We fabricate nano-structural metal films to improve photoluminescence of perovskite films. When the perovskite film is placed on an ammonia-treated alumina film, stronger photoluminescence is found due to local field ...We fabricate nano-structural metal films to improve photoluminescence of perovskite films. When the perovskite film is placed on an ammonia-treated alumina film, stronger photoluminescence is found due to local field en- hancement effects. In addition, the oxide spacer layer between the metal （e.g., AI, Ag and Au） substrate and the perovskite film plays an important role. The simulations and experiments imply that the enhancement is related to surface plasmons of nano-structural metals.展开更多
High-quality perovskite films with larger grain size and fewer defects is a prerequisite for highperformance perovskite solar cells(PSCs).Antisolvent-assisted crystallization is an effective approach to obtain compact...High-quality perovskite films with larger grain size and fewer defects is a prerequisite for highperformance perovskite solar cells(PSCs).Antisolvent-assisted crystallization is an effective approach to obtain compact and uniform perovskite films;however,the majority of antisolvents currently applied have strong toxicity,and the control of perovskite crystallization is not easy through single antisolvent.In this work,a green antisolvent of ethyl acetate(EA)with acetylacetone(AA)additive is used to fine-tune perovskite crystallization and passivate defect,which produces uniform and compact CH;NH;PbI;perovskite films having larger grain and fewer grain boundaries and reduced defect density.Meanwhile,the interfacial hydrophobic characteristic of the perovskite films is enhanced.At the optimized concentration of AA in EA,the power conversion efficiency(PCE)of the CH;NH;PbI;PSCs was improved from 19.2%to 21.1%and their stability in air was also enhanced.These results present a green antisolvent additive engineering strategy to enhance the crystallinity,passivate defects,and fabricate efficient and stable PSCs.展开更多
基金Supported by the Ministry of Science and Technology of China under Grant No 2016YFA0202201the National Natural Science Foundation of China under Grant Nos 61290304,11574335 and 61376016+1 种基金the Youth Innovation Promotion Association of the Chinese Academy of Sciencesthe 333 Project of Jiangsu province under Grant No BRA2017352
文摘We fabricate nano-structural metal films to improve photoluminescence of perovskite films. When the perovskite film is placed on an ammonia-treated alumina film, stronger photoluminescence is found due to local field en- hancement effects. In addition, the oxide spacer layer between the metal （e.g., AI, Ag and Au） substrate and the perovskite film plays an important role. The simulations and experiments imply that the enhancement is related to surface plasmons of nano-structural metals.
基金funded by the National Key Research and Development Program of China(2016YFA0202403)the Natural Science Basic Research Program of Shaanxi Province(S2021-0-JCZD-0178)。
文摘High-quality perovskite films with larger grain size and fewer defects is a prerequisite for highperformance perovskite solar cells(PSCs).Antisolvent-assisted crystallization is an effective approach to obtain compact and uniform perovskite films;however,the majority of antisolvents currently applied have strong toxicity,and the control of perovskite crystallization is not easy through single antisolvent.In this work,a green antisolvent of ethyl acetate(EA)with acetylacetone(AA)additive is used to fine-tune perovskite crystallization and passivate defect,which produces uniform and compact CH;NH;PbI;perovskite films having larger grain and fewer grain boundaries and reduced defect density.Meanwhile,the interfacial hydrophobic characteristic of the perovskite films is enhanced.At the optimized concentration of AA in EA,the power conversion efficiency(PCE)of the CH;NH;PbI;PSCs was improved from 19.2%to 21.1%and their stability in air was also enhanced.These results present a green antisolvent additive engineering strategy to enhance the crystallinity,passivate defects,and fabricate efficient and stable PSCs.
