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Facies logging identification of intermediate-basic volcanic rocks in Huoshiling Formation of Songliao Basin
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作者 LI Yonggang YAN Bo 《Global Geology》 2024年第2期93-104,共12页
Volcanic oil and gas reservoirs are generally buried deep,which leads to a high whole-well coring cost,and the degree of development and size of reservoirs are controlled by volcanic facies.Therefore,accurately identi... Volcanic oil and gas reservoirs are generally buried deep,which leads to a high whole-well coring cost,and the degree of development and size of reservoirs are controlled by volcanic facies.Therefore,accurately identifying volcanic facies by logging curves not only provides the basis of volcanic reservoir prediction but also saves costs during exploration.The Songliao Basin is a‘fault-depression superimposed’composite basin with a typical binary filling structure.Abundant types of volcanic lithologies and facies are present in the Lishu fault depression.Volcanic activity is frequent during the sedimentary period of the Huoshiling Formation.Through systematic petrographic identification of the key exploratory well(SN165C)of the Lishu fault-depression,which is a whole-well core,it is found that the Huoshiling Formation in SN165C contains four facies and six subfacies,including the volcanic conduit facies(crypto explosive breccia subfacies),explosive facies(pyroclastic flow and thermal wave base subfacies),effusive facies(upper and lower subfacies),and volcanogenic sedimentary facies(pyroclastic sedimentary subfacies).Combining core,thin section,and logging data,the authors established identification markers and petrographic chart logging phases,and also interpreted the longitudinal variation in volcanic petro-graphic response characteristics to make the charts more applicable to this area's volcanic petrographic interpretation of the Huoshiling Formation.These charts can provide a basis for the further exploration and development of volcanic oil and gas in this area. 展开更多
关键词 Lishu fault-depression Huoshiling Formation volcanic lithofacies logging identification whole-coring well SN165c
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Data mining and well logging interpretation: application to a conglomerate reservoir 被引量:8
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作者 石宁 李洪奇 罗伟平 《Applied Geophysics》 SCIE CSCD 2015年第2期263-272,276,共11页
Data mining is the process of extracting implicit but potentially useful information from incomplete, noisy, and fuzzy data. Data mining offers excellent nonlinear modeling and self-organized learning, and it can play... Data mining is the process of extracting implicit but potentially useful information from incomplete, noisy, and fuzzy data. Data mining offers excellent nonlinear modeling and self-organized learning, and it can play a vital role in the interpretation of well logging data of complex reservoirs. We used data mining to identify the lithologies in a complex reservoir. The reservoir lithologies served as the classification task target and were identified using feature extraction, feature selection, and modeling of data streams. We used independent component analysis to extract information from well curves. We then used the branch-and- bound algorithm to look for the optimal feature subsets and eliminate redundant information. Finally, we used the C5.0 decision-tree algorithm to set up disaggregated models of the well logging curves. The modeling and actual logging data were in good agreement, showing the usefulness of data mining methods in complex reservoirs. 展开更多
