states of the system under control. The effects of the constraint parameter and the control parameter of the model on the amplitude of oscillations are presented. The effects of the active control on the behaviors of the model are analyzed and it appears that with the appropriate selection of the coupling parameter, the chaotic behavior of the model has given way to periodic movements. Numerical simulations are used to validate and complete the analytical results obtained.展开更多
A new Belousov-Zhabotinsky oscillator induced by Triton X-100 (a nonionic surfactant)with glucose as the organic substrate and Ce^(4+)as the catalyst has been reported in this paper.
Based on the physical chemistry principle, this paper proposes that the surface adsorption catalytic mechanism of HF is the key to dissolving the oscillation of the CaF\-2\|HCl\|H\-2O solid\|liquid reaction system. Me...Based on the physical chemistry principle, this paper proposes that the surface adsorption catalytic mechanism of HF is the key to dissolving the oscillation of the CaF\-2\|HCl\|H\-2O solid\|liquid reaction system. Meanwhile the dynamical model of this system has been established in order to study its non\|linear dynamical genesis. Although this mathematics model is based on CSTR reaction apparatus, it is applicable to the foliate flow reaction apparatus, too.展开更多
The electrical oscillations across a liquid membrane in water/oil/water system was studied with octanol as oil phase by introducing two opposite charged surfactants in oil and aqueous phase, respectively. The sustaine...The electrical oscillations across a liquid membrane in water/oil/water system was studied with octanol as oil phase by introducing two opposite charged surfactants in oil and aqueous phase, respectively. The sustained and rhythmic oscillation was observed. To a certain extent, the features of the oscillation （e.g. induction time, frequency, life time and orientation of the pulse pikes） strongly depend on the property of surfactant, dissolved in octanol. The mechanism may be explained by the formation and destruction of dual-ion surfactant membrane accompanying with emulsification at the interface and considering the coupling effect of diffusion and associated reaction in the vicinity of the interface.展开更多
Temperature dependent viscosity and thermal conducting heat and mass transfer flow with chemical reaction and periodic magnetic field past an isothermal oscillating cylinder have been considered. The partial dimension...Temperature dependent viscosity and thermal conducting heat and mass transfer flow with chemical reaction and periodic magnetic field past an isothermal oscillating cylinder have been considered. The partial dimensionless equations governing the flow have been solved numerically by applying explicit finite difference method with the help Compaq visual 6.6a. The obtained outcome of this inquisition has been discussed for different values of well-known flow parameters with different time steps and oscillation angle. The effect of chemical reaction and periodic MHD parameters on the velocity field, temperature field and concentration field, skin-friction, Nusselt number and Sherwood number have been studied and results are presented by graphically. The novelty of the present problem is to study the streamlines by taking into account periodic magnetic field.展开更多
In this paper, the dependences of the frequeucy-temperature coefficient (df/dt) of an electrode-sepa-rated piezolectric sensor(ESPS) on desity, viscosity, permittivity and conductivity of the solution to be tested wer...In this paper, the dependences of the frequeucy-temperature coefficient (df/dt) of an electrode-sepa-rated piezolectric sensor(ESPS) on desity, viscosity, permittivity and conductivity of the solution to be tested were investigated’ A comparison of the frequency -temperature coefficient between the ESPS and a conwentioal piezoelectric quartz crystal was made, In a nou-electrolyte liquid, the df/dt)walwe of the ESPS increases with the increase of viscosity, density and permittivity of the liquid There is df/dt>0 in low or high conductivity solutions, but df/dt>0 in middle conductivity solution.And two zoues where df/dt is approximately equal to zero are observed in electrolyte展开更多
In this paper we report a chemical oscillation catalyzed by [Ni(Me2[14]1,3-diene N4)]2+ (Me2[14]l,3-diene N4 denotes 2,3-dimethyl-l,4,8,ll-tetraazacyclotetradeca-1,3-diene) in BrO3--pyruvic acid-H2SO4 system.The domai...In this paper we report a chemical oscillation catalyzed by [Ni(Me2[14]1,3-diene N4)]2+ (Me2[14]l,3-diene N4 denotes 2,3-dimethyl-l,4,8,ll-tetraazacyclotetradeca-1,3-diene) in BrO3--pyruvic acid-H2SO4 system.The domain of the existence of the oscillation was obtained.The effects of initial concentration of the components on the oscillation were studied.The features of the oscillations were described in detail.We also examined the effects of Ag+,Hg2+,CCl4,free radical inhibitors,etc.on the osillations.展开更多
