利用建立起来的理论模型,深入研究了联合电解催化交换(Combined Electrolysis and Catalytic Exchange,CECE)工艺中各种因素对氢同位素分离性能的影响。电解池分离因子的提高对浓缩倍数和脱氚率均有显著影响,降低电解池滞留量是提高浓...利用建立起来的理论模型,深入研究了联合电解催化交换(Combined Electrolysis and Catalytic Exchange,CECE)工艺中各种因素对氢同位素分离性能的影响。电解池分离因子的提高对浓缩倍数和脱氚率均有显著影响,降低电解池滞留量是提高浓缩倍数的有效手段。进料位置在1.5m处系统性能好于3m处;催化剂传质系数在3~4mol·m-3·s-1范围内,浓缩倍数和脱氚率基本呈线性增长。各种因素对HD/H2O和HT/H2O两个体系的影响具有相似的规律性,由于热力学因素的差异,相同条件下,HT/H2O体系分离性能好于HD/H2O。展开更多
T Measurements of the cation exchange capacity (CEC) show significant soil properties, in particular its ability to retain the cations because of their mobility in the soil. Thirteen soil samples rich in electrolytes ...T Measurements of the cation exchange capacity (CEC) show significant soil properties, in particular its ability to retain the cations because of their mobility in the soil. Thirteen soil samples rich in electrolytes of the Cheliff plain (Algeria) were analyzed in order to measure their CEC and to draw up the existing relationship between texture, organic matter content and pH. In calcareous soils, the CECe values are always higher than those measured at pH 7. Regression equations using the percentages of organic carbon and clay as independent variables would make it possible to estimate 90% of the variability of the CEC measured in the ammonium acetate buffered at pH 7 and 89% of the variability for that measured at the pH of the soil. These percentages are particularly useful due to the fact that they make it possible to estimate the CEC of the soil according to the pH only starting from the organic matter and texture. The correlations between the salinity indices, the parameters of the saline phase and the physical properties, show that the cobalt-hexamine method makes it possible to characterize the soil of this plain with more precision than the Metson method. It constitutes a means for following-up the chemical quality of the soil. The Metson method makes it possible to approach the reactivity of the soil in relation with the geometry of the components. The measurement of the CEC at pH 7 makes it possible to envisage the water content at the permanent wilting point of the plants. Finally, it is noticed that a sodisation of the adsorbing compound, which consequently generates a reduction in the structural stability and a reduction in the infiltration always leads to the salinity in these soil types.展开更多
文摘利用建立起来的理论模型,深入研究了联合电解催化交换(Combined Electrolysis and Catalytic Exchange,CECE)工艺中各种因素对氢同位素分离性能的影响。电解池分离因子的提高对浓缩倍数和脱氚率均有显著影响,降低电解池滞留量是提高浓缩倍数的有效手段。进料位置在1.5m处系统性能好于3m处;催化剂传质系数在3~4mol·m-3·s-1范围内,浓缩倍数和脱氚率基本呈线性增长。各种因素对HD/H2O和HT/H2O两个体系的影响具有相似的规律性,由于热力学因素的差异,相同条件下,HT/H2O体系分离性能好于HD/H2O。
文摘T Measurements of the cation exchange capacity (CEC) show significant soil properties, in particular its ability to retain the cations because of their mobility in the soil. Thirteen soil samples rich in electrolytes of the Cheliff plain (Algeria) were analyzed in order to measure their CEC and to draw up the existing relationship between texture, organic matter content and pH. In calcareous soils, the CECe values are always higher than those measured at pH 7. Regression equations using the percentages of organic carbon and clay as independent variables would make it possible to estimate 90% of the variability of the CEC measured in the ammonium acetate buffered at pH 7 and 89% of the variability for that measured at the pH of the soil. These percentages are particularly useful due to the fact that they make it possible to estimate the CEC of the soil according to the pH only starting from the organic matter and texture. The correlations between the salinity indices, the parameters of the saline phase and the physical properties, show that the cobalt-hexamine method makes it possible to characterize the soil of this plain with more precision than the Metson method. It constitutes a means for following-up the chemical quality of the soil. The Metson method makes it possible to approach the reactivity of the soil in relation with the geometry of the components. The measurement of the CEC at pH 7 makes it possible to envisage the water content at the permanent wilting point of the plants. Finally, it is noticed that a sodisation of the adsorbing compound, which consequently generates a reduction in the structural stability and a reduction in the infiltration always leads to the salinity in these soil types.