In order to investigate the Magnetic Behavior of Compounds,the Variable —temperature magnetic susceptibility data of the title compounds(I:[Cu(C6H8O4)(C7H6N2)2H2O]∞) and(II:[Cu(C4H4O4)(C7H6N2)2 H2O]∞) were recorded...In order to investigate the Magnetic Behavior of Compounds,the Variable —temperature magnetic susceptibility data of the title compounds(I:[Cu(C6H8O4)(C7H6N2)2H2O]∞) and(II:[Cu(C4H4O4)(C7H6N2)2 H2O]∞) were recorded and discussed quantitatively based on to Ising’s model and particle swarm optimization(PSO).J≈-1.3cm-1,which shows that there is a weak interaction between two Cu(II) ions in the title compounds.It can be interpreted with Kahn’s approximate molecular orbital model.Room-temperature magnetic moment(2.150μB) is larger than pure-spin magnetic moment(1.732μB) and g is larger than ge(2.002),which comfirms the existence of spin-orbit coupling in the compounds.展开更多
Double perovskite-type catalysts including La2 CoMnO6 and La2 CuMnO6 are first evaluated for the effectiveness in removing volatile organic compounds（VOCs）, and single perovskites（La CoO3, LaMnO3, and La Cu O3） ar...Double perovskite-type catalysts including La2 CoMnO6 and La2 CuMnO6 are first evaluated for the effectiveness in removing volatile organic compounds（VOCs）, and single perovskites（La CoO3, LaMnO3, and La Cu O3） are also tested for comparison. All perovskites are tested with the gas hourly space velocity（GHSV） of 30,000 hr^-1, and the temperature range of100–600℃ for C7H8 removal. Experimental results indicate that double perovskites have better activity if compared with single perovskites. Especially, toluene（C7H8） can be completely oxidized to CO2 at 300℃ as La2 Co MnO6 is applied. Characterization of catalysts indicates that double perovskites own unique surface properties and are of higher amounts of lattice oxygen,leading to higher activity. Additionally, apparent activation energy of 68 k J/mol is calculated using Mars-van Krevelen model for C7 H8 oxidation with La2 Co Mn O6 as catalyst. For durability test, both La2 Co Mn O6 and La2 CuMnO6 maintain high C7 H8 removal efficiencies of 100% and98%, respectively, at 300℃ and 30,000 hr^-1, and they also show good resistance to CO2（5%） and H2 O（g）（5%） of the gas streams tested. For various VOCs including isopropyl alcohol（C3H8 O）,ethanal（C2H4O）, and ethylene（C2H4） tested, as high as 100% efficiency could be achieved with double perovskite-type catalysts operated at 300–350℃, indicating that double perovskites are promising catalysts for VOCs removal.展开更多
文摘In order to investigate the Magnetic Behavior of Compounds,the Variable —temperature magnetic susceptibility data of the title compounds(I:[Cu(C6H8O4)(C7H6N2)2H2O]∞) and(II:[Cu(C4H4O4)(C7H6N2)2 H2O]∞) were recorded and discussed quantitatively based on to Ising’s model and particle swarm optimization(PSO).J≈-1.3cm-1,which shows that there is a weak interaction between two Cu(II) ions in the title compounds.It can be interpreted with Kahn’s approximate molecular orbital model.Room-temperature magnetic moment(2.150μB) is larger than pure-spin magnetic moment(1.732μB) and g is larger than ge(2.002),which comfirms the existence of spin-orbit coupling in the compounds.
基金the Ministry of Science and Technology(MOST),Republic of China(ROC)(No.102WFA0700516)National Central University(No.105G910-9)for fundingfinancial support from the Industrial Technology Research Institute(No.105G910-8)
文摘Double perovskite-type catalysts including La2 CoMnO6 and La2 CuMnO6 are first evaluated for the effectiveness in removing volatile organic compounds（VOCs）, and single perovskites（La CoO3, LaMnO3, and La Cu O3） are also tested for comparison. All perovskites are tested with the gas hourly space velocity（GHSV） of 30,000 hr^-1, and the temperature range of100–600℃ for C7H8 removal. Experimental results indicate that double perovskites have better activity if compared with single perovskites. Especially, toluene（C7H8） can be completely oxidized to CO2 at 300℃ as La2 Co MnO6 is applied. Characterization of catalysts indicates that double perovskites own unique surface properties and are of higher amounts of lattice oxygen,leading to higher activity. Additionally, apparent activation energy of 68 k J/mol is calculated using Mars-van Krevelen model for C7 H8 oxidation with La2 Co Mn O6 as catalyst. For durability test, both La2 Co Mn O6 and La2 CuMnO6 maintain high C7 H8 removal efficiencies of 100% and98%, respectively, at 300℃ and 30,000 hr^-1, and they also show good resistance to CO2（5%） and H2 O（g）（5%） of the gas streams tested. For various VOCs including isopropyl alcohol（C3H8 O）,ethanal（C2H4O）, and ethylene（C2H4） tested, as high as 100% efficiency could be achieved with double perovskite-type catalysts operated at 300–350℃, indicating that double perovskites are promising catalysts for VOCs removal.
