The Weiquan Ag-polymetallic deposit is located on the southern margin of the Central Asian Orogenic Belt and in the western segment of the Aqishan-Yamansu arc belt in East Tianshan,northwestern China. Its orebodies, c...The Weiquan Ag-polymetallic deposit is located on the southern margin of the Central Asian Orogenic Belt and in the western segment of the Aqishan-Yamansu arc belt in East Tianshan,northwestern China. Its orebodies, controlled by faults, occur in the lower Carboniferous volcanosedimentary rocks of the Yamansu Formation as irregular veins and lenses. Four stages of mineralization have been recognized on the basis of mineral assemblages, ore fabrics, and crosscutting relationships among the ore veins. Stage I is the skarn stage(garnet + pyroxene), Stage Ⅱ is the retrograde alteration stage(epidote + chlorite + magnetite ± hematite 士 actinolite ± quartz),Stage Ⅲ is the sulfide stage(Ag and Bi minerals + pyrite + chalcopyrite + galena + sphalerite + quartz ± calcite ± tetrahedrite),and Stage IV is the carbonate stage(quartz + calcite ± pyrite). Skarnization,silicification, carbonatization,epidotization,chloritization, sericitization, and actinolitization are the principal types of hydrothermal alteration. LAICP-MS U-Pb dating yielded ages of 326.5±4.5 and 298.5±1.5 Ma for zircons from the tuff and diorite porphyry, respectively. Given that the tuff is wall rock and that the orebodies are cut by a late diorite porphyry dike, the ages of the tuff and the diorite porphyry provide lower and upper time limits on the age of ore formation. The δ13C values of the calcite samples range from-2.5‰ to 2.3‰, the δ18OH2 Oand δDVSMOWvalues of the sulfide stage(Stage Ⅲ) vary from 1.1‰ to 5.2‰ and-111.7‰ to-66.1‰, respectively,and the δ13C, δ18OH2 Oand δDV-SMOWvalues of calcite in one Stage IV sample are 1.5‰,-0.3‰, and-115.6‰, respectively. Carbon, hydrogen, and oxygen isotopic compositions indicate that the ore-forming fluids evolved gradually from magmatic to meteoric sources. The δ34SV-CDTvalues of the sulfides have a large range from-6.9‰ to 1.4‰, with an average of-2.2‰, indicating a magmatic source, possibly with sedimentary contributions. The206Pb/204Pb,207Pb/204Pb, and208Pb/204Pb ratios of the sulfides are 17.9848-18.2785,15.5188-15.6536, and 37.8125-38.4650, respectively, and one whole-rock sample at Weiquan yields206Pb/204Pb,207Pb/204Pb, and208Pb/204Pb ratios of 18.2060, 15.5674, and 38.0511,respectively. Lead isotopic systems suggest that the ore-forming materials of the Weiquan deposit were derived from a mixed source involving mantle and crustal components. Based on geological features, zircon U-Pb dating, and C-H-OS-Pb isotopic data, it can be concluded that the Weiquan polymetallic deposit is a skarn type that formed in a tectonic setting spanning a period from subduction to post-collision. The ore materials were sourced from magmatic ore-forming fluids that mixed with components derived from host rocks during their ascent, and a gradual mixing with meteoric water took place in the later stages.展开更多
This paper focuses on the effect of the later hydrotherm on uraniferous leucogranites and the stages of uranium mineralization. Here, we review C-H-O stable isotope, elements and fluid geochemistry of uraniferous leuc...This paper focuses on the effect of the later hydrotherm on uraniferous leucogranites and the stages of uranium mineralization. Here, we review C-H-O stable isotope, elements and fluid geochemistry of uraniferous leucogranites in Gaudeanmus, Namibia. The results show that there is significant increasing amount of rare earth element from non-mineralized to uraniferous leucogra-nites, indicating the synchronization of REE enrichment and uranium mineralization. Uranium enrichment may have close relations with Pb, Th, Co, Ni, REE in this region, so REE and U evidently exist homology. There are at least two stages of uranium mineralization by later hydrothermal alteration: firstly, due to magnatic residual high temperature and low salinity fluid, the temperature of main metallogenetic epoch ranges from 470°C to 530°C, salinity ranges from 3.55% to 9.60% NaCleq, and C, H, O stable isotope is -23‰ - -13.6‰, -53.3‰ - -46.4‰, 7.71‰ - 8.81‰, respectively. Secondly, due to superim-posed hydrothermal fluid, the temperature, salinity, and C, H, O stable isotope is 150°C - 220°C, 4.65% - 19.05% NaCleq, -20.3‰ -?-3.7‰, -64.7‰ - -53.6‰, 1.49‰ - 1.99‰, respectively. The fluid for reformation is derived from postmagmatic fluid, mixed with a number of meteoric water.展开更多