基金Funding for the TESS mission is provided by the NASA Explorer Programsupport of the National Natural Science Foundation of China(NSFC,grant Nos.U2031204,12373038,12163005,and 12288102)+1 种基金the science research grants from the China Manned Space Project with No.CMSCSST-2021-A10the Natural Science Foundation of Xinjiang Nos.2022D01D85 and 2022TSYCLJ0006。
文摘We analyze the frequencies of three known roAp stars,TIC 96315731,TIC 72392575,and TIC 318007796,using the light curves from the Transiting Exoplanet Survey Satellite.For TIC 96315731,the rotational and pulsational frequencies are 0.1498360 day^(-1)and 165.2609 day^(-1),respectively.In the case of TIC 72392575,the rotational frequency is 0.25551 day^(-1).We detect a quintuplet of pulsation frequencies with a center frequency of135.9233 day^(-1),along with two signals within the second pair of rotational sidelobes of the quintuplet separated by the rotation frequency.These two signals may correspond to the frequencies of a dipole mode.In TIC318007796,the rotational and pulsational frequencies are 0.2475021 day^(-1),192.73995 day^(-1),and196.33065 day^(-1),respectively.Based on the oblique pulsator model,we calculate the rotation inclination(i)and magnetic obliquity angle(b)for the stars,which provide the geometry of the pulsation modes.Combining the phases of the frequency quintuplets,the pulsation amplitude and phase modulation curves,and the results of spherical harmonic decomposition,we conclude that the pulsation modes of frequency quintuplets in TIC96315731,TIC 72392575,and TIC 318007796 correspond to distorted dipole mode,distorted quadrupole mode,and distorted dipole mode,respectively.
基金the Project of International Cooperation between China and Ukraine(No.043-05)National Natural Science Foundation and Key Lab of Polymer Materials of Gansu Province for their financial supports.
文摘A novel kinetic method for determination of trace amounts of cobalt ion was proposed and validated. The method is based on adding malic acid into classical Belousov-Zhabotinskii （B-Z） oscillating chemical system to form a double substrate one. The results showed that when the concentration of cobalt ion was in the range of 5.27× 10^-8 to 5.37 × 10^-12 mol L^-1, the change of the oscillating period was directly proportional to the negative logarithm of cobalt ion concentration. The sensitivity and precision of the developed method were quite satisfactory. The limit of detection was down to 5.20 × 10^-13 mol L^-1 which was a highest sensitivity found for determination of metal ions using oscillating chemical reaction so far. Some factors influencing the determination were also examined. The method has been successfully used to determine cobalt ion in vitamin B12 injection.
文摘A novel oscillating chemical reaction using ninhydrin as a single organic substrate was represented in this paper. It distinguished from the classically catalyzed BZ oscillating chemical reaction due to there was no active methene （CH2=） and/or enol structure in the ninhydrin molecule, which served as single organic substrate. This suggested that the substrates used in catalyzed BZ reaction were not always the organic compounds containing active methene （CH2=） and/or enol structure and bromination process in this kind of catalyzed chemical oscillating reaction was not also necessary.
文摘The oscillation behavior of a two-dimension lattice-gas Brusselator model was investigated. We have adopted a coarse-grained kinetic Monte Carlo （CG-KMC） procedure, where m×m microscopic lattice sites are grouped together to form a CG cell, upon which CG processes take place with well-defined CG rates. Such a CG approach almost fails if the CG rates are obtained by a simple local mean field （s-LMF） approximation, due to the ignorance of correlation among adjcent cells resulting fl＇om the trimolecular reaction in this nonlinear system. By proper incorporating such boundary effects, thus introduce the so-cMled b-LMF CG approach. Extensive numerical simulations demonstrate that the b-LMF method can reproduce the oscillation behavior of the system quite well, given that the diffusion constant is not too small. In addition, the deviation from the KMC results reaches a nearly zero minimum level at an intermediate cell size, which lies in between the effective diffusion length and the minimal size required to sustain a well-defined temporal oscillation.
