The polymer-ceramic composites of epoxy resin (EP) and barium titanate (BT) were prepared. BT powders of different BT particle sizes from 100 nm to 1 μm were used in the preparation. The dielectric properties, such a...The polymer-ceramic composites of epoxy resin (EP) and barium titanate (BT) were prepared. BT powders of different BT particle sizes from 100 nm to 1 μm were used in the preparation. The dielectric properties, such as dielectric constant, dielectric loss and electrical breakdown strength, of the EP/BT composites were studied. The morphology of the composites was characterized by the means of scanning electron microscopy (SEM). The results show that the dielectric constant of the composites is much higher than the epoxy matrix at frequency range from 1 kHz to 10 MHz, and it is also obviously dependent on the size of BT particles. The electrical breakdown strength of the composites decreases with the increase of the BT content. The dependence of electrical breakdown strength on BT particle sizes was also discussed.展开更多
Flame retardant epoxy resins were prepared by a simple mixed method using ammonium aluminum carbonate hydroxy hydrate （AACHH） as a halogen-free flame retardant. The prepared samples were characterized by X-ray diffr...Flame retardant epoxy resins were prepared by a simple mixed method using ammonium aluminum carbonate hydroxy hydrate （AACHH） as a halogen-free flame retardant. The prepared samples were characterized by X-ray diffraction, thermogravimetric and differential scanning calorimetry, scanning electron microscope and limiting oxygen index（LOI） experiments. Effects of AACHH content on LOI of epoxy resins/AACHH composite and flame retardant mechanism were investigated and discussed. Results show that AACHH exhibites excellent flame-retardant properties in epoxy resin（EP）. When the content of AACHH was 47.4%, the LOI of EP reached 32.2%. Moreover, the initial and terminal decomposition temperature of EP increased by 48 ℃ and 40 ℃, respectively. The flame retarded mechanism of AACHH is due to the synergic flame retardant effects of diluting, cooling, decomposition resisting and obstructing.展开更多
The oil sorption capacity of composite materials made up of different polymeric fabrics (namely acrylic fabric (AF), polypropylene nonwoven (PP), and silk stocking (SS) as composite out-packing materials) and expanded...The oil sorption capacity of composite materials made up of different polymeric fabrics (namely acrylic fabric (AF), polypropylene nonwoven (PP), and silk stocking (SS) as composite out-packing materials) and expanded perlite (EP) was evaluated for oil removal from the water. The effects of sorbent dosage, desorption time, oil amount in the water, and contact time on composite materials sorption were investigated. The results showed that the optimum quantity of EP was between 0.5 g and 1.0 g for 25 cm2 polymeric fabrics bags. Oil removal efficiency for 6 L/m2 of oil amount in the water was 52%-72%, 44%-63%, and 37%-48% for AF, PP, and SS composite materials, respectively. Oil/water selectivity analysis of different composite materials showed that AF composite material had a very high degree of hydrophobicity and oil sorption capacity of approximately 10.17 g/g. Both oil sorption kinetics and equilibrium studies were carried out, and the equilibrium process of composite materials was described well by the Langmuir isotherm, and the oil sorption kinetics of composite materials showed good correlation coefficients for the pseudo-second order kinetic model. Intra-particle diffusion studies showed that oil sorption mechanism was controlled by the three processes, involving in external liquid membrane diffusion, surface sorption, and intra-particle diffusion.展开更多
As the main seismic component of a bridge,seismic damage to the bridge pier has a greater effect on its subsequent service.In the offshore chloride environment,the issues(e.g.,reinforcement bar corrosion and attenuati...As the main seismic component of a bridge,seismic damage to the bridge pier has a greater effect on its subsequent service.In the offshore chloride environment,the issues(e.g.,reinforcement bar corrosion and attenuation of concrete strength)of piers caused by chloride ion seriously curtail the normal service life and deteriorate the anti-seismic property of bridge structures.The engineered cementitious composite(ECC)-reinforced concrete(RC)composite pier with high strength reinforcement bars(HSRB)is expected to solve the above problems.This study aims to clarify the time-varying seismic vulnerability(SV)of the HSRBECC-RC composite pier during its full life cycle(FLC).Based on OpenSees,the refined finite element analysis models of RC pier,ECC-RC composite pier,and HSRBECC-RC composite pier have been established.Moreover,using the nonlinear time-path dynamic analysis method,the influence of chloride ion erosion on the time-dependent seismic vulnerability(SV)of these different piers in different service life and different peak ground acceleration(PGA)were analyzed from a dynamic point of view.The research shows that the exceeding probability(EP)of the same damage level increases with the enhancement of service time and PGA and with the increase of destruction,the exceeding probability(EP)of slight damage(DL-1),moderate damage(DL-2),serious damage(DL-3),and complete collapse(DL-4)decreases in turn;the corrosion degree of chloride ion to piers is small during the early service period,the time-varying vulnerability curve of the bridge piers is almost the same as that of a new bridge,and during later service,as the extent of chloride ion corrosion deepens,exceeding probability(EP)under severe damage(DL-3)and complete collapse(DL-4)is increased,and the seismic performance is significantly enhanced.展开更多
文摘The polymer-ceramic composites of epoxy resin (EP) and barium titanate (BT) were prepared. BT powders of different BT particle sizes from 100 nm to 1 μm were used in the preparation. The dielectric properties, such as dielectric constant, dielectric loss and electrical breakdown strength, of the EP/BT composites were studied. The morphology of the composites was characterized by the means of scanning electron microscopy (SEM). The results show that the dielectric constant of the composites is much higher than the epoxy matrix at frequency range from 1 kHz to 10 MHz, and it is also obviously dependent on the size of BT particles. The electrical breakdown strength of the composites decreases with the increase of the BT content. The dependence of electrical breakdown strength on BT particle sizes was also discussed.
