Exploring a broadened operating pH range for norfloxacin removal via simulated solar-light-mediated Bi_2WO_6 process

Semiconductor photocatalysis can be operated over a narrow pH range for wastewater treatment. In this study, a simulated solar-light-mediated bismuth tungstate (SSL/Bi2WO6) process is found to be effective for norfloxacin degradation over a narrow pH range. To broaden the operating pH range of the SSL/Bi2WO6 process, an NH4+ buffer system and an Fe3+ salt were introduced under extremely basic and acidic pH conditions, respectively. The NH4+ buffer system continuously supplied hydroxyl ions to generate ·OH radicals and prevented acidification of the solution, resulting in improved norfloxacin removal and mineralization removal under alkaline conditions. In contrast, the Fe3+ salt offered an additional homogeneous photo-sensitization pathway. The former treatment assisted in norfloxacin decay and the latter increased the collision frequency between the photo-generated hole and hydroxyl ions. Moreover, the effect of parameters such as pH and Fe3+ dosage was optimized.

Exfoliated multi-layered graphene anode with the broadened delithiation voltage plateau below 0.5 V

The commercial graphite(CG)is the conventional anode material for lithium ion batteries(LIBs)due to its low delithiation voltage plateau(below 0.5 V)and extraordinary durability.Nevertheless,the further promotion of energy density of LIBs is restricted by the limited capacity below 0.5 V of CG.Here,based on the supercritical CO2 exfoliation technique,the production of multi-layered graphene(MLG)is achieved from the pilot scale production line.The great merit of the exfoliated MLG anode is that the voltage plateau below 0.5 V is broadened obviously as compared to those of natural graphite and CG.Additionally,no obvious lithium dendrites are observed for MLG during the lithiation process.The large delithiation capacity under the low voltage plateau of MLG is mainly benefited from the combination of Li intercalation and boundary storage mechanism,which is further confirmed by the density functional theory calculations.The LiFePO4/MLG full cell can afford the satisfactory electrochemical property with respect to the capacity,energy density and ultralong cycling stability(90%capacity retention after 500 cycles at 2 C),significantly better than that of LiFePO4/CG.Besides,this developed technique not only dedicates to producing the high-performance anode for LIBs but also opens a door for the mass production of MLG in the industrial scale.

Pressure-broadened atomic Li(2s-2p) line perturbed by ground neon atoms in the spectral wings and core

Full quantum calculations are performed to investigate the broadening profiles of the atomic lithium Li（2s-2p） resonance line induced by interactions with ground Ne（2s^22p^6） perturbers in the spectral wings and core. The X^2Σ~＋, A^2Π,and B^2Σ~＋ potential-energy curves of the two first low lying Li Ne molecular states, as well as the corresponding transition dipole moments, are determined with ab initio methods based on the SA-CASSCF-MRCI calculations. The emission and absorption coefficients in the wavelength range 550-800 nm and the line-core width and shift are investigated theoretically for temperatures ranging from 130 K to 3000 K. Their temperature dependence is analyzed, and the obtained results are compared with the previous experimental measurements and theoretical works.

the phase-dependent gain without inversion in a Doppler broadened open four-level system

It is shown that in a Doppler broadened open N-type four-level atomic system with spontaneously generated coherence （SGC）, the gain without inversion （GWI） is very sensitive to the variation of the relative phase between the probe field and the driving field; the atomic exit rate （R0） and the ratio （S） of the atomic injection rates have a considerable modulation effect on the phase-dependent GWI. GWI first increases and then decreases with R0 increasing; in a certain value range of S, GWI increases monotonically with S increasing; by adjusting the values of R0 and S, in an open system a much larger GWI can be obtained than in the corresponding closed system [2011 Phys. Rev. A 83 043805]. The modulation effects of R0 and S on the phase-dependent GWI in the case with the counter-propagating probe and driving fields are stronger than those in the co-propagating case, GWI in the co-propagating case is much larger than that in the counter-propagating case.