关键词 Data mining well logging interpretation independent component analysis branch-and-bound algorithm c5.0 decision tree
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从废旧电池中回收二水磷酸铁再生LiFePO_(4)/C
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作者 陈显彪 梁爽 +6 位作者 代芳 刘嘉 刘伟昊 王帅 彭望 曾杰 张文华 《南昌工程学院学报》 CAS 2024年第4期84-89,共6页
使用酸浸—加热回流法从废旧磷酸铁锂电池中回收得到二水磷酸铁,将其作为原料并添加一定量的锂源和碳源,通过高温固相法再生了LiFePO_(4)/C,并研究了温度对再生LiFePO_(4)/C电化学性能的影响。首先采用酸浸—加热回流法对废旧磷酸铁锂... 使用酸浸—加热回流法从废旧磷酸铁锂电池中回收得到二水磷酸铁,将其作为原料并添加一定量的锂源和碳源,通过高温固相法再生了LiFePO_(4)/C,并研究了温度对再生LiFePO_(4)/C电化学性能的影响。首先采用酸浸—加热回流法对废旧磷酸铁锂正极片进行处理生成FePO_(4)·2H_(2)O,洗涤烘干后研磨得到FePO_(4)·2H_(2)O粉末,XRD表征和ICP测试结果显示回收得到的FePO_(4)·2H_(2)O结构完整、纯度较高。然后在FePO_(4)·2H_(2)O粉末中添加碳源,在高温下制备LiFePO_(4)/C材料,对其进行结构与形貌表征以及电化学测试,发现以葡萄糖为碳源、温度为700℃、葡萄糖量为理论生成磷酸铁锂质量的17%时再生的LiFePO_(4)/C电化学性能最佳,0.3 C倍率下再生的LiFePO_(4)/C首周放电比容量可达141.8 mAh/g,循环100周后容量保持率可维持在94.3%。通过与商用LiFePO_(4)/C进行电化学性能对比,进一步验证了该工艺再生的LiFePO_(4)/C有着优良的电化学性能。 展开更多
关键词 废旧磷酸铁锂电池 FePo_(4)·2H_(2)o 高温固相法 再生LiFePo_(4)/c
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晶粒尺寸对界面含Cr-O-C防黏层Cu/Ni复合体拉伸性能的影响
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作者 杨光 胡正晨 +1 位作者 惠越 陈菊 《中国有色金属学报》 EI CAS CSCD 北大核心 2024年第5期1599-1610,共12页
通过分子动力学方法研究含Cr-O-C防黏层的具有不同晶粒尺寸的Cu/Ni复合体的拉伸变形。结果表明:当Cu/Ni复合体的晶粒尺寸大于12 nm时,不论界面不含Cr、O和C原子或含有定量Cr、O和C原子,复合体的屈服强度随着晶粒尺寸的减小呈现增大趋势... 通过分子动力学方法研究含Cr-O-C防黏层的具有不同晶粒尺寸的Cu/Ni复合体的拉伸变形。结果表明:当Cu/Ni复合体的晶粒尺寸大于12 nm时,不论界面不含Cr、O和C原子或含有定量Cr、O和C原子,复合体的屈服强度随着晶粒尺寸的减小呈现增大趋势,符合细晶强化规律,晶粒塑性变形主要受晶体内部的位错滑移控制,最大应力增加9.52%;当晶粒尺寸小于12 nm时,由于晶界所占比例的增加,拉伸过程的塑性变形更多受晶界变形控制,屈服强度下降。Cr-O-C界面弱化了Cu/Ni复合体的强度,随着界面上Cr、O和C原子数量的增加,Cu/Ni复合体的抗拉强度随之降低,最大应力下降56.40%,Cu/Ni复合体内部的位错数量也随之降低,转移到Ni表面的Cu原子数量随之减少。 展开更多
关键词 分子动力学 晶粒尺寸 cu/Ni复合体 cr-o-c防黏层 拉伸性能
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ControlLogix PLC及其分布式I/O在水电厂监控系统中的应用 被引量:3
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作者 靳祥林 纪菁 《智慧工厂》 2016年第8期68-70,87,共4页
ControlLogix PLC是美国罗克韦尔公司推出的大型可编程控制器,本文介绍了该PLC及其分布式I/O在水电厂监控系统中的应用。在满足对辅助设备的监控要求下,通过使用分布式I/O,简化了监控系统网络结构,减少了监控系统和辅助控制系统之间的... ControlLogix PLC是美国罗克韦尔公司推出的大型可编程控制器,本文介绍了该PLC及其分布式I/O在水电厂监控系统中的应用。在满足对辅助设备的监控要求下,通过使用分布式I/O,简化了监控系统网络结构,减少了监控系统和辅助控制系统之间的转接设备,节约了建设成本,减轻了维护工作量。 展开更多
关键词 监控系统 PLc 分布式I/o
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C/O与C/H测井响应的数值模拟对比研究
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作者 李巽 吴文圣 董夺 《核技术》 EI CAS CSCD 北大核心 2024年第4期90-96,共7页
准确地测定地层中含油饱和度是储层岩石物理评价的重要组成部分,C/H测井和C/O测井都是计算低矿化度储层含油饱和度的主要方法。为了对比C/H与C/O两种方法的测井响应效果,采用蒙特卡罗模拟方法,应用球状模型和参考Halliburton公司的C/O... 准确地测定地层中含油饱和度是储层岩石物理评价的重要组成部分,C/H测井和C/O测井都是计算低矿化度储层含油饱和度的主要方法。为了对比C/H与C/O两种方法的测井响应效果,采用蒙特卡罗模拟方法,应用球状模型和参考Halliburton公司的C/O测井仪器储层性能检测仪(Reservoir Performance Monitor,RPM)所设置的模型进行数值模拟。计算得到了不同地质参数和孔隙结构下地层原子特征能窗的γ光子计数,分析了C/O和C/H与孔隙度和饱和度的关系以及对饱和度的灵敏度。计算结果表明:在套管井中C/H和C/O与孔隙度和饱和度具有相同的关系,都可以用于井下的饱和度计算。但是C/H受井眼环境影响更大,对饱和度的灵敏度更低,不适用于复杂井眼的饱和度计算。 展开更多
