With the development of reaction kinetics and transfer science, the modeling of NOx formation plays more and more important roles in the protection of environment and the design of combustion reactors; in this case,tu...With the development of reaction kinetics and transfer science, the modeling of NOx formation plays more and more important roles in the protection of environment and the design of combustion reactors; in this case,turbulence-chemistry model and NOx formation model are the two most important aspects. For thermal NOx mechanism, this article studied the CH4/air system and applied a set of latest NO formation rate constants published at the Leed University which replaced the original model code in FLUENT to increase its precision on prediction of NO concentration. The realizable k-ε model, Reynold Stress model and standard k-ε model were also investigated to predict the turbulent combustion reaction, which indicated that the simulation results of velocities, temperatures and concentrations of combustion productions by the standard k-ε model were in good accordance with the experimental data. With the application of the simulation results to the experimental data to fit some important kinetic parameters in the equation of O atom model and revision of the equation later, this article obtained a new NO formation rate model. It has been proved that the prediction of the developed model coincides well with the measurements.展开更多
Global mean surface air temperature is expected to increase 1.1˚C - 6.4˚C by the end of 21st century which may affect rice productivity and methane emissions in the future climate. This experiment was conducted to inv...Global mean surface air temperature is expected to increase 1.1˚C - 6.4˚C by the end of 21st century which may affect rice productivity and methane emissions in the future climate. This experiment was conducted to investigate the response of rice cultivars to elevated air temperature (+1.5˚C higher than ambient) and soil amendments in regards to rice yield, yield scaled methane emissions and global warming potentials. The experimental findings revealed that replacement of inorganic fertilizers (20% - 40% of recommended NPKS) with Vermicompost, Azolla biofertilizer, enriched sugarcane pressmud, rice husk biochar and silicate fertilization increased rice yield 13.0% - 23.0%, and 11.0% - 19.0% during wet aman and dry boro season, respectively. However, seasonal cumulative CH4 fluxes were decreased by 9.0% - 25.0% and 5.0% - 19.0% during rainfed wet aman and irrigated dry boro rice cultivation, respectively with selected soil amendments. The maximum reduction in seasonal cumulative CH4 flux (19.0% - 25.0%) was recorded with silicate fertilization and azolla biofertilizer amendments (9.0% - 13.0%), whereas maximum grain yield increment 10.0 % - 14.0% was found with Vermicompost and Sugarcane pressmud amendments compared to chemical fertilization (100% NPKS) treated soils at ambient air temperature. However, rice grain yield decreased drastically 43.0% - 50.0% at elevated air temperature (3˚C higher than ambient air temperature), eventhough accelerated the total cumulative CH4 flux as well as GWPs in all treatments. Maximum seasonal mean GWPs were calculated at 391.0 kg CO2 eq·ha−1 in rice husk biochar followed by sugarcane pressmud (mean GWP 387.0 kg CO2 eq·ha−1), while least GWPs were calculated at 285 - 305 kg CO2 eq·ha−1 with silicate fertilizer and Azolla biofertilizer amendments. Rice cultivar BRRI dhan 87 revealed comparatively higher seasonal cumulative CH4 fluxes, yield scaled CH4 flux and GWPs than BRRI dhan 71 during wet aman rice growing season;while BRRI dhan 89 showed higher cumulative CH4 flux and GWPs than BINA dhan 10 during irrigated boro rice cultivation. Conclusively, inorganic fertilizers may be partially (20% - 40% of the recommended NPKS) replaced with Vermicompost, azolla biofertilizer, silicate fertilizer and enriched sugarcane pressmud compost for sustainable rice production and decreasing GWPs under elevated air temperature condition.展开更多
With the development of reaction kinetics and transfer science, the modeling of NOx formation plays more and more important roles in the protection of environment and the design of combustion reactors; in this case, t...With the development of reaction kinetics and transfer science, the modeling of NOx formation plays more and more important roles in the protection of environment and the design of combustion reactors; in this case, turbulence-chemistry model and NOx formation model are the two most important aspects. For thermal NOx mechanism, this article studied the CH4/air system and applied a set of latest NO formation rate constants published at the Leed University which replaced the original model code in FLUENT to increase its precision on prediction of NO concentration. The realizable k-ε model, Reynold Stress model and standard k-ε model were also investigated to predict the turbulent combustion reaction, which indicated that the simulation results of velocities, temperatures and concentrations of combustion productions by the standard k-ε model were in good accordance with the experi- mental data. With the application of the simulation results to the experimental data to fit some important kinetic pa- rameters in the equation of O atom model and revision of the equation later, this article obtained a new NO forma- tion rate model. It has been proved that the prediction of the developed model coincides well with the measure- ments.展开更多