基金funded by the China Geological Survey (No. 1212011220731)
文摘The Weiquan Ag-polymetallic deposit is located on the southern margin of the Central Asian Orogenic Belt and in the western segment of the Aqishan-Yamansu arc belt in East Tianshan,northwestern China. Its orebodies, controlled by faults, occur in the lower Carboniferous volcanosedimentary rocks of the Yamansu Formation as irregular veins and lenses. Four stages of mineralization have been recognized on the basis of mineral assemblages, ore fabrics, and crosscutting relationships among the ore veins. Stage I is the skarn stage(garnet + pyroxene), Stage Ⅱ is the retrograde alteration stage(epidote + chlorite + magnetite ± hematite 士 actinolite ± quartz),Stage Ⅲ is the sulfide stage(Ag and Bi minerals + pyrite + chalcopyrite + galena + sphalerite + quartz ± calcite ± tetrahedrite),and Stage IV is the carbonate stage(quartz + calcite ± pyrite). Skarnization,silicification, carbonatization,epidotization,chloritization, sericitization, and actinolitization are the principal types of hydrothermal alteration. LAICP-MS U-Pb dating yielded ages of 326.5±4.5 and 298.5±1.5 Ma for zircons from the tuff and diorite porphyry, respectively. Given that the tuff is wall rock and that the orebodies are cut by a late diorite porphyry dike, the ages of the tuff and the diorite porphyry provide lower and upper time limits on the age of ore formation. The δ13C values of the calcite samples range from-2.5‰ to 2.3‰, the δ18OH2 Oand δDVSMOWvalues of the sulfide stage(Stage Ⅲ) vary from 1.1‰ to 5.2‰ and-111.7‰ to-66.1‰, respectively,and the δ13C, δ18OH2 Oand δDV-SMOWvalues of calcite in one Stage IV sample are 1.5‰,-0.3‰, and-115.6‰, respectively. Carbon, hydrogen, and oxygen isotopic compositions indicate that the ore-forming fluids evolved gradually from magmatic to meteoric sources. The δ34SV-CDTvalues of the sulfides have a large range from-6.9‰ to 1.4‰, with an average of-2.2‰, indicating a magmatic source, possibly with sedimentary contributions. The206Pb/204Pb,207Pb/204Pb, and208Pb/204Pb ratios of the sulfides are 17.9848-18.2785,15.5188-15.6536, and 37.8125-38.4650, respectively, and one whole-rock sample at Weiquan yields206Pb/204Pb,207Pb/204Pb, and208Pb/204Pb ratios of 18.2060, 15.5674, and 38.0511,respectively. Lead isotopic systems suggest that the ore-forming materials of the Weiquan deposit were derived from a mixed source involving mantle and crustal components. Based on geological features, zircon U-Pb dating, and C-H-OS-Pb isotopic data, it can be concluded that the Weiquan polymetallic deposit is a skarn type that formed in a tectonic setting spanning a period from subduction to post-collision. The ore materials were sourced from magmatic ore-forming fluids that mixed with components derived from host rocks during their ascent, and a gradual mixing with meteoric water took place in the later stages.
文摘This paper focuses on the effect of the later hydrotherm on uraniferous leucogranites and the stages of uranium mineralization. Here, we review C-H-O stable isotope, elements and fluid geochemistry of uraniferous leucogranites in Gaudeanmus, Namibia. The results show that there is significant increasing amount of rare earth element from non-mineralized to uraniferous leucogra-nites, indicating the synchronization of REE enrichment and uranium mineralization. Uranium enrichment may have close relations with Pb, Th, Co, Ni, REE in this region, so REE and U evidently exist homology. There are at least two stages of uranium mineralization by later hydrothermal alteration: firstly, due to magnatic residual high temperature and low salinity fluid, the temperature of main metallogenetic epoch ranges from 470°C to 530°C, salinity ranges from 3.55% to 9.60% NaCleq, and C, H, O stable isotope is -23‰ - -13.6‰, -53.3‰ - -46.4‰, 7.71‰ - 8.81‰, respectively. Secondly, due to superim-posed hydrothermal fluid, the temperature, salinity, and C, H, O stable isotope is 150°C - 220°C, 4.65% - 19.05% NaCleq, -20.3‰ -?-3.7‰, -64.7‰ - -53.6‰, 1.49‰ - 1.99‰, respectively. The fluid for reformation is derived from postmagmatic fluid, mixed with a number of meteoric water.
