CMK-3 and C-FDU-15 samples were synthesized using hard-templating and evaporationinduced self-assembly(EISA)methods,respectively.The pore structures of CMK-3 and CFDU-15 as well as commercial activated carbon were cha...CMK-3 and C-FDU-15 samples were synthesized using hard-templating and evaporationinduced self-assembly(EISA)methods,respectively.The pore structures of CMK-3 and CFDU-15 as well as commercial activated carbon were characterized by means of X-ray diffraction,field emission scanning electron microscopy,transmission electron microscopy,and N2 adsorption–desorption.Adsorption of NO was investigated by means of thermogravimetric analysis,temperature-programmed desorption of NO+O2,and in situ diffuse reflectance Fourier transform infrared spectroscopy.The results show that the CMK-3 and C-FDU-15 materials possessed ordered and uniform structures.The coadsorption capacity of NO and O2 decreased in the sequence CMK-3(88.6 mg/g)>C-FDU-15(71.7 mg/g)>AC(25.3 mg/g).There were two main adsorption species on CMK-3 and CFDU-15:nitrite and nitrate.Nitrite is converted to nitrate easily.However,the adsorption species were more complex on AC,with nitrite being the main species.Moreover,CMK-3 and C-FDU-15 exhibit excellent regeneration efficiency compared with AC.The excellent NO adsorption performance of CMK-3 and C-FDU-15 was associated with their ordered mesoporous structures and high surface areas.The research provides more options for NO adsorption in the future.展开更多
To improve the removal capacity of NO + O_(2) effectively, the alkaline earth metal-doped order mesoporous carbon(A-C-FDU-15(0.001)(A = Mg, Ca, Sr and Ba)) and Mg-C-FDU-15( x)( x = 0.001-0.003) samples were prepared, ...To improve the removal capacity of NO + O_(2) effectively, the alkaline earth metal-doped order mesoporous carbon(A-C-FDU-15(0.001)(A = Mg, Ca, Sr and Ba)) and Mg-C-FDU-15( x)( x = 0.001-0.003) samples were prepared, and their physicochemical and NO + O_(2) adsorption properties were determined by means of various techniques. The results show that the sequence in(NO + O_(2)) adsorption performance was as follows: Mg-C-FDU-15(0.001)(93.2 mg/g) > Ca-C-FDU-15(0.001)(82.2 mg/g) > Sr-C-FDU-15(0.001)(76.1 mg/g) > Ba-C-FDU-15(0.001)(72.9 mg/g) > C-FDU-15(67.1 mg/g). Among all of the A-C-FDU-15(0.001) samples, Mg-C-FDU-15(0.001) possessed the highest(NO + O_(2)) adsorption capacity(106.2 mg/g). The species of alkaline earth metals and basic sites were important factors determining the adsorption of NO + O_(2) on the A-C-FDU-15( x) samples, and(NO + O_(2)) adsorption on the samples was mainly chemical adsorption. Combined with the results of(NO + O_(2))-temperatureprogrammed desorption((NO + O_(2))-TPD) and in situ diffused reflectance infrared Fourier transform spectroscopy(DRIFTS) characterization, we deduced that there were two main pathways of(NO + O_(2)) adsorption: one was first the conversion of NO and O_(2) to NO_(2) and then part of NO_(2) was converted to NO_(2)^(-) and NO_(3)^(-);and the other was the direct oxidation of NO to NO-2 and NO_(3)^(-).展开更多
基金supported by the National Natural Science Foundation of China(Nos.21277008 and 20777005)the National Key Research and Development Program of China(No.2017YFC0209905)
文摘CMK-3 and C-FDU-15 samples were synthesized using hard-templating and evaporationinduced self-assembly(EISA)methods,respectively.The pore structures of CMK-3 and CFDU-15 as well as commercial activated carbon were characterized by means of X-ray diffraction,field emission scanning electron microscopy,transmission electron microscopy,and N2 adsorption–desorption.Adsorption of NO was investigated by means of thermogravimetric analysis,temperature-programmed desorption of NO+O2,and in situ diffuse reflectance Fourier transform infrared spectroscopy.The results show that the CMK-3 and C-FDU-15 materials possessed ordered and uniform structures.The coadsorption capacity of NO and O2 decreased in the sequence CMK-3(88.6 mg/g)>C-FDU-15(71.7 mg/g)>AC(25.3 mg/g).There were two main adsorption species on CMK-3 and CFDU-15:nitrite and nitrate.Nitrite is converted to nitrate easily.However,the adsorption species were more complex on AC,with nitrite being the main species.Moreover,CMK-3 and C-FDU-15 exhibit excellent regeneration efficiency compared with AC.The excellent NO adsorption performance of CMK-3 and C-FDU-15 was associated with their ordered mesoporous structures and high surface areas.The research provides more options for NO adsorption in the future.
基金supported by the National Natural Science Foundation of China(Nos.21277008 and 20777005)the National Key Research and Development Program of China(No.2017YFC0209905)。
文摘To improve the removal capacity of NO + O_(2) effectively, the alkaline earth metal-doped order mesoporous carbon(A-C-FDU-15(0.001)(A = Mg, Ca, Sr and Ba)) and Mg-C-FDU-15( x)( x = 0.001-0.003) samples were prepared, and their physicochemical and NO + O_(2) adsorption properties were determined by means of various techniques. The results show that the sequence in(NO + O_(2)) adsorption performance was as follows: Mg-C-FDU-15(0.001)(93.2 mg/g) > Ca-C-FDU-15(0.001)(82.2 mg/g) > Sr-C-FDU-15(0.001)(76.1 mg/g) > Ba-C-FDU-15(0.001)(72.9 mg/g) > C-FDU-15(67.1 mg/g). Among all of the A-C-FDU-15(0.001) samples, Mg-C-FDU-15(0.001) possessed the highest(NO + O_(2)) adsorption capacity(106.2 mg/g). The species of alkaline earth metals and basic sites were important factors determining the adsorption of NO + O_(2) on the A-C-FDU-15( x) samples, and(NO + O_(2)) adsorption on the samples was mainly chemical adsorption. Combined with the results of(NO + O_(2))-temperatureprogrammed desorption((NO + O_(2))-TPD) and in situ diffused reflectance infrared Fourier transform spectroscopy(DRIFTS) characterization, we deduced that there were two main pathways of(NO + O_(2)) adsorption: one was first the conversion of NO and O_(2) to NO_(2) and then part of NO_(2) was converted to NO_(2)^(-) and NO_(3)^(-);and the other was the direct oxidation of NO to NO-2 and NO_(3)^(-).