关键词 c/o测井 c/H测井 测井响应 计算模型
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内蒙古根河三道桥铅锌银矿床C-H-O-S同位素和U-Pb定年研究及其意义 被引量:1
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作者 关强兵 刘俊辰 +5 位作者 王义天 胡乔青 何猛 段志辉 党顺安 史新 《矿产勘查》 2024年第4期526-539,共14页
内蒙古根河三道桥大型铅锌银矿床位于大兴安岭得尔布干成矿带中北段,矿体主要呈脉状赋存于火山岩地层中。氢氧同位素研究表明,成矿期石英和绢云母的δD值变化范围为-149.1‰~-156.7‰,δ^(18)OH_(2)O值变化范围为-13.6‰~3.4‰;成矿后... 内蒙古根河三道桥大型铅锌银矿床位于大兴安岭得尔布干成矿带中北段,矿体主要呈脉状赋存于火山岩地层中。氢氧同位素研究表明,成矿期石英和绢云母的δD值变化范围为-149.1‰~-156.7‰,δ^(18)OH_(2)O值变化范围为-13.6‰~3.4‰;成矿后期石英δD值变化范围为-131.9‰~-147.7‰,δ^(18)OH_(2)O值变化范围为-16.5‰~-18.2‰。碳同位素分析结果表明,与矿化有关的方解石δ^(13)C值变化范围为-1.8‰~-3.1‰,δ^(18)O值变化范围为5.3‰~8.6‰。原位S同位素分析结果表明,硫化物的δ^(34)S值变化范围为2.3‰~5.6‰,与其西南侧下护林矽卡岩型铅锌银矿床中的硫化物的δ^(34)S值(1.2‰~5.9‰)基本一致。上述同位素组成特征指示成矿物质主要来源于岩浆热液,在上升到地壳浅部时有一定量的大气降水混入。锆石U-Pb年代学研究表明,矿化的闪长玢岩脉年龄为(136.0±0.7)Ma(MSWD=0.44);未矿化、穿切硫化物微细脉的闪长玢岩脉的锆石U-Pb年龄为(120.8±0.6)Ma(MSWD=0.49)。结合前人相关研究进展,认为三道桥铅锌银矿床形成于136.0~120.8 Ma期间(早白垩世),为伸展构造背景下与浅成侵入岩有关的中温热液型铅锌银矿床。 展开更多
关键词 c-H-o-S同位素 锆石U-Pb定年 成矿物质来源 三道桥铅锌银矿床 内蒙古
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基于Cr-O-C钝化层改变多晶Cu表面能和表层位错的脱模力与脱模精度
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作者 田振岐 杨光 +1 位作者 陈菊 李波 《中国表面工程》 EI CAS CSCD 北大核心 2024年第1期205-215,共11页
Cr-O-C钝化层可以提高精密电铸脱模精度,但Cr-O-C钝化层对基底表面的钝化规律和对表层的影响尚未清楚。利用分子动力学方法,在多晶Cu表面沉积离散的Cr、O和C原子,获得不同比例和数量的Cr-O-C钝化层。计算结果表明,不同比例的Cr、O和C原... Cr-O-C钝化层可以提高精密电铸脱模精度,但Cr-O-C钝化层对基底表面的钝化规律和对表层的影响尚未清楚。利用分子动力学方法,在多晶Cu表面沉积离散的Cr、O和C原子,获得不同比例和数量的Cr-O-C钝化层。计算结果表明,不同比例的Cr、O和C原子均可以大幅降低多晶Cu的表面能;随着原子数量的增加,多晶Cu的表面能呈下降趋势;Cr-O-C钝化层增加了多晶Cu表层的位错密度;新增加的位错以Shockley位错为主;在一定沉积原子数量内,位错密度有极值。在多晶Cu表面电沉积不同密度的Cr、O和C原子,通过接触角测试验证了Cr-O-C钝化层降低多晶Cu表面能的结论。电沉积脱模强度和脱模表面粗糙度结果显示,随着沉积原子数的增加,脱模强度和脱模表面粗糙度均降低。研究结果可为利用离散Cr-O-C界面辅助精密电铸脱模提供一种解释。 展开更多
关键词 cr-o-c界面 多晶cu 表面能 位错 脱模 分子动力学
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单原子Ru_(1)-N_(x)/C(x=3,4)催化剂活化H_(2)、H_(2)O和CH_(3)OH的理论研究
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作者 张寅胜 苟进韬 +1 位作者 刘挺豪 杨华清 《化学研究与应用》 CAS 北大核心 2024年第10期173-178,共6页
在GGA-PBE/DNP水平下,构建了两种氮掺杂石墨烯负载Ru单原子催化剂,记作Ru_(1)-N_(x)/C(x=3,4)。在热力学上,Ru_(1)-N_(4)/C比Ru_(1)-N_(3)/C更稳定。研究了Ru_(1)-N_(x)/C(x=3,4)对H_(2)、H_(2)O和CH_(3)OH的活化性能。H_(2)、H_(2)O和C... 在GGA-PBE/DNP水平下,构建了两种氮掺杂石墨烯负载Ru单原子催化剂,记作Ru_(1)-N_(x)/C(x=3,4)。在热力学上,Ru_(1)-N_(4)/C比Ru_(1)-N_(3)/C更稳定。研究了Ru_(1)-N_(x)/C(x=3,4)对H_(2)、H_(2)O和CH_(3)OH的活化性能。H_(2)、H_(2)O和CH_(3)OH在Ru_(1)-N_(3)/C上的化学吸附比在Ru_(1)-N_(4)/C上的化学吸附更强。同时,在实验温度下,它们在Ru_(1)-N_(x)/C(x=3,4)上的解离均为吸能反应。在动力学上,Ru_(1)-N_(4)/C活化解离H_(2)、H_(2)O和CH_(3)OH的能力均强于Ru_(1)-N_(3)/C。在水溶液中,两种催化剂对H2的活化较H_(2)O更强。在甲醇溶液中,Ru_(1)-N_(3)/C对CH_(3)OH的活化强于对H_(2)的活化;Ru_(1)-N_(4)/C对H_(2)的活化强于对CH_(3)OH的活化。 展开更多
关键词 GGA-PBE Ru_(1)-N_(x)/c H_(2) H_(2)o cH_(3)oH 活化
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基于C#+OpenGL的多探头测井井筒三维成像软件研制与应用研究
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作者 李家骏 马焕英 +3 位作者 侯振永 吴晓龙 宋文广 郭海敏 《长江大学学报(自然科学版)》 2024年第2期101-109,共9页
基于油水、气水等多相流实验数据和图像资料,采用C#语言结合Tao框架OpenGL研发一套适用于MAPS阵列多探头测井(以下简称“MAPS测井”)仪器的井筒流体三维成像显示(COSL-MapsView)软件。该软件可实现测井数据的直接加载,快速精确直观显示... 基于油水、气水等多相流实验数据和图像资料,采用C#语言结合Tao框架OpenGL研发一套适用于MAPS阵列多探头测井(以下简称“MAPS测井”)仪器的井筒流体三维成像显示(COSL-MapsView)软件。该软件可实现测井数据的直接加载,快速精确直观显示井筒内油气水的分布情况。基于图像重构对MAPS测井仪器进行了适用性研究,表明MAPS测井在水平井和大斜度井中低流量情况下的分层流中具有良好的应用效果,在高流量分散流中应用效果不佳。经验证,该软件成像效果达到了国外同等水平,对海上油气田找堵水等工程作业具有指导意义。 展开更多