In order to investigate the fire suppression effectiveness of water mist with metal chloride additives, ultrafine water mists of these salts with diameters about 10μm were introduced into CH4 /air non-premixed flame ...In order to investigate the fire suppression effectiveness of water mist with metal chloride additives, ultrafine water mists of these salts with diameters about 10μm were introduced into CH4 /air non-premixed flame in the cup burner. Results showed that these droplets hard to make itself to the flame front under the cup burner flow conditions functioned as a carrier of the vaporized solid particles or its decomposed materials. The metal chloride improved fire suppression efficacy of water mist which were affected by the type and concentration of metal chloride. On a mass basis, there is a fire suppression effectiveness relationship of MgCl2 <CaCl2 <NaCl<KCl< MnCl2 <FeCl2 . The flame suppression ability of water solution/metal chlorides improves as the concentration of metal chlorides increase. However, upper additive limits exist due to the associated limiting vapour pressure of the additive.展开更多
NH_(3)作为氢能载体,可实现氢能远距离输运。针对NH_(3)燃烧的反应性低、稳定性差、高燃料型NO_(x)排放问题,设计旋流燃烧器和空气分级燃烧室,实验研究功率为5~23 k W的NH_(3)、NH_(3)/CH_(4)扩散火焰NO_(x)排放特性。并采用化学反应器...NH_(3)作为氢能载体,可实现氢能远距离输运。针对NH_(3)燃烧的反应性低、稳定性差、高燃料型NO_(x)排放问题,设计旋流燃烧器和空气分级燃烧室,实验研究功率为5~23 k W的NH_(3)、NH_(3)/CH_(4)扩散火焰NO_(x)排放特性。并采用化学反应器网络(CRN)进行化学动力学模拟,分析排放变化的原因。结果表明:5 kW、Ф_(pri)=1.05的条件下,NH_(3)火焰NO_(x)测量排放最低为114.4×10^(-6)@15%O_(2);随着功率升高,NO_(x)排放增加,且导致燃烧不充分、火焰延长,此时最佳Ф_(pri)提前、燃烧范围减少、NO_(x)进一步增加;本文的CRN更适合模拟预混燃烧的NO_(x)排放,而不是扩散燃烧;功率升高不会改变反应路径,但生成NO的基元反应速率的升高幅度略大于消耗NO的基元反应速率,从而导致NO排放升高.展开更多
A2B2O7 pyrochlore is a kind of important functional materials for different purposes,which has been investigated extensively by crystallographers and material scientists.However,the catalytic chemistry of this type of...A2B2O7 pyrochlore is a kind of important functional materials for different purposes,which has been investigated extensively by crystallographers and material scientists.However,the catalytic chemistry of this type of special compounds has rarely been documented,though a few researchers have tried to synthesize some pyrochlore compounds with different chemical compositions for a variety of green energy production and air pollution control reactions in the history.With the expectation to help catalysis scientists to get better acquaintance with,and gain deeper understanding on this type of compounds as heterogeneous catalysts,the major publications over the past several decades have been screened and reviewed in this paper,based also on our own experience of studying on this type of catalytic materials.The crystalline phase transformations of the compounds with the change of the A and B site cations,the phase change’s influences on the surface and bulk properties,and their subsequent impact on the catalytic performance for different reactions have been summarized.Furthermore,the future work which needs to be performed to perceive in depth this kind of important materials as catalysts has been proposed and suggested.We trust that this short review contains valuable information,which will provide great help for people to get better cognition for A2 B2 O7 pyrochlore compounds,and assist them to develop better catalysts for various reactions.展开更多
The concentrations of CH4 in the atmosphere over the past 2000 years have been deduced by extracting and analyzing the air in bubbles embedded in the Dasuopu ice core, Qing-hai-Tibetan Plateau. Upon analyzing 57 ice c...The concentrations of CH4 in the atmosphere over the past 2000 years have been deduced by extracting and analyzing the air in bubbles embedded in the Dasuopu ice core, Qing-hai-Tibetan Plateau. Upon analyzing 57 ice core samples we found that the concentration of CH4 200 years ago and earlier was 0.85 μ mol· mol-1 or about 40% of present atmospheric CH4 levels over Qinghai-Tibetan Plateau. A rapid and significant increase of atmospheric CH4 started about 200–250 a ago. For a given age before 19th century, the Dasuopu CH4 concentrations were about 15%-20% higher than those in Antarctic and Greenland references. It was also found that the Dasuopu CH4 concentrations changed more frequently, and its fluctuations could reflect the temperature change sensitively.展开更多
文摘With the development of reaction kinetics and transfer science, the modeling of NOx formation plays more and more important roles in the protection of environment and the design of combustion reactors; in this case,turbulence-chemistry model and NOx formation model are the two most important aspects. For thermal NOx mechanism, this article studied the CH4/air system and applied a set of latest NO formation rate constants published at the Leed University which replaced the original model code in FLUENT to increase its precision on prediction of NO concentration. The realizable k-ε model, Reynold Stress model and standard k-ε model were also investigated to predict the turbulent combustion reaction, which indicated that the simulation results of velocities, temperatures and concentrations of combustion productions by the standard k-ε model were in good accordance with the experimental data. With the application of the simulation results to the experimental data to fit some important kinetic parameters in the equation of O atom model and revision of the equation later, this article obtained a new NO formation rate model. It has been proved that the prediction of the developed model coincides well with the measurements.