Modulation of atomic exit and injection rates on the phase-dependent gain without inversion in a Doppler broadened open four-level system

It is shown that in a Doppler broadened open N-type four-level atomic system with spontaneously generated coherence (SGC), the gain without inversion (GWI) is very sensitive to the variation of the relative phase between the probe field and the driving field; the atomic exit rate (R0) and the ratio (S) of the atomic injection rates have a considerable modulation effect on the phase-dependent GWI. GWI first increases and then decreases with R0 increasing; in a certain value range of S, GWI increases monotonically with S increasing; by adjusting the values of R0 and S, in an open system a much larger GWI can be obtained than in the corresponding closed system [2011 Phys. Rev. A 83 043805]. The modulation effects of R0 and S on the phase-dependent GWI in the case with the counter-propagating probe and driving fields are stronger than those in the co-propagating case, GWI in the co-propagating case is much larger than that in the counter-propagating case.

Decoupling of temporal/spatial broadening effects in Doppler wind LiDAR by 2D spectral analysis

Pulse echo accumulation is commonly employed in coherent Doppler wind LiDAR(light detection and ranging)under the assumption of steady wind.Here,the measured spectral data are analyzed in the time dimension and frequency dimension to cope with the temporal wind shear and achieve the optimal accumulation time.A hardware-efficient algorithm combining the interpolation and cross-correlation is used to enhance the wind retrieval accuracy by reducing the frequency sampling interval and then reduce the spectral width calculation error.Moreover,the temporal broadening effect and spatial broadening effect are decoupled according to the strategy we developed.

Design of tightly linked dual ring antenna and imaging of magnetic field distribution using a diamond fiber probe

A tightly linked dual ring antenna is designed,and it is specifically tailored for uniformly coupling the microwave magnetic field to the nitrogen-vacancy(NV)center.The designed antenna operates at a center frequency of about 2.87 GHz,with a bandwidth of around 200 MHz,allowing it to address multiple resonance peaks in the optically detected magnetic resonance(ODMR)spectrum in an external magnetic field.Moreover,the antenna generates a fairly uniform magnetic field in a range with a radius of 0.75 mm.High resolution imaging of the magnetic field distribution on the surface of the antenna is conducted by using a fiber diamond probe.We also investigate the effect of magnetic field uniformity on the linewidth of ODMR,so as to provide insights into reducing the inhomogeneous broadening of ODMR.

Comparing simulated and experimental spectral line splitting in visible spectroscopy diagnostics in the HL-2A tokamak

We established the passive-visible spectroscopy diagnostics(P-VSD)and active-VSD(A-VSD)spectral splitting models for the HL-2A tokamak.Spectral splitting due to the influence of electromagnetic fields on the spectra in VSD is studied.Zeeman splitting induced by the magnetic field(B)is used to distinguish reflected light overlap in the divertor for P-VSD.Stark splitting caused by the Lorentz electric field(E_(Lorentz))from the neutral beam injection particle’s interaction with the magnetic field(V_(beam)×B)is used to measure the safety factor q profile for A-VSD.We give a comparison and error analysis by fitting the experimental spectra with the simulation results.The distinguishing of edge(scrape-off layer and divertor)hydrogen/deuterium spectral lines and the q profile derived from the spectra provides a reference for HL-2M VSD.

In situ temperature measurement of vapor based on atomic speed selection

We demonstrate an experimental method for the in situ temperature measurement of atomic vapor using the saturated absorption spectrum. By separately manipulating the frequency of the pump and probe beams, the position of the crossover peaks can move along the spectrum. Different velocity classes of atoms contribute to the crossover during the movement. We study the relationship between the intensity change of peaks and vapor temperature. Our experimental result around room temperature shows a deviation of less than 0.3 K. Compared with traditional thermometry using absorption spectroscopy, higher accuracy can theoretically be achieved with real-time thermometry.