关键词 水平井 MAPS测井仪器 三维成像 c# oPENGL
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南秦岭柞水-山阳矿集区金盆梁金矿床成因——来自流体包裹体及C-H-O-S-Pb同位素的制约
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作者 葛战林 顾雪祥 +5 位作者 章永梅 高永宝 郝迪 郑艳荣 刘明 王辉 《矿床地质》 CAS CSCD 北大核心 2024年第4期877-898,共22页
金盆梁是南秦岭柞水-山阳矿集区勘查的一处微细浸染型金矿床,矿床成因与成矿机制尚不清楚。矿体产于上泥盆统桐峪寺组粉砂质板岩和钙质板岩中,以浸染状、脉状金锑矿化为主,成矿过程可划分为3个阶段:毒砂-黄铁矿-硅化阶段(Ⅰ)、石英-辉锑... 金盆梁是南秦岭柞水-山阳矿集区勘查的一处微细浸染型金矿床,矿床成因与成矿机制尚不清楚。矿体产于上泥盆统桐峪寺组粉砂质板岩和钙质板岩中,以浸染状、脉状金锑矿化为主,成矿过程可划分为3个阶段:毒砂-黄铁矿-硅化阶段(Ⅰ)、石英-辉锑矿-白铁矿±锑氧化物阶段(Ⅱ)和方解石-石英阶段(Ⅲ)。流体包裹体及C-H-O-S-Pb同位素研究结果显示,Ⅱ阶段主要为金锑矿化,以H_(2)O-NaCl两相包裹体占绝对优势,成矿流体属于中温(200~290℃)、低盐度(w(NaCl_(eq))为0~6.0%)、低密度(0.64~0.99 g/cm^(3))的H_(2)O-NaCl±CO_(2)体系,以循环大气降水为主。无矿化的Ⅲ阶段主要发育H_(2)O-NaCl两相包裹体,含少量CO_(2)-H_(2)O-NaCl±CH_(4)、纯CO_(2)±CH_(4)及含子晶多相包裹体,流体以中低温(140~280℃)、低盐度(w(NaCl_(eq))为2.0%~8.0%)、低密度(0.68~1.02 g/cm^(3))的富CO_(2)-H_(2)O-NaCl±CH_(4)体系为主,或存在少量高温、高盐度、高密度H_(2)O-NaCl体系的岩浆热液混入。硫化物δ^(34)S值为较大负值(−12.50‰~−10.20‰),Pb同位素组成具上地壳源铅特征,成矿物质主要来源于围岩地层。综合研究表明,金盆梁金矿的成因类型属于卡林型金矿,水-岩反应(围岩硫化作用)是金富集沉淀的主要机制。 展开更多
关键词 矿床成因 流体包裹体 c-H-o-S-Pb同位素 金盆梁金矿床 南秦岭
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应用屏栅电离室测量^(16)O(n,α)^(13)C反应的模拟研究
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作者 夏聪 胡益伟 +5 位作者 刘杰 邬泽鹏 白浩帆 任文凯 陈金象 张国辉 《现代应用物理》 2024年第2期52-60,76,共10页
基于Geant4建立了一套利用屏栅电离室测量^(16)O(n,α)^(13)C反应的模拟方法,能预测不同入射中子能量、不同屏栅电离室结构、不同工作气体和样品参数等实验条件下屏栅电离室测量到的阴极-阳极幅度2维谱。为了验证该模拟方法的可靠性,在... 基于Geant4建立了一套利用屏栅电离室测量^(16)O(n,α)^(13)C反应的模拟方法,能预测不同入射中子能量、不同屏栅电离室结构、不同工作气体和样品参数等实验条件下屏栅电离室测量到的阴极-阳极幅度2维谱。为了验证该模拟方法的可靠性,在北京大学4.5 MV静电加速器上开展了实验,实验所用的中子能量为5.06 MeV,工作气体为0.3 MPa的Ar与体积分数为3.45%CO 2组成的混合气体(其中的氧作为待测样品)。实验测得了屏栅电离室的阴极阳极幅度2维谱,且模拟与实验结果吻合较好。基于此模拟方法提出了一套实验条件的优化方案,可为下一步在宽能区精确测量^(16)O(n,α)^(13)C反应截面提供参考。 展开更多
关键词 ^(16)o(n α)^(13)c反应 GEANT4 屏栅电离室 阴极阳极幅度2维谱 截面测量
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氮掺杂及表面活性剂辅助Co-N@C催化剂的制备及催化加氢应用
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作者 戴玉玉 王千禧 +3 位作者 沈纪达 张骏 王亚权 严新焕 《浙江化工》 CAS 2024年第11期37-45,共9页
设计具有高稳定性和高催化活性的非贵金属纳米催化剂是催化加氢工业化的迫切需求,金属有机框架衍生形成的非贵金属纳米颗粒均匀分散在多孔碳网格中被认为是构筑高稳定性和高活性催化剂非常有效的方法。本文通过金属钴离子和含氮配体/含... 设计具有高稳定性和高催化活性的非贵金属纳米催化剂是催化加氢工业化的迫切需求,金属有机框架衍生形成的非贵金属纳米颗粒均匀分散在多孔碳网格中被认为是构筑高稳定性和高活性催化剂非常有效的方法。本文通过金属钴离子和含氮配体/含羧酸配体之间的络合作用,非离子型表面活性剂辅助制备获得钴基金属有机框架(Co MOF)前驱体,进一步高温衍生获得金属纳米颗粒均匀分布的Co-N@C催化剂,研究含氮配体和表面活性剂的用量对Co MOF形貌及相应催化活性的影响。Co-N@C催化剂应用于催化邻氯硝基苯的加氢还原表现出优异的活性和选择性,在80℃、2 MPa H2压力下,反应60 min,转化率为100%,选择性为99.9%。此外,该催化剂对其他含卤素、醛基等硝基苯类化合物亦显示出优异的催化活性和选择性。 展开更多
关键词 金属有机框架 co-N@c 邻氯硝基苯 催化加氢
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滇中九龙方解石矿床成因——来自方解石矿物化学、流体包裹体、C-O同位素组成和U-Pb年代学的证据
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作者 周红琳 魏爱英 +2 位作者 王维 张佳慧 薛传东 《岩石矿物学杂志》 CAS CSCD 北大核心 2024年第6期1431-1447,共17页
九龙方解石矿床位于扬子地台西南缘滇中古生代盆地北西部,是滇中地区迄今发现的唯一一个大型巨晶方解石矿床,其成因目前尚不明确。本文选取由矿体内至围岩依次出现的巨晶方解石矿石、白云石化带以及近矿灰岩中的团块状方解石为对象,在... 九龙方解石矿床位于扬子地台西南缘滇中古生代盆地北西部,是滇中地区迄今发现的唯一一个大型巨晶方解石矿床,其成因目前尚不明确。本文选取由矿体内至围岩依次出现的巨晶方解石矿石、白云石化带以及近矿灰岩中的团块状方解石为对象,在地质调查、岩相学观测的基础上,分别对不同分带的方解石及围岩进行了矿物化学、C-O同位素组成及流体包裹体分析,并开展了矿石方解石U-Pb定年。结果显示,九龙方解石矿床主要矿体顺层产出,部分以大脉状赋存于顺层及高角度切层的断裂带中,下二叠统茅口组(P_(1)m)中上部层位灰岩是主要赋矿围岩,NE-SW向文林复向斜两翼及次级的"穹-盆"构造过渡部位是有利的赋矿部位,热液交代充填成矿、构造控矿特点突出,属后生低温热液型矿床;成矿流体为Cl-Na·Ca型盆地卤水,成矿物质主要源自赋矿围岩和下伏地层的循环作用,并存在深部岩浆热液的贡献;温度变化小、成核速率缓慢、结晶时间长是巨晶方解石大规模成矿的主要机制;其成矿时代为36.0±4.0 Ma(始-渐新世)。因而,九龙方解石矿床的成矿是喜马拉雅期区域性盆地流体活动的产物,代表了新生代印度-欧亚大陆碰撞造山作用在滇中古生代盆地的远程响应。 展开更多