基金Funded by the Defense Preresearch Project of the Eleventh-Five-Year-Plan of China(No.51312040404)
文摘Flame retardant epoxy resins were prepared by a simple mixed method using ammonium aluminum carbonate hydroxy hydrate （AACHH） as a halogen-free flame retardant. The prepared samples were characterized by X-ray diffraction, thermogravimetric and differential scanning calorimetry, scanning electron microscope and limiting oxygen index（LOI） experiments. Effects of AACHH content on LOI of epoxy resins/AACHH composite and flame retardant mechanism were investigated and discussed. Results show that AACHH exhibites excellent flame-retardant properties in epoxy resin（EP）. When the content of AACHH was 47.4%, the LOI of EP reached 32.2%. Moreover, the initial and terminal decomposition temperature of EP increased by 48 ℃ and 40 ℃, respectively. The flame retarded mechanism of AACHH is due to the synergic flame retardant effects of diluting, cooling, decomposition resisting and obstructing.
基金National Important Science & Technology Specific Projects of China ( No. 2009ZX07317-006-02,No. 2009ZX07318-008-007)State Key Laboratory of Urban Water Resource and Environment,Harbin Institute of Technology,China ( No. 2013DX06)
文摘The oil sorption capacity of composite materials made up of different polymeric fabrics (namely acrylic fabric (AF), polypropylene nonwoven (PP), and silk stocking (SS) as composite out-packing materials) and expanded perlite (EP) was evaluated for oil removal from the water. The effects of sorbent dosage, desorption time, oil amount in the water, and contact time on composite materials sorption were investigated. The results showed that the optimum quantity of EP was between 0.5 g and 1.0 g for 25 cm2 polymeric fabrics bags. Oil removal efficiency for 6 L/m2 of oil amount in the water was 52%-72%, 44%-63%, and 37%-48% for AF, PP, and SS composite materials, respectively. Oil/water selectivity analysis of different composite materials showed that AF composite material had a very high degree of hydrophobicity and oil sorption capacity of approximately 10.17 g/g. Both oil sorption kinetics and equilibrium studies were carried out, and the equilibrium process of composite materials was described well by the Langmuir isotherm, and the oil sorption kinetics of composite materials showed good correlation coefficients for the pseudo-second order kinetic model. Intra-particle diffusion studies showed that oil sorption mechanism was controlled by the three processes, involving in external liquid membrane diffusion, surface sorption, and intra-particle diffusion.
基金National Natural Science Foundation of China under Grant No.51608488China Postdoctoral Science Foundation under Grant No.2020M672277Scientific and Technological Project of Henan province,China under Grant No.192102210185。
文摘As the main seismic component of a bridge,seismic damage to the bridge pier has a greater effect on its subsequent service.In the offshore chloride environment,the issues(e.g.,reinforcement bar corrosion and attenuation of concrete strength)of piers caused by chloride ion seriously curtail the normal service life and deteriorate the anti-seismic property of bridge structures.The engineered cementitious composite(ECC)-reinforced concrete(RC)composite pier with high strength reinforcement bars(HSRB)is expected to solve the above problems.This study aims to clarify the time-varying seismic vulnerability(SV)of the HSRBECC-RC composite pier during its full life cycle(FLC).Based on OpenSees,the refined finite element analysis models of RC pier,ECC-RC composite pier,and HSRBECC-RC composite pier have been established.Moreover,using the nonlinear time-path dynamic analysis method,the influence of chloride ion erosion on the time-dependent seismic vulnerability(SV)of these different piers in different service life and different peak ground acceleration(PGA)were analyzed from a dynamic point of view.The research shows that the exceeding probability(EP)of the same damage level increases with the enhancement of service time and PGA and with the increase of destruction,the exceeding probability(EP)of slight damage(DL-1),moderate damage(DL-2),serious damage(DL-3),and complete collapse(DL-4)decreases in turn;the corrosion degree of chloride ion to piers is small during the early service period,the time-varying vulnerability curve of the bridge piers is almost the same as that of a new bridge,and during later service,as the extent of chloride ion corrosion deepens,exceeding probability(EP)under severe damage(DL-3)and complete collapse(DL-4)is increased,and the seismic performance is significantly enhanced.