文摘Global mean surface air temperature is expected to increase 1.1˚C - 6.4˚C by the end of 21st century which may affect rice productivity and methane emissions in the future climate. This experiment was conducted to investigate the response of rice cultivars to elevated air temperature (+1.5˚C higher than ambient) and soil amendments in regards to rice yield, yield scaled methane emissions and global warming potentials. The experimental findings revealed that replacement of inorganic fertilizers (20% - 40% of recommended NPKS) with Vermicompost, Azolla biofertilizer, enriched sugarcane pressmud, rice husk biochar and silicate fertilization increased rice yield 13.0% - 23.0%, and 11.0% - 19.0% during wet aman and dry boro season, respectively. However, seasonal cumulative CH4 fluxes were decreased by 9.0% - 25.0% and 5.0% - 19.0% during rainfed wet aman and irrigated dry boro rice cultivation, respectively with selected soil amendments. The maximum reduction in seasonal cumulative CH4 flux (19.0% - 25.0%) was recorded with silicate fertilization and azolla biofertilizer amendments (9.0% - 13.0%), whereas maximum grain yield increment 10.0 % - 14.0% was found with Vermicompost and Sugarcane pressmud amendments compared to chemical fertilization (100% NPKS) treated soils at ambient air temperature. However, rice grain yield decreased drastically 43.0% - 50.0% at elevated air temperature (3˚C higher than ambient air temperature), eventhough accelerated the total cumulative CH4 flux as well as GWPs in all treatments. Maximum seasonal mean GWPs were calculated at 391.0 kg CO2 eq·ha−1 in rice husk biochar followed by sugarcane pressmud (mean GWP 387.0 kg CO2 eq·ha−1), while least GWPs were calculated at 285 - 305 kg CO2 eq·ha−1 with silicate fertilizer and Azolla biofertilizer amendments. Rice cultivar BRRI dhan 87 revealed comparatively higher seasonal cumulative CH4 fluxes, yield scaled CH4 flux and GWPs than BRRI dhan 71 during wet aman rice growing season;while BRRI dhan 89 showed higher cumulative CH4 flux and GWPs than BINA dhan 10 during irrigated boro rice cultivation. Conclusively, inorganic fertilizers may be partially (20% - 40% of the recommended NPKS) replaced with Vermicompost, azolla biofertilizer, silicate fertilizer and enriched sugarcane pressmud compost for sustainable rice production and decreasing GWPs under elevated air temperature condition.
文摘With the development of reaction kinetics and transfer science, the modeling of NOx formation plays more and more important roles in the protection of environment and the design of combustion reactors; in this case, turbulence-chemistry model and NOx formation model are the two most important aspects. For thermal NOx mechanism, this article studied the CH4/air system and applied a set of latest NO formation rate constants published at the Leed University which replaced the original model code in FLUENT to increase its precision on prediction of NO concentration. The realizable k-ε model, Reynold Stress model and standard k-ε model were also investigated to predict the turbulent combustion reaction, which indicated that the simulation results of velocities, temperatures and concentrations of combustion productions by the standard k-ε model were in good accordance with the experi- mental data. With the application of the simulation results to the experimental data to fit some important kinetic pa- rameters in the equation of O atom model and revision of the equation later, this article obtained a new NO forma- tion rate model. It has been proved that the prediction of the developed model coincides well with the measure- ments.