关键词 矿物化学 c-o同位素组成 方解石U-Pb定年 后生热液成因 九龙方解石矿床 滇中古生代盆地
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桂西巴平石英矿床成因:来自流体包裹体、C-H-O同位素及稀土元素证据
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作者 何丽佳 阮青锋 +2 位作者 邱志惠 程诗渤 周子涵 《矿物岩石地球化学通报》 CAS CSCD 北大核心 2024年第2期326-342,共17页
为探讨碳酸盐岩区石英矿床的成因机理,对桂西巴平石英矿床中的水晶、脉石英、方解石和赋矿围岩(白云岩)进行了分析测试。流体包裹体岩相学及激光拉曼分析表明,水晶和脉石英中的流体包裹体主要为气液两相包裹体,可见富CO_(2)两相及三相... 为探讨碳酸盐岩区石英矿床的成因机理,对桂西巴平石英矿床中的水晶、脉石英、方解石和赋矿围岩(白云岩)进行了分析测试。流体包裹体岩相学及激光拉曼分析表明,水晶和脉石英中的流体包裹体主要为气液两相包裹体,可见富CO_(2)两相及三相包裹体,包裹体的液相成分为H_(2)O和CO_(2),气相成分为H_(2)O、CO_(2)和少量N_(2)。流体包裹体的均一温度为160~312℃,盐度为0.41%~6.16%NaCl_(eqv),属CO_(2)-H_(2)O-NaCl体系的中-低温、低盐度、低密度热液流体。水晶和脉石英的稀土元素配分模式呈轻稀土富集右倾型,具有明显的Eu、Tb、Ho、Yb负异常,推测其母岩浆流体是亏损Eu的,成矿流体与深部的隐伏花岗岩体有关。方解石的稀土元素配分模式呈明显右倾型式,具有轻稀土富集和轻微的Eu正异常,指示其形成于氧化环境,白云岩的Ce负异常指示其形成于低温氧化环境。水晶及脉石英的δD_(SMOW)和δ^(18)OH_(2)O分别为-75.5‰~-54.1‰和5.72‰~7.06‰,指示成矿流体主要为岩浆热液;方解石及白云岩的δ^(13)CPDB分别为-3.92‰~-3.35‰和2.41‰~3.59‰,δ^(18)O_(SMOW)分别为18.84‰~19.13‰和23.25‰~27.45‰,表明方解石的CO_(2)主要来源于围岩的海相碳酸盐岩。成矿过程中深部岩浆热液沿深大断裂侵入,富Si流体沿断裂、裂隙运移过程中与碳酸盐岩围岩发生水岩相互作用,大量的CO_(2)进入到热液中。成矿环境的pH值、压力的降低及流体沸腾作用促使方解石和SiO_(2)开始沉淀,并随着温度和压力持续降低,H_(4)SiO_(4)溶解度不断降低,SiO_(2)大量沉淀,最后形成石英矿床。 展开更多
关键词 流体包裹体 c-H-o同位素 成矿流体 石英矿床 矿床成因
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Hydrogeochemical and isotopic assessment of the origin of NO_(3)^(−)and N-NH_(3)contents in the aquifer located in a closed lacustrine volcano-sedimentary basin in the metropolitan area of Mexico City
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作者 Jose Ivan Morales-Arredondo Maria Aurora Armienta Hernandez +1 位作者 Joel Edmundo Ortega-Gutierrez Elisa Cuellar Ramirez 《Acta Geochimica》 EI CAS CSCD 2024年第4期719-736,共18页
To explain the presence and spatial distribution of NO_(3)^(−)and N-NH_(3)in the Aquifer of the Metropolitan Area of Mexico City(AMAMC),a hydrogeochemical and isotopic analysis using^(13)C DIC(as well as the stable is... To explain the presence and spatial distribution of NO_(3)^(−)and N-NH_(3)in the Aquifer of the Metropolitan Area of Mexico City(AMAMC),a hydrogeochemical and isotopic analysis using^(13)C DIC(as well as the stable isotopes^(18)O and^(2)H)in groundwater was conducted.This aquifer is located in an old closed lacustrine volcano-sedimentary basin;some wells hosted in the semi-confined zone contain high N-NH_(3)concentrations,while others present NO_(3)^(−)contents in the recharge zones(hosted in an oxidizing environment).In this study,a change in the isotopic signature(primarily in^(18)O and^(2)H)was observed from the recharge zones to the basin center in some of the wells with high NO_(3)^(−)concentrations,this behavior can be attributed to evaporation during the incorporation of recently infiltrated water.In addition,the results for^(13)C(along with ^(2) H)in wells with the highest N-NH_(3)concentrations exhibited an atypically broad range of values.Results indicated the occurrence of hydrogeochemical and/or biochemical processes in the aquifer(in an oxidizing or reducing environment),such as organic degradation,bacterial decomposition(primarily in the ancient Lake Texcoco and which acts as a natural sink for carbon,nitrogen,sulfur,and phosphorus),besides rock weathering and dissolution,which may be responsible for a very marked isotopic modification of the^(13)C(and,to a lesser extent,2 H).Methanotrophic bacterial activity and methanogenic activity may be related to N-NH_(3)removal processes by oxidation and residual water incorporation respectively,whereas the increase in the NO_(3)^(−)content in some wells is due to the recent contribution of poor-quality water due to contamination. 展开更多
