为提升瓦斯抽采利用率、促进煤矿安全生产,采用介质阻挡放电(DBD)试验系统对CH4-O2-N2-H2O反应体系进行低温等离子体转化研究,分析水蒸气与CH4物质的量比、O2/N2物质的量比、放电电压、放电频率,以及气体总流量对CH4转化率及主要产物产...为提升瓦斯抽采利用率、促进煤矿安全生产,采用介质阻挡放电(DBD)试验系统对CH4-O2-N2-H2O反应体系进行低温等离子体转化研究,分析水蒸气与CH4物质的量比、O2/N2物质的量比、放电电压、放电频率,以及气体总流量对CH4转化率及主要产物产率的影响。结果表明:CH4-O2-N2-H2O反应体系DBD的主要产物为H2、CO、CO2、C2H2、C2H4、C2H6和CH3OH;反应参数对CH4转化率和H2、CO、CO2、C2H6、CH3OH产率影响较为显著,而对C2H2、C2H4产率影响不显著;CH4转化率及主要产物产率均在放电频率为9.8 k Hz时取得最大值。展开更多
Diffusion of pure H2, CO, N2,O2 and CH4 gases through nanoporous carbon membrane is investigated by carrying out non-equilibrium molecular dynamics （NEMD） simulations. The flux, transport diffusivity and activation ...Diffusion of pure H2, CO, N2,O2 and CH4 gases through nanoporous carbon membrane is investigated by carrying out non-equilibrium molecular dynamics （NEMD） simulations. The flux, transport diffusivity and activation energy for the pure gases diffusing through carbon membranes with various pore widths were investigated. The simulation results reveal that transport diffusivity increases with temperature and pore width, and its values have a magnitude of 10^-7 m^2·s^-1 for pore widths of about 0.80 to 1.21 nm at 273 to 300 K. The activation energies for the gases diffusion through the membrane with various pore widths are about 1-5 kJ·mol^-1, The results of transport diffusivities are comparable with that of Rao and Sircar （J. Membr. Sci., 1996）, indicating the NEMD simulation method is a good tool for predicting the transport diffusivities for gases in porous materials, which is always difficult to be accurately measured by experiments.展开更多
We report comparatively on fabrication of two-section ridge-waveguide tapered 3 quantum well (QW) InGaAsP/InP (1300 nm) and 5 QW AlGaInAs/InP (1550 nm) diode lasers. Gas mixtures of CCl2F2/O2 and H2/CH4 were used to f...We report comparatively on fabrication of two-section ridge-waveguide tapered 3 quantum well (QW) InGaAsP/InP (1300 nm) and 5 QW AlGaInAs/InP (1550 nm) diode lasers. Gas mixtures of CCl2F2/O2 and H2/CH4 were used to form ridge-waveguide on the lasers with InP-based material structures. As known, chlorine- and hydro-carbon based gases are used to fabricate ridge-waveguide structures. Here, we show the difference between the structures obtained by using the both gas mixtures in which surface and sidewall structures as well as performance of the lasers were analysed using scanning electron microscopy. It is demonstrated that gas mixtures of CCl2F2/O2 highly deteriorated the etched structures although different flow rates, rf powers and base pressures were tried. We also show that the structures etched with H2/CH4 gas mixtures produced much better results that led to the successful fabrication of two-section devices with ridge-waveguide. The lasers fabricated using H2/CH4 were characterized using output power-current (P-I) and spectral results.展开更多
