The additives such as phosphoric acid, calcium phosphate, calcium super phosphate, calcium over super phosphate, calcium carbonate, sodium hydrosulphite, etc. were used to produce furfural from the straw by hydrolys...The additives such as phosphoric acid, calcium phosphate, calcium super phosphate, calcium over super phosphate, calcium carbonate, sodium hydrosulphite, etc. were used to produce furfural from the straw by hydrolysis with sulfuric acid. The effect of amount of the additives, the content of the added substance and the conditions of distillation on the acidity of the residues were studied. The experiment results showed that the all residues became neutral complex fertilizer, and the productivity of furfural increases under the following conditions: sulfuric acid concentration is 20% (by weight), the ratio of liquid to solid is 3∶1—4∶1 (by weight), the ratio of the additives to straw is suitable.展开更多
The acidic wastewater containing manganese and other heavy metal ions came from the plant which produce titanium dioxide in the method of the sulfuric acid digestion was disposed under the processes of the pre\|neutra...The acidic wastewater containing manganese and other heavy metal ions came from the plant which produce titanium dioxide in the method of the sulfuric acid digestion was disposed under the processes of the pre\|neutralization with the mineral containing phosphorus and calcium, alkaline precipitation and re\|regulating pH with the raw wastewater. The removal ratio of manganese and ferrous were higher than 99% and 98%, respectively, when the concentration of manganese and ferrous were 46 mg/L and 2000 mg/L. More than 5800 mg/L of SO\+\{2-\}\-4 were neutralized also. The effluent pH was the range between 6 and 9, the concentration of other pollution substances were all very lower even have not discoveried.展开更多
Azo dye cationic blue X GRL, which is non biodegradable toxic organic compound, is decolorized and subsequently mineralized by UV/H 2O 2/N 2 or UV/H 2O 2/air (O 2) system. The effects of initial solution conce...Azo dye cationic blue X GRL, which is non biodegradable toxic organic compound, is decolorized and subsequently mineralized by UV/H 2O 2/N 2 or UV/H 2O 2/air (O 2) system. The effects of initial solution concentration, initial solution pH, and some ions produced during the degradation on the rate of decolorization of cationic blue X GRL were investigated. The photodegradation of cationic blue X GRL approximately follows first order kinetics. The regression curve of the natural logarithm of concentration verus reaction time becomes less linear with initial concentration increasing. Oxygen and appropriate OH\+· generator can accelerate reaction rate. The effect of reaction atmosphere, initial concentration, light intensity on the optimal dosage of H 2O 2 were studied. It was found that the optimal H 2O 2 dosage was determined by UV light intensity. These intermediates of cationic blue X GRL decolorization are biodegradable.展开更多
A solid phase extraction procedure of methomyl and thiodicarb from environmental water was presented. This method utilizes a 40—60 mesh activated carbon cartridge and high performance liquid chromatography (HPLC). Th...A solid phase extraction procedure of methomyl and thiodicarb from environmental water was presented. This method utilizes a 40—60 mesh activated carbon cartridge and high performance liquid chromatography (HPLC). The 40—60 mesh activated carbon works faster and yield higher adsorption efficiency. Detection limits of methomyl and thiodicarb in environmental water are 0 1 μg/L and 0 2 μg/L, respectively. Average recoveries of fortified methomyl and thiodicarb in water are in the range of 90 7%—98 8% and 88 9%—103 6%, respectively. The relative standard deviations are lower than 7%. This method is simple, rapid, accurate and precise.展开更多
A laboratory study was conducted to evaluate the suitability of a mixed surfactant for washing oil from soils in the unsaturated zone. The commercial surfactant used for making mixed surfactant were alcohol polyethoxy...A laboratory study was conducted to evaluate the suitability of a mixed surfactant for washing oil from soils in the unsaturated zone. The commercial surfactant used for making mixed surfactant were alcohol polyethoxylate (AEO\|9, nonionic) and sodium alcohol polyethoxylated ethers sulfate (AES, anionic). Based on the properties (critical micelle concentration, hydrophilic/ lipophilic balance and surface tension) of individual surfactants and the mixed surfactant, the preferred composition of an aqueous mixed surfactant solution was determined which consisted of 0 5% AEO\|9 and 0 1% AES. The batch washing experiments have shown that the removal efficiency of oil from soils with mixed surfactant was higher than that with individual surfactants. Soil column washing results have shown that the sequence of oil removal efficiency was mixed surfactant (0.5% AEