Different amounts of AlON have been introduced in calcium hexaaluminate(CA_(6)) using two approaches, that is, one-step and twostep methods, to improve the slag resistance of CA_(6). A one-step method can directly sin...Different amounts of AlON have been introduced in calcium hexaaluminate(CA_(6)) using two approaches, that is, one-step and twostep methods, to improve the slag resistance of CA_(6). A one-step method can directly sinter the mixtures combining Al_(2)O_(3), CaCO_(3), and Al in flowing nitrogen, in which AlON clusters are always formed because of the poor wettability of Al by Al_(2)O_(3), leading to the high porosity of CA_(6)/AlON composite. In a two-step method, CA_(6)and AlON are prepared separately and then mixed and sintered in flowing nitrogen. Compared with the sample prepared by the one-step method, CA_(6)and AlON in composite by the two-step method are more uniformly distributed,and the optimized amount of AlON added is 10wt%. The slag corrosion and penetration test shows that the CA_(6)/AlON composite using the two-step method exhibits superior slag corrosion protection. The promoted effect of AlON on slag penetration and corrosion resistance is also discussed.展开更多
基金financially supported by the National Natural Science Foundation of China (Grant No. 51862012)the Natural Science Foundation of Jiangxi Province (Grants No. 20202BAB204008, 20165ABC28010)the Innovation Leadership Program of Ganzhou。
基金financially supported by the National Science Fund for Distinguished Young Scholars (No. 52025041)the National Natural Science Foundation of China (Nos. 51904021, 51974021, 52174294, and 51902020)+2 种基金the Fundamental Research Funds for the Central Universities (No. FRF-TP-19-008A1)the Project of Liaoning Province’s “Rejuvenating Liaoning Talents Plan”, China (No. XLYC1902092)the Beijing Excellent Talents Foundation。
文摘Different amounts of AlON have been introduced in calcium hexaaluminate(CA_(6)) using two approaches, that is, one-step and twostep methods, to improve the slag resistance of CA_(6). A one-step method can directly sinter the mixtures combining Al_(2)O_(3), CaCO_(3), and Al in flowing nitrogen, in which AlON clusters are always formed because of the poor wettability of Al by Al_(2)O_(3), leading to the high porosity of CA_(6)/AlON composite. In a two-step method, CA_(6)and AlON are prepared separately and then mixed and sintered in flowing nitrogen. Compared with the sample prepared by the one-step method, CA_(6)and AlON in composite by the two-step method are more uniformly distributed,and the optimized amount of AlON added is 10wt%. The slag corrosion and penetration test shows that the CA_(6)/AlON composite using the two-step method exhibits superior slag corrosion protection. The promoted effect of AlON on slag penetration and corrosion resistance is also discussed.