基金the support of Project 50676092 supported by National Natural Science Foundation of ChinaProject 11YZ131 supported by Shanghai Municipal Education Commission
文摘In order to investigate the fire suppression effectiveness of water mist with metal chloride additives, ultrafine water mists of these salts with diameters about 10μm were introduced into CH4 /air non-premixed flame in the cup burner. Results showed that these droplets hard to make itself to the flame front under the cup burner flow conditions functioned as a carrier of the vaporized solid particles or its decomposed materials. The metal chloride improved fire suppression efficacy of water mist which were affected by the type and concentration of metal chloride. On a mass basis, there is a fire suppression effectiveness relationship of MgCl2 <CaCl2 <NaCl<KCl< MnCl2 <FeCl2 . The flame suppression ability of water solution/metal chlorides improves as the concentration of metal chlorides increase. However, upper additive limits exist due to the associated limiting vapour pressure of the additive.
文摘NH_(3)作为氢能载体,可实现氢能远距离输运。针对NH_(3)燃烧的反应性低、稳定性差、高燃料型NO_(x)排放问题,设计旋流燃烧器和空气分级燃烧室,实验研究功率为5~23 k W的NH_(3)、NH_(3)/CH_(4)扩散火焰NO_(x)排放特性。并采用化学反应器网络(CRN)进行化学动力学模拟,分析排放变化的原因。结果表明:5 kW、Ф_(pri)=1.05的条件下,NH_(3)火焰NO_(x)测量排放最低为114.4×10^(-6)@15%O_(2);随着功率升高,NO_(x)排放增加,且导致燃烧不充分、火焰延长,此时最佳Ф_(pri)提前、燃烧范围减少、NO_(x)进一步增加;本文的CRN更适合模拟预混燃烧的NO_(x)排放,而不是扩散燃烧;功率升高不会改变反应路径,但生成NO的基元反应速率的升高幅度略大于消耗NO的基元反应速率,从而导致NO排放升高.
基金Project supported by the National Natural Science Foundation of China(21962009,21567016,21666020)Natural Science Foundation of Jiangxi Province(20181ACB20005,20171BAB213013,20181BAB203017)Key Laboratory Foundation of Jiangxi Province for Environment and Energy Catalysis(20181BCD40004)。
文摘A2B2O7 pyrochlore is a kind of important functional materials for different purposes,which has been investigated extensively by crystallographers and material scientists.However,the catalytic chemistry of this type of special compounds has rarely been documented,though a few researchers have tried to synthesize some pyrochlore compounds with different chemical compositions for a variety of green energy production and air pollution control reactions in the history.With the expectation to help catalysis scientists to get better acquaintance with,and gain deeper understanding on this type of compounds as heterogeneous catalysts,the major publications over the past several decades have been screened and reviewed in this paper,based also on our own experience of studying on this type of catalytic materials.The crystalline phase transformations of the compounds with the change of the A and B site cations,the phase change’s influences on the surface and bulk properties,and their subsequent impact on the catalytic performance for different reactions have been summarized.Furthermore,the future work which needs to be performed to perceive in depth this kind of important materials as catalysts has been proposed and suggested.We trust that this short review contains valuable information,which will provide great help for people to get better cognition for A2 B2 O7 pyrochlore compounds,and assist them to develop better catalysts for various reactions.
基金the National Natural Science Foundation of China (Grant No.49671021), the National Key Project for Basic Research (Grant No. KZ951-A1-204), CAS Project for Tibetan Research Project (Grant No. KZ95-T-06) and Innovation Project of Cold and Arid Regions E
文摘The concentrations of CH4 in the atmosphere over the past 2000 years have been deduced by extracting and analyzing the air in bubbles embedded in the Dasuopu ice core, Qing-hai-Tibetan Plateau. Upon analyzing 57 ice core samples we found that the concentration of CH4 200 years ago and earlier was 0.85 μ mol· mol-1 or about 40% of present atmospheric CH4 levels over Qinghai-Tibetan Plateau. A rapid and significant increase of atmospheric CH4 started about 200–250 a ago. For a given age before 19th century, the Dasuopu CH4 concentrations were about 15%-20% higher than those in Antarctic and Greenland references. It was also found that the Dasuopu CH4 concentrations changed more frequently, and its fluctuations could reflect the temperature change sensitively.