Theoretical study of electron-impact broadening for highly charged Ar XV ion lines

Spectral line widths produced by collisions between charged particles and emitters are of special interest for precise plasma spectroscopy.The highly charged Ar XV ion is demonstrated to have strong intrashell electron interactions,which manifest as an atomic system with many resonance structures,due to the quasi-degeneracy of orbital energies.In this paper we use the relativistic R-matrix method to investigate the electron-impact broadening of highly charged Ar XV ion spectral lines under the impact approximation.It is found that the results considering resonance structures are significantly different from those of the distorted wave approach.Furthermore,we propose a new empirical formula with a correction term to take into account the effect of resonances for electron-impact widths over a relatively wide range of plasma conditions.The corresponding fitting parameters of the new empirical formula for all 47 calculated transitions are also given with an estimated accuracy within 1%,which should be convenient for practical applications.The dataset that supported the findings of this study is available in Science Data Bank,with the link https://doi.org/10.57760/sciencedb.j00113.00101.

“入世”的基本战略和主要对策

China will enter WTO in the near future. The great shock to uncompleted reform and excessive protection firstly means challenges and opportunities. The way to deal with this situation is to regard entering WTO as the second reform and open. By upholding opening - door policy, we can stride forward towards internationalization and really merge into world market. By expending the reform, we can actively push forward marketization, and further improve system of enterprise, market construction and governmetnt’s function. All industries should take different strategies and pay much attention to improving core technology and international competitiveness.

Statistical Properties of a Ring Laser with Injected SIgnal and Backscattering

The statistical properties of a homogeneously broadened ring laser with an injected signal are investigated and the normalized two-mode intensity auto- and cross-correlation functions are calculated by a full saturation laser theory with backscattering. The theoretical predictions are in good agreement with the experimental measurements.Further investigation reveals that the backscattering can reduce the fluctuations in the system while the full saturation effect plays a major role when the laser is operated above threshold. It is also quite important to notice that the injected signal can drive the weak mode from incoherent light to coherent light.

Effect of inhomogeneous broadening on threshold current of GaN-based green laser diodes

The inhomogeneous broadening parameter and the internal loss of green LDs are determined by experiments and theoretical fitting. It is found that the inhomogeneous broadening plays an important role on the threshold current density of green LDs. The green LD with large inhomogeneous broadening even cannot lase. Therefore, reducing inhomogeneous broadening is a key issue to improve the performance of green LDs.

Effect of spontaneously generated coherence on inversionless lasing gain in an atomic system with Doppler broadening

We have studied the effect of the spontaneously generated coherence （SGC） on gain of lasing without inversion （LWI） in a closed three-level A-type atomic system with Doppler broadening. It is shown that, regardless of the driving and probe fields being co- or counter-propagating, at a suitable value of the Doppler width, we can obtain a much larger LWI gain with SGC than that without SGC; and the region of the LWI gain spectrum with SGC is obviously larger than that without SGC. When the Doppler width takes a constant value, the gain does not monotonically decrease or increase with increasing strength of SGC, the largest LWI gain can be obtained by adjusting strength of SGC. Generally speaking, the co-propagating probe and driving fields is favourable to obtain a larger LWI gain.

Influence of low-temperature sulfidation on the structure of ZnS thin films

ZnS thin films were prepared by sulfuring zinc thin films at different sulfuration temperatures. The crystal structure,surface morphology, defects, and optical properties of the thin films were characterized by x-ray diffraction(XRD), scanning electron microscopy(SEM), positron annihilation Doppler broadening, and UV-Vis spectrophotometer, respectively.It was found that the(200)-plane preferred orientation of the ZnS thin films changed to(111)-plane with increasing sulfidation temperature. Moreover, a number of large holes were generated at 420?C and eliminated at 440?C. The concentration of defects was lowest when the sulfuration temperature was 440?C. The optical transmission of all samples was maintained at 60%–80% in the wavelength range of 400 nm–800 nm, and the band energy of the ZnS thin films was approximately3.5 e V for all treatment temperatures except 430?C.