基金sponsored by the Project of Youth Teachers Foundation of Education Ministry(3076),the Project of KJCXGC-01,NWNUNational Natural Science Foundation of China(29875018)
文摘A new chemical oscillating reaction system involving the manganese(II)-catalyzed reaction among potassium bromate, acetone and tyrosine in acidic medium was described in this paper. The apparent activation energy of the induction period (Ein) and that of oscillation period (Ep) were calculated, Ein=110.61KJ/mol, Ep=159.41KJ/mol. The optimum concentration of each reactant was investigated and a steady chemical oscillating system was obtained.
文摘Abstract: This work studies the active control of chemical oscillations governed by a forced modified Van der Pol-Duffing oscillator. We considered the dynamics of nonlinear chemical systems subjected to an external sinusoidal excitation. The approximative solution to the first order of the modified Van der Pol-Duffing oscillator is found using the Lindstedt’s perturbation method. The harmonic balance method is used to find the amplitudes of the oscillatory states of the system under control. The effects of the constraint parameter and the control parameter of the model on the amplitude of oscillations are presented. The effects of the active control on the behaviors of the model are analyzed and it appears that with the appropriate selection of the coupling parameter, the chaotic behavior of the model has given way to periodic movements. Numerical simulations are used to validate and complete the analytical results obtained.
文摘A new Belousov-Zhabotinsky oscillator induced by Triton X-100 (a nonionic surfactant)with glucose as the organic substrate and Ce^(4+)as the catalyst has been reported in this paper.
文摘Based on the physical chemistry principle, this paper proposes that the surface adsorption catalytic mechanism of HF is the key to dissolving the oscillation of the CaF\-2\|HCl\|H\-2O solid\|liquid reaction system. Meanwhile the dynamical model of this system has been established in order to study its non\|linear dynamical genesis. Although this mathematics model is based on CSTR reaction apparatus, it is applicable to the foliate flow reaction apparatus, too.
文摘The electrical oscillations across a liquid membrane in water/oil/water system was studied with octanol as oil phase by introducing two opposite charged surfactants in oil and aqueous phase, respectively. The sustained and rhythmic oscillation was observed. To a certain extent, the features of the oscillation （e.g. induction time, frequency, life time and orientation of the pulse pikes） strongly depend on the property of surfactant, dissolved in octanol. The mechanism may be explained by the formation and destruction of dual-ion surfactant membrane accompanying with emulsification at the interface and considering the coupling effect of diffusion and associated reaction in the vicinity of the interface.
文摘Temperature dependent viscosity and thermal conducting heat and mass transfer flow with chemical reaction and periodic magnetic field past an isothermal oscillating cylinder have been considered. The partial dimensionless equations governing the flow have been solved numerically by applying explicit finite difference method with the help Compaq visual 6.6a. The obtained outcome of this inquisition has been discussed for different values of well-known flow parameters with different time steps and oscillation angle. The effect of chemical reaction and periodic MHD parameters on the velocity field, temperature field and concentration field, skin-friction, Nusselt number and Sherwood number have been studied and results are presented by graphically. The novelty of the present problem is to study the streamlines by taking into account periodic magnetic field.
文摘In this paper, the dependences of the frequeucy-temperature coefficient (df/dt) of an electrode-sepa-rated piezolectric sensor(ESPS) on desity, viscosity, permittivity and conductivity of the solution to be tested were investigated’ A comparison of the frequency -temperature coefficient between the ESPS and a conwentioal piezoelectric quartz crystal was made, In a nou-electrolyte liquid, the df/dt)walwe of the ESPS increases with the increase of viscosity, density and permittivity of the liquid There is df/dt>0 in low or high conductivity solutions, but df/dt>0 in middle conductivity solution.And two zoues where df/dt is approximately equal to zero are observed in electrolyte
基金Project supported by the National Natural Science Foundation of China and the State Key Laboratory of Coordination Chemistry in Nanjing University.
文摘In this paper we report a chemical oscillation catalyzed by [Ni(Me2[14]1,3-diene N4)]2+ (Me2[14]l,3-diene N4 denotes 2,3-dimethyl-l,4,8,ll-tetraazacyclotetradeca-1,3-diene) in BrO3--pyruvic acid-H2SO4 system.The domain of the existence of the oscillation was obtained.The effects of initial concentration of the components on the oscillation were studied.The features of the oscillations were described in detail.We also examined the effects of Ag+,Hg2+,CCl4,free radical inhibitors,etc.on the osillations.