对长江下游稻麦两熟农田生态系统2009—2010年的CH4和N2O排放以及土壤碳固定进行了分析,初步研究了秸秆还田对稻麦两熟高产农田净增温潜势的影响。结果表明,秸秆还田对稻麦两熟高产农田周年CH4和N2O排放总量、土壤碳固定量以及净增温潜...对长江下游稻麦两熟农田生态系统2009—2010年的CH4和N2O排放以及土壤碳固定进行了分析,初步研究了秸秆还田对稻麦两熟高产农田净增温潜势的影响。结果表明,秸秆还田对稻麦两熟高产农田周年CH4和N2O排放总量、土壤碳固定量以及净增温潜势均有显著或极显著影响:秸秆还田条件下周年CH4、N2O排放总量分别为394 kg CH4.hm-2、2.39 kg N2O.hm-2,土壤碳固定量、净增温潜势分别为1.14 t C·hm-2、6383 kg CO2-equivalents·hm-2;较秸秆不还田增加CH4排放总量152%、减少N2O排放总量14%、增加土壤碳固定量531%、增加净增温潜势57%。以上结果表明,秸秆还田使短期内稻麦两熟高产农田的温室效应明显提高,但其长期效果如何还有待观测。展开更多
文摘为提升瓦斯抽采利用率、促进煤矿安全生产,采用介质阻挡放电(DBD)试验系统对CH4-O2-N2-H2O反应体系进行低温等离子体转化研究,分析水蒸气与CH4物质的量比、O2/N2物质的量比、放电电压、放电频率,以及气体总流量对CH4转化率及主要产物产率的影响。结果表明:CH4-O2-N2-H2O反应体系DBD的主要产物为H2、CO、CO2、C2H2、C2H4、C2H6和CH3OH;反应参数对CH4转化率和H2、CO、CO2、C2H6、CH3OH产率影响较为显著,而对C2H2、C2H4产率影响不显著;CH4转化率及主要产物产率均在放电频率为9.8 k Hz时取得最大值。
基金Supported by the state Key Development Program for Basic Research of China （2003CB615707） and the National Natural Science Foundation of China （20736005）.
文摘Diffusion of pure H2, CO, N2,O2 and CH4 gases through nanoporous carbon membrane is investigated by carrying out non-equilibrium molecular dynamics （NEMD） simulations. The flux, transport diffusivity and activation energy for the pure gases diffusing through carbon membranes with various pore widths were investigated. The simulation results reveal that transport diffusivity increases with temperature and pore width, and its values have a magnitude of 10^-7 m^2·s^-1 for pore widths of about 0.80 to 1.21 nm at 273 to 300 K. The activation energies for the gases diffusion through the membrane with various pore widths are about 1-5 kJ·mol^-1, The results of transport diffusivities are comparable with that of Rao and Sircar （J. Membr. Sci., 1996）, indicating the NEMD simulation method is a good tool for predicting the transport diffusivities for gases in porous materials, which is always difficult to be accurately measured by experiments.
基金the financial support of TUB-ITAK via Project 107E163.
文摘We report comparatively on fabrication of two-section ridge-waveguide tapered 3 quantum well (QW) InGaAsP/InP (1300 nm) and 5 QW AlGaInAs/InP (1550 nm) diode lasers. Gas mixtures of CCl2F2/O2 and H2/CH4 were used to form ridge-waveguide on the lasers with InP-based material structures. As known, chlorine- and hydro-carbon based gases are used to fabricate ridge-waveguide structures. Here, we show the difference between the structures obtained by using the both gas mixtures in which surface and sidewall structures as well as performance of the lasers were analysed using scanning electron microscopy. It is demonstrated that gas mixtures of CCl2F2/O2 highly deteriorated the etched structures although different flow rates, rf powers and base pressures were tried. We also show that the structures etched with H2/CH4 gas mixtures produced much better results that led to the successful fabrication of two-section devices with ridge-waveguide. The lasers fabricated using H2/CH4 were characterized using output power-current (P-I) and spectral results.
文摘对长江下游稻麦两熟农田生态系统2009—2010年的CH4和N2O排放以及土壤碳固定进行了分析,初步研究了秸秆还田对稻麦两熟高产农田净增温潜势的影响。结果表明,秸秆还田对稻麦两熟高产农田周年CH4和N2O排放总量、土壤碳固定量以及净增温潜势均有显著或极显著影响:秸秆还田条件下周年CH4、N2O排放总量分别为394 kg CH4.hm-2、2.39 kg N2O.hm-2,土壤碳固定量、净增温潜势分别为1.14 t C·hm-2、6383 kg CO2-equivalents·hm-2;较秸秆不还田增加CH4排放总量152%、减少N2O排放总量14%、增加土壤碳固定量531%、增加净增温潜势57%。以上结果表明,秸秆还田使短期内稻麦两熟高产农田的温室效应明显提高,但其长期效果如何还有待观测。