关键词 18 o and^(13)c isotopes Iron Hydrogeochemical processes NITRATE Nitrogen species
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C6H10S2O联合Nano-CaCO3对铅染毒小鼠海马学习记忆功能的影响
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作者 魏凯威 赵霜 董海影 《中文科技期刊数据库(引文版)医药卫生》 2024年第10期0185-0188,共4页
评价 C6H10S2O联合Nano-CaCO3对铅染毒小鼠的海马学习记忆功能产生的影响,以指导铅染毒相关问题的处理。方法 选择齐齐哈尔医学院动物实验中心提供的20-30g 健康雌性 KM 小鼠,健康清洁级,分为正常对照组、模型对照组、C6H10S2O 组、Nano... 评价 C6H10S2O联合Nano-CaCO3对铅染毒小鼠的海马学习记忆功能产生的影响,以指导铅染毒相关问题的处理。方法 选择齐齐哈尔医学院动物实验中心提供的20-30g 健康雌性 KM 小鼠,健康清洁级,分为正常对照组、模型对照组、C6H10S2O 组、Nano-CaCO3组、联合治疗组,其中后四组均为铅染毒模型。五组的饲养条件相同,方法 /剂量建立铅染毒模型,提供对应治疗方法,通过评估体质量与血液中铅元素含量、NO含量和ACHE活力、水迷宫、新物体识别测量的结果,判断治疗效果。结果 与空白对照组比较,模型对照组的体质量显著降低(P<0.05),血铅含量显著增加(P<0.05);与模型对照组比较,C6H10S2O组和联合治疗组小鼠的体质量显著提高(P<0.05),而血铅含量仅在联合治疗组显著减少(P<0.05);其他三组的体质量和血铅含量均无统计学差异(P>0.05)。与模型对照组比较,联合治疗组的跨越隐匿平台次数和平台象限游泳路程显著增加(P<0.05);与Nano-CaCO3组比较,联合治疗组的跨越隐匿平台次数和平台象限游泳路程也显著增加(P<0.05)。五组在NO含量和ACHE活力、认知指数方面的对比,差异均不存在统计学意义(P>0.05)。结论 C6H10S2O联合Nano-CaCO3可以减少铅含量,提高体质量,对空间学习能力有一定影响,但对认知能力、学习记忆能力不存在显著影响。 展开更多
关键词 铅染毒小鼠 c6H10S2o NANo-cAco3 海马学习记忆功能
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A Study of the Comets with Large Perihelion Distances C/2019 L3(ATLAS)and C/2019 O3(Palomar)
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作者 Alberto S.Betzler 《Research in Astronomy and Astrophysics》 SCIE CAS CSCD 2024年第9期199-213,共15页
This work analyzes the photometric data of the Oort spike comets C/2019 L3(ATLAS)and C/2019 O3(Palomar)obtained between 2016 and 2023 by the ATLAS network and the Belgian Olmen Observatory.The comets Palomar and ATLAS... This work analyzes the photometric data of the Oort spike comets C/2019 L3(ATLAS)and C/2019 O3(Palomar)obtained between 2016 and 2023 by the ATLAS network and the Belgian Olmen Observatory.The comets Palomar and ATLAS have a typical and unusually high activity level,respectively,based on the Afρparameter corrected to phase angle zero at perihelion.The absolute magnitude of comets ATLAS and Palomar in the o-band is 4.71±0.05 and 4.16±0.02 respectively.The cometary activity of comets ATLAS and Palomar probably began at r>13 au before perihelion and will end at r>14 au after perihelion,which means that they could remain active until the second half of 2026.The nucleus of comet ATLAS has a minimum radius of 7.9 km,and the nucleus of comet Palomar could be a little larger.The c-o colors of the comets ATLAS and Palomar are redder and bluer,respectively,at perihelion than the solar twin YBP 1194.These comets showed a bluish trend in the coma color with decreasing heliocentric distance.Comet Palomar probably had two outbursts after its perihelion,each releasing about 10^(8)kg of dust.The slopes of the photometric profile of the comae of these comets were between 1and 1.5,indicating a steady state during the observation campaign. 展开更多
