Structural strengthening of the nano porous silica films has been reported. The films were prepared with a base/acid two-step catalyzed TEOS-based sol-gel processing and dip-coating, and then baked in the mixed gas of...Structural strengthening of the nano porous silica films has been reported. The films were prepared with a base/acid two-step catalyzed TEOS-based sol-gel processing and dip-coating, and then baked in the mixed gas of ammonia and water vapor. The silica films were characterized with TEM, AFM, FTIR, spectrophotometer, ellipsometer, and abrasion test, respectively. The experimental results have shown that the films have a nanostructure with a low refractive index and can form an excellent scratch-resistant broadband anti-reflectance. The two-step catalysis noticeably strengthens the films, and the mixed gas treatment further improves mechanical strength of the silica network. Finally the strengthening mechanism has been discussed.展开更多
A simple design of broadband metamaterial absorber（MA） based on resistive film is numerically presented in this paper.The unit cell of this absorber is composed of crossed rectangular rings-shaped resistive film,die...A simple design of broadband metamaterial absorber（MA） based on resistive film is numerically presented in this paper.The unit cell of this absorber is composed of crossed rectangular rings-shaped resistive film,dielectric substrate,and continuous metal film.The simulated results indicate that the absorber obtains a 12.82-GHz-wide absorption from about 4.75 GHz to 17.57 GHz with absorptivity over 90% at normal incidence.Distribution of surface power loss density is illustrated to understand the intrinsic absorption mechanism of the structure.The proposed structure can work at wide polarization angles and wide angles of incidence for both transverse electric（TE） and transverse magnetic（TM） waves.Finally,the multi-reflection interference theory is involved to analyze and explain the broadband absorption mechanism at both normal and oblique incidence.Moreover,the polarization-insensitive feature is also investigated by using the interference model.It is seen that the simulated and calculated absorption rates agree fairly well with each other for the absorber.展开更多
Structure and properties of anti-reflection thin films of spherical silicon solar cells were investigated and discussed. Conversion efficiencies of spherical Si solar cells coated with F-doped SnO2 anti-reflection fil...Structure and properties of anti-reflection thin films of spherical silicon solar cells were investigated and discussed. Conversion efficiencies of spherical Si solar cells coated with F-doped SnO2 anti-reflection films were improved by annealing. Optical absorption and fluorescence of the solar cells increased after annealing. Lattice constants of F-doped SnO2 anti-reflection layers, which were investigated by X-ray diffraction, decreased after annealing. A mechanism of atomic diffusion of F in SnO2 was discussed. The present work indicated a guideline for spherical silicon solar cells with higher efficiencies.展开更多
Light absorption enhancement is very important for improving the power conversion efficiency of a thin film a-Si solar cell. In this paper, a thin-film a-Si solar cell model with double-sided SiO2 particle layers is d...Light absorption enhancement is very important for improving the power conversion efficiency of a thin film a-Si solar cell. In this paper, a thin-film a-Si solar cell model with double-sided SiO2 particle layers is designed, and then the underlying mechanism of absorption enhancement is investigated by finite difference time domain（FDTD） simulation;finally the feasible experimental scheme for preparing the SiO2 particle layer is discussed. It is found that the top and bottom SiO2 particle layers play an important role in anti-reflection and light trapping, respectively. The light absorption of the cell with double-sided SiO2 layers greatly increases in a wavelength range of 300 nm-800 nm, and the ultimate efficiency increases more than 22% compared with that of the flat device. The cell model with double-sided SiO2 particle layers reported here can be used in varieties of thin film solar cells to further improve their performances.展开更多
基金the National Natural Science Foundation of China(No:69978017,20133040)Shanghai Key Subject Programme,Chinese Foundation of High Technology(2002AA842052)Shanghai Natural Science Foundation(02ZE14101)as well as Shanghai Nanotechnology Promotion Center(0159um039).
文摘Structural strengthening of the nano porous silica films has been reported. The films were prepared with a base/acid two-step catalyzed TEOS-based sol-gel processing and dip-coating, and then baked in the mixed gas of ammonia and water vapor. The silica films were characterized with TEM, AFM, FTIR, spectrophotometer, ellipsometer, and abrasion test, respectively. The experimental results have shown that the films have a nanostructure with a low refractive index and can form an excellent scratch-resistant broadband anti-reflectance. The two-step catalysis noticeably strengthens the films, and the mixed gas treatment further improves mechanical strength of the silica network. Finally the strengthening mechanism has been discussed.
文摘A simple design of broadband metamaterial absorber（MA） based on resistive film is numerically presented in this paper.The unit cell of this absorber is composed of crossed rectangular rings-shaped resistive film,dielectric substrate,and continuous metal film.The simulated results indicate that the absorber obtains a 12.82-GHz-wide absorption from about 4.75 GHz to 17.57 GHz with absorptivity over 90% at normal incidence.Distribution of surface power loss density is illustrated to understand the intrinsic absorption mechanism of the structure.The proposed structure can work at wide polarization angles and wide angles of incidence for both transverse electric（TE） and transverse magnetic（TM） waves.Finally,the multi-reflection interference theory is involved to analyze and explain the broadband absorption mechanism at both normal and oblique incidence.Moreover,the polarization-insensitive feature is also investigated by using the interference model.It is seen that the simulated and calculated absorption rates agree fairly well with each other for the absorber.
文摘Structure and properties of anti-reflection thin films of spherical silicon solar cells were investigated and discussed. Conversion efficiencies of spherical Si solar cells coated with F-doped SnO2 anti-reflection films were improved by annealing. Optical absorption and fluorescence of the solar cells increased after annealing. Lattice constants of F-doped SnO2 anti-reflection layers, which were investigated by X-ray diffraction, decreased after annealing. A mechanism of atomic diffusion of F in SnO2 was discussed. The present work indicated a guideline for spherical silicon solar cells with higher efficiencies.
基金Project supported by the National High-Tech Research and Development Program of China(Grant No.2011AA050518)the University Research Program of Guangxi Education Department,China(Grant No.LX2014288)the Natural Science Foundation of Guangxi Zhuang Autonomous Region,China(Grant No.2013GXNSBA019014)
文摘Light absorption enhancement is very important for improving the power conversion efficiency of a thin film a-Si solar cell. In this paper, a thin-film a-Si solar cell model with double-sided SiO2 particle layers is designed, and then the underlying mechanism of absorption enhancement is investigated by finite difference time domain（FDTD） simulation;finally the feasible experimental scheme for preparing the SiO2 particle layer is discussed. It is found that the top and bottom SiO2 particle layers play an important role in anti-reflection and light trapping, respectively. The light absorption of the cell with double-sided SiO2 layers greatly increases in a wavelength range of 300 nm-800 nm, and the ultimate efficiency increases more than 22% compared with that of the flat device. The cell model with double-sided SiO2 particle layers reported here can be used in varieties of thin film solar cells to further improve their performances.
