A novel three dimensional fluorinated gallium phosphate has been hydrothermally synthesized by using diethylenetriamine as an organic structure directing agent. X ray single crystal structure analysis indicates this c...A novel three dimensional fluorinated gallium phosphate has been hydrothermally synthesized by using diethylenetriamine as an organic structure directing agent. X ray single crystal structure analysis indicates this compound crystallizes in the orthorhombic space group Pbca, a =1.605 6(7) nm, b = 1 011 4 (4) nm, c =1.854 6(5) nm, V =3.011 6(19) nm 3, Z =4. The three dimensional framework based on linkage of corner sharing polyhedron PO 4, GaO 4F and GaO 4F 2 delimit ten ring channels along b axis in which the triply protonated amines are located serving as charge compensating guests and supporters.展开更多
The title compound H2SiW12O40·(CH3)2NH was synthesized in mixed solvent of aqueous and acetonitrile, and its crystal structure had been determined using single crystal X ray diffraction. The crystal belongs to mo...The title compound H2SiW12O40·(CH3)2NH was synthesized in mixed solvent of aqueous and acetonitrile, and its crystal structure had been determined using single crystal X ray diffraction. The crystal belongs to monoclinic, space group C2/m, a=2.0654(4)nm, b=1.3306(3)nm, c=1.3194(3)nm, β=119.59(3)°, V=3.1531(11)nm3, Dc=3.606Mg·m-3, Z=2, R=0.0462, Rw=0.0836. The title compound comprises of a 2+ unit, a polyanion and a free (CH3)2NH molecule. The ESR spectrum of the title compound shows that charge transfer between organic groups and polyanion takes place under irradiation of the sunlight in solid state. The TG study of the title compound shows that it had four stages of the weight loss, and the increase of the decomposition temperature for the polyanion shows that the stability of the polyanion was enhanced due to the influence of Zn2+ ion. CCDC:175866.展开更多
In this paper, a novel polymeric complex [MnNa（Salicylate）2（CH3OH）（H2O）]n·0.5nH2O was obtained and characterized by IR spectra, elemental analysis and single crystal X-ray diffraction. The titled complex is...In this paper, a novel polymeric complex [MnNa（Salicylate）2（CH3OH）（H2O）]n·0.5nH2O was obtained and characterized by IR spectra, elemental analysis and single crystal X-ray diffraction. The titled complex is crystallized in triclinic system, space group P1 with a=0.763 82（15） nm, b= 1.037 1（2） nm, c=1.290 9（3） nm, α= 103.59（3）°, β=104.65（3）°, γ=109.50（3）°, V=0.873 6（3） nm 3, Z=2, Dc=1.556 Mg/m 3, Mr=409.20, μ=0.823 mm -1, F（000）=418, R=0.0614, wR= 0.147 6. The activity in catalyzing the superoxygen anionic free radical dismutation was determinated.展开更多
A new molybdophosphate, (NH3CH2CH2NH3)2Mo5O15(HPO4)2 has been synthesized under hydrothermal conditions and structurally characterized by single crystal X ray diffractions. The compound crystallizes in the monoclinic,...A new molybdophosphate, (NH3CH2CH2NH3)2Mo5O15(HPO4)2 has been synthesized under hydrothermal conditions and structurally characterized by single crystal X ray diffractions. The compound crystallizes in the monoclinic, space group C2/c, a=1.7633(2)nm, b=1.00122(11) nm, c=1.37624(13)nm, β=96.974(5)°, V=2.4117(5)nm3, Z=4, Dc=2.853g·cm-3, μ(MoKα)=2.766mm-1, F(000)=1992. The structure contains the isolated polyanions of [Mo5O15(HPO4)2]4- units around which the portonated ethylenediamine ions are pos itioned. By hydrogen bond interactions the polyanions are interconnected to form a three dimensional network. Other characterizations by powder XRD, IR and thermal analysis are also described. CCDC: 206321.展开更多
Ga 3(PO 4) 4](H 3NCH 2CH 2) 2NH 2(abbr. to GaP 1) has been synthesized by a hydrothermal method. X ray crystal structure analysis indicates GaP 1 crystallizes in monoclinic, with space group C2/c , a =2 079 3(5) nm, b...Ga 3(PO 4) 4](H 3NCH 2CH 2) 2NH 2(abbr. to GaP 1) has been synthesized by a hydrothermal method. X ray crystal structure analysis indicates GaP 1 crystallizes in monoclinic, with space group C2/c , a =2 079 3(5) nm, b =1 194 2(2) nm, c =1 648 0(4) nm, β =117 064(14)°, V =3 644 2(13) nm 3, Z =6, D c=1 901 g/cm 3, I ≥2 σ(I )=2 274, R =0 055 6, R w=0 134 8. GaP 1 is characteristic of the intercalation of disordered fully protonated diethylenetriamine among two dimensional inorganic framework built up from PO 4, GaO 5 and GaO 6 primary structure units. The framework features 3 , 4 , 5 and 8 ring topological connectivity.展开更多
文摘A novel three dimensional fluorinated gallium phosphate has been hydrothermally synthesized by using diethylenetriamine as an organic structure directing agent. X ray single crystal structure analysis indicates this compound crystallizes in the orthorhombic space group Pbca, a =1.605 6(7) nm, b = 1 011 4 (4) nm, c =1.854 6(5) nm, V =3.011 6(19) nm 3, Z =4. The three dimensional framework based on linkage of corner sharing polyhedron PO 4, GaO 4F and GaO 4F 2 delimit ten ring channels along b axis in which the triply protonated amines are located serving as charge compensating guests and supporters.