关键词 individual c/2019 L3(ATLAS) c/2019 o3(Palomar) techniques:photometric methods:data analysis
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Geology and Isotope Geochemistry of the Yinchanggou-Qiluogou Pb-Zn Deposit,Sichuan Province,Southwest China 被引量:5
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作者 LI Bo ZHOU Jiaxi +2 位作者 LI Yingshu CHEN Aibing WANG Ruixue 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2016年第5期1768-1779,共12页
The Yinchanggou-Qiluogou Pb-Zn deposit,located in the western Yangtze Block,southwest China,is hosted by the Upper Sinian Dengying Formation dolostone.Ore bodies occur in the Qiluogou anticline and the NS-and NNW-tren... The Yinchanggou-Qiluogou Pb-Zn deposit,located in the western Yangtze Block,southwest China,is hosted by the Upper Sinian Dengying Formation dolostone.Ore bodies occur in the Qiluogou anticline and the NS-and NNW-trending faults.Sulfide ores mainly consist of sphalerite,pyrite,galena and calcite,with subordinate dolomite and quartz.Seventeen ore bodies have been discovered to date and they have a combined 1.0 million tons of sulfide ores with average grades of 2.27wt%Zn and 6.89wt%Pb.The δD(H2O-SMOW) and δ18O(H2O-SMOW) values of fluid inclusions in quartz and calcite samples range from-68.9‰ to-48.7‰ and 7.3‰ to 15.9‰,respectively,suggesting that H2O in the hydrothermal fluids sourced from metamorphic water.Calcite samples have δ13C(PDB) values ranging from-6.2‰ to-4.1‰ and δ18O(SMOW) values ranging from 15.1‰ to 17.4‰,indicating C and O in the hydrothermal fluids likely derived from a mixed source of metamorphic fluids and the host carbonates.The δ34S(CDT) values of sulfide minerals range from 5.5‰ to 20.3‰,suggesting that thermal chemical reduction of sulfate minerals in evaporates were the most probable source of S in the hydrothermal fluids.The 206Pb/204Pb,207Pb/204Pb and 208Pb/204Pb ratios of sulfide minerals fall in the range of 18.11 to 18.40,15.66 to 15.76 and 38.25 to 38.88,respectively.The Pb isotopic data of the studied deposit plot near the upper crust Pb evolution curve and overlap with the age-corrected Proterozoic basement rocks and the Upper Sinian Dengying Formation hosting dolostone.This indicates that the Pb originated from a mixed source of the basement metamorphic rocks and the ore-hosting carbonate rocks.The ore geology and C-H-O-S-Pb isotopic data suggest that the YinchanggouQiluogou deposit is an unusual carbonate-hosted,strata-bound and epigenetic deposit that derived ore-forming materials from a mixed source of the underlying Porterozoic basements and the Sinian hosting carbonates. 展开更多
关键词 c-H-o-S-Pb isotopes source of ore-forming fluids and metals the Yinchanggou-QiluogouPb-Zn deposit southwest china
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Genesis of the Weiquan Ag-Polymetallic Deposit in East Tianshan, China: Evidence from Zircon U-Pb Geochronology and C-H-O-S-Pb Isotope Systematics 被引量:3
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作者 DING Hui GE Wensheng +4 位作者 DONG Lianhui ZHANG Liangliang CHEN Xiaodong LIU Yan NIE Junjie 《Acta Geologica Sinica(English Edition)》 CAS CSCD 2018年第3期1100-1122,共23页