Burnup analysis for the pebble-bed fluoride-salt-cooled high-temperature reactor based on the energy-dependent elastic scattering cross-sectional model

To carry out accurate burnup calculations for a pebble-bed fluoride-salt-cooled high-temperature reactor,the energy-dependent cross-sectional model based on the Doppler broadening rejection correction method has been proposed to develop the energy-dependent elastic scattering cross-sectional model. In this study, the Monte Carlo continuous energy code PSG2/Serpent was used to examine the difference between the constant cross-sectional model and the energy-dependent cross-sectional model during burnup. For the cases analyzed in this study,numerical simulations show that the multiplication coefficient was improved by hundreds pcm and ^(239)Pu concentration was improved by approximately 1–2% during burnup when the energy-dependent elastic scattering crosssectional model is considered.

Nonlinear compression of picosecond chirped pulse from thin-disk amplifier system through a gas-filled hollow-core fiber

We theoretically study the nonlinear compression of a 20-rnJ, 1030-nm picosecond chirped pulse from the thin-disk amplifier in a krypton gas-filled hollow-core fiber. The chirp from the thin-disk amplifier system has little influence on the initial pulse, however, it shows an effect on the nonlinear compression in hollow-core fiber. We use a large diameter hollow waveguide to restrict undesirable nonlinear effects such as ionization; on the other hand, we employ suitable gas pressure and fiber length to promise enough spectral broadening; with 600-μm, 6-bar （1 bar = 105 Pa）, 1.8-m hollow fiber, we obtain 31.5-fs pulse. Moreover, we calculate and discuss the optimal fiber lengths and gas pressures with different initial durations induced by different grating compression angles for reaching a given bandwidth. These results are meaningful for a compression scheme from picoseconds to femtoseconds.

Atomic Emission Spectra Diagnosis and Electron Density Measurement of Semiconductor Bridge (SCB) Plasma

Emission spectra of a semiconductor bridge （SCB） plasma in a visible range was studied in air. The electron density was measured in a conventional way from the broadening of the Al Ⅰ 394.4 nm Stark width. Based on the Saha equation, a system for recording the intensity of Si Ⅰ 390.5 nm and Si Ⅱ 413.1 nm was designed. With this technique, the SCB plasma electron density was measured well and accurately. Moreover, the electron density distribution Vs time was acquired from one SCB discharge. The individual result from the broadening of the Al Ⅰ 394.4 nm Stark width and Saha equation was all in the range of 1015 cm^-3 to 1016 cm^-3. Finally the presumption of the local thermodynamic equilibrium （LTE） condition was validated.

Autler–Townes spectroscopy of high-lying state by phase conjugate six-wave mixing

An Autler-Townes（AT） spectroscopy based on phase conjugate six-wave mixing（SWM） is proposed to detect AT doublet of high-lying state in a Doppler-broadened cascade four-level system.It is found that the SWM spectrum is dependent strongly on the ratios between the magnitudes of the wave vectors.We discuss how the Doppler broadening affects the SWM spectrum from a time-domain viewpoint and find that,due the atomic motion,the atomic polarizations acquire different phases for atoms with different velocities as time evolves.The Doppler free SWM spectrum can be obtained only when the atomic polarization can be rephasing again at certain time after the interactions of all the incident fields.

Effects of 946-nm thermal shift and broadening on Nd^(3+):YAG laser performance

Spectroscopic properties of flashlamp pumped Nd^3＋：YAG laser are studied as a function of temperature in a range from-30℃ to 60℃. The spectral width and shift of quasi three-level 946.0-nm inter-Stark emission within the respective intermanifold transitions of ^4F3/2→^4I9/2are investigated. The 946.0-nm line shifts toward the shorter wavelength and broadens. In addition, the threshold power and slope efficiency of the 946.0-nm laser line are quantified with temperature.The lower the temperature, the lower the threshold power is and the higher the slope efficiency of the 946.0-nm laser line is,thus the higher the laser output is. This phenomenon is attributed to the ion-phonon interaction and the thermal population in the ground state.