To explore the kinetic adsorption under continuous and nonequilibrium states, an integration of continuous measurement and adsorption platform kinetics method was proposed, which was initially called the ICM-AP kineti...To explore the kinetic adsorption under continuous and nonequilibrium states, an integration of continuous measurement and adsorption platform kinetics method was proposed, which was initially called the ICM-AP kinetics method, and a corresponding kinetic adsorption experimental method was developed. Adsorption experiments of europium(Eu) on Ca-bentonite,Na-bentonite, and the D231 cation exchange resin were performed using the ICM-AP kinetics method and continuous measurements. Because the kinetic experimental results observed in this study were different from those of traditional batch adsorption data, pseudo-first-order or pseudo-second-order kinetic models were unsuitable for fitting the experimental data.Hence, a liquid membrane diffusion(LMD) model was developed based on the assumption of simultaneous adsorption/desorption to discuss the mechanism of kinetic adsorption. The kinetic adsorption mechanism was also studied by using XPS.The results indicated that the proposed adsorption model can fit the experimental data more suitably, and the adsorption/desorption behaviors of Eu on bentonite and the D231 resin were simultaneously observed, suggesting that the adsorption kinetics of Eu(Ⅲ) was mainly dominated by hydrated Eu(Ⅲ) ions on the liquid membrane.展开更多
To investigate the relationship between surface currents and wave distributions in typhoons,we took the Typhoon Talim in 2017 as a case,and found that the track of the typhoon winds up to 50 m/s was almost consistent ...To investigate the relationship between surface currents and wave distributions in typhoons,we took the Typhoon Talim in 2017 as a case,and found that the track of the typhoon winds up to 50 m/s was almost consistent with the Kuroshio track,particularly from September 13 to 16,2017.The surface current data,derived from the NCEP Climate Forecast System Version 2(CFSv2)from the National Center of Atmospheric Research(NCAR),revealed that the speed of the wind-induced current exceeded that of the Kuroshio in the region with the maximum wind speed.In this study,was utilized a third-generation numeric wave model,WAVEWATCH-Ⅲ(the latest version 5.16),developed by the National Oceanic and Atmospheric Administration(NOAA),to simulate the wave fields of Typhoon Talim using the European Centre for Medium-Range Weather Forecasts(ECMWF)reanalysis wind data in 0.125°×0.125°grid as the forcing field.We found that the root-mean-square error(RMSE)of the significant wave height(SWH)was 0.34 m when validated against measurements from altimeter Jason-2.In addition,we discovered that the SWH had a similar tendency to the change in the surface current speed that was approximately 0.5 m/s at the beginning of Typhoon Talim.However,the relationship became weak as the surface current speed was below 0.2 m/s.Our findings show that the distribution of typhoon waves is resulted from the interaction of surface current and the wind-sea portion of the wave system,since the distribution pattern of wind-sea is consistent with the surface current,and there is a weak relationship between surface current and swell.展开更多
基金This work was supported by the Natural Science Foundation of the Jiangxi Province,China(No.20202BABL203004)Opening Project of the State Key Laboratory of Nuclear Resources and Environment(East China University of Technology)(No.2022NRE23)Opening Project of the Jiangxi Province Key Laboratory of Polymer Micro/Nano Manufacturing and Devices(No.PMND202101).
文摘To explore the kinetic adsorption under continuous and nonequilibrium states, an integration of continuous measurement and adsorption platform kinetics method was proposed, which was initially called the ICM-AP kinetics method, and a corresponding kinetic adsorption experimental method was developed. Adsorption experiments of europium(Eu) on Ca-bentonite,Na-bentonite, and the D231 cation exchange resin were performed using the ICM-AP kinetics method and continuous measurements. Because the kinetic experimental results observed in this study were different from those of traditional batch adsorption data, pseudo-first-order or pseudo-second-order kinetic models were unsuitable for fitting the experimental data.Hence, a liquid membrane diffusion(LMD) model was developed based on the assumption of simultaneous adsorption/desorption to discuss the mechanism of kinetic adsorption. The kinetic adsorption mechanism was also studied by using XPS.The results indicated that the proposed adsorption model can fit the experimental data more suitably, and the adsorption/desorption behaviors of Eu on bentonite and the D231 resin were simultaneously observed, suggesting that the adsorption kinetics of Eu(Ⅲ) was mainly dominated by hydrated Eu(Ⅲ) ions on the liquid membrane.
基金Supported by the Fundamental Research Funds for Zhejiang Provincial Universities and Research Institutes(No.2019J00010)the National Key Research and Development Program of China(No.2017YFA0604901)+2 种基金the National Natural Science Foundation of China(Nos.41806005,41776183,41706206)the Public Welfare Technical Applied Research Project of Zhejiang Province of China(No.LGF19D060003)the Science and Technology Project of Zhoushan City(No.2019C21008)。
文摘To investigate the relationship between surface currents and wave distributions in typhoons,we took the Typhoon Talim in 2017 as a case,and found that the track of the typhoon winds up to 50 m/s was almost consistent with the Kuroshio track,particularly from September 13 to 16,2017.The surface current data,derived from the NCEP Climate Forecast System Version 2(CFSv2)from the National Center of Atmospheric Research(NCAR),revealed that the speed of the wind-induced current exceeded that of the Kuroshio in the region with the maximum wind speed.In this study,was utilized a third-generation numeric wave model,WAVEWATCH-Ⅲ(the latest version 5.16),developed by the National Oceanic and Atmospheric Administration(NOAA),to simulate the wave fields of Typhoon Talim using the European Centre for Medium-Range Weather Forecasts(ECMWF)reanalysis wind data in 0.125°×0.125°grid as the forcing field.We found that the root-mean-square error(RMSE)of the significant wave height(SWH)was 0.34 m when validated against measurements from altimeter Jason-2.In addition,we discovered that the SWH had a similar tendency to the change in the surface current speed that was approximately 0.5 m/s at the beginning of Typhoon Talim.However,the relationship became weak as the surface current speed was below 0.2 m/s.Our findings show that the distribution of typhoon waves is resulted from the interaction of surface current and the wind-sea portion of the wave system,since the distribution pattern of wind-sea is consistent with the surface current,and there is a weak relationship between surface current and swell.