The Weiquan Ag-polymetallic deposit is located on the southern margin of the Central Asian Orogenic Belt and in the western segment of the Aqishan-Yamansu arc belt in East Tianshan,northwestern China. Its orebodies, c... The Weiquan Ag-polymetallic deposit is located on the southern margin of the Central Asian Orogenic Belt and in the western segment of the Aqishan-Yamansu arc belt in East Tianshan,northwestern China. Its orebodies, controlled by faults, occur in the lower Carboniferous volcanosedimentary rocks of the Yamansu Formation as irregular veins and lenses. Four stages of mineralization have been recognized on the basis of mineral assemblages, ore fabrics, and crosscutting relationships among the ore veins. Stage I is the skarn stage(garnet + pyroxene), Stage Ⅱ is the retrograde alteration stage(epidote + chlorite + magnetite ± hematite 士 actinolite ± quartz),Stage Ⅲ is the sulfide stage(Ag and Bi minerals + pyrite + chalcopyrite + galena + sphalerite + quartz ± calcite ± tetrahedrite),and Stage IV is the carbonate stage(quartz + calcite ± pyrite). Skarnization,silicification, carbonatization,epidotization,chloritization, sericitization, and actinolitization are the principal types of hydrothermal alteration. LAICP-MS U-Pb dating yielded ages of 326.5±4.5 and 298.5±1.5 Ma for zircons from the tuff and diorite porphyry, respectively. Given that the tuff is wall rock and that the orebodies are cut by a late diorite porphyry dike, the ages of the tuff and the diorite porphyry provide lower and upper time limits on the age of ore formation. The δ13C values of the calcite samples range from-2.5‰ to 2.3‰, the δ18OH2 Oand δDVSMOWvalues of the sulfide stage(Stage Ⅲ) vary from 1.1‰ to 5.2‰ and-111.7‰ to-66.1‰, respectively,and the δ13C, δ18OH2 Oand δDV-SMOWvalues of calcite in one Stage IV sample are 1.5‰,-0.3‰, and-115.6‰, respectively. Carbon, hydrogen, and oxygen isotopic compositions indicate that the ore-forming fluids evolved gradually from magmatic to meteoric sources. The δ34SV-CDTvalues of the sulfides have a large range from-6.9‰ to 1.4‰, with an average of-2.2‰, indicating a magmatic source, possibly with sedimentary contributions. The206Pb/204Pb,207Pb/204Pb, and208Pb/204Pb ratios of the sulfides are 17.9848-18.2785,15.5188-15.6536, and 37.8125-38.4650, respectively, and one whole-rock sample at Weiquan yields206Pb/204Pb,207Pb/204Pb, and208Pb/204Pb ratios of 18.2060, 15.5674, and 38.0511,respectively. Lead isotopic systems suggest that the ore-forming materials of the Weiquan deposit were derived from a mixed source involving mantle and crustal components. Based on geological features, zircon U-Pb dating, and C-H-OS-Pb isotopic data, it can be concluded that the Weiquan polymetallic deposit is a skarn type that formed in a tectonic setting spanning a period from subduction to post-collision. The ore materials were sourced from magmatic ore-forming fluids that mixed with components derived from host rocks during their ascent, and a gradual mixing with meteoric water took place in the later stages. 展开更多
关键词 zircon U-Pb geochronology c-H-o-S-Pb isotopes skarn-type Ag-polymetallic deposit Weiquan East Tianshan china
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