文摘The title compound H2SiW12O40·(CH3)2NH was synthesized in mixed solvent of aqueous and acetonitrile, and its crystal structure had been determined using single crystal X ray diffraction. The crystal belongs to monoclinic, space group C2/m, a=2.0654(4)nm, b=1.3306(3)nm, c=1.3194(3)nm, β=119.59(3)°, V=3.1531(11)nm3, Dc=3.606Mg·m-3, Z=2, R=0.0462, Rw=0.0836. The title compound comprises of a 2+ unit, a polyanion and a free (CH3)2NH molecule. The ESR spectrum of the title compound shows that charge transfer between organic groups and polyanion takes place under irradiation of the sunlight in solid state. The TG study of the title compound shows that it had four stages of the weight loss, and the increase of the decomposition temperature for the polyanion shows that the stability of the polyanion was enhanced due to the influence of Zn2+ ion. CCDC:175866.
文摘In this paper, a novel polymeric complex [MnNa（Salicylate）2（CH3OH）（H2O）]n·0.5nH2O was obtained and characterized by IR spectra, elemental analysis and single crystal X-ray diffraction. The titled complex is crystallized in triclinic system, space group P1 with a=0.763 82（15） nm, b= 1.037 1（2） nm, c=1.290 9（3） nm, α= 103.59（3）°, β=104.65（3）°, γ=109.50（3）°, V=0.873 6（3） nm 3, Z=2, Dc=1.556 Mg/m 3, Mr=409.20, μ=0.823 mm -1, F（000）=418, R=0.0614, wR= 0.147 6. The activity in catalyzing the superoxygen anionic free radical dismutation was determinated.
文摘A new molybdophosphate, (NH3CH2CH2NH3)2Mo5O15(HPO4)2 has been synthesized under hydrothermal conditions and structurally characterized by single crystal X ray diffractions. The compound crystallizes in the monoclinic, space group C2/c, a=1.7633(2)nm, b=1.00122(11) nm, c=1.37624(13)nm, β=96.974(5)°, V=2.4117(5)nm3, Z=4, Dc=2.853g·cm-3, μ(MoKα)=2.766mm-1, F(000)=1992. The structure contains the isolated polyanions of [Mo5O15(HPO4)2]4- units around which the portonated ethylenediamine ions are pos itioned. By hydrogen bond interactions the polyanions are interconnected to form a three dimensional network. Other characterizations by powder XRD, IR and thermal analysis are also described. CCDC: 206321.
文摘Ga 3(PO 4) 4](H 3NCH 2CH 2) 2NH 2(abbr. to GaP 1) has been synthesized by a hydrothermal method. X ray crystal structure analysis indicates GaP 1 crystallizes in monoclinic, with space group C2/c , a =2 079 3(5) nm, b =1 194 2(2) nm, c =1 648 0(4) nm, β =117 064(14)°, V =3 644 2(13) nm 3, Z =6, D c=1 901 g/cm 3, I ≥2 σ(I )=2 274, R =0 055 6, R w=0 134 8. GaP 1 is characteristic of the intercalation of disordered fully protonated diethylenetriamine among two dimensional inorganic framework built up from PO 4, GaO 5 and GaO 6 primary structure units. The framework features 3 , 4 , 5 and 8 ring topological connectivity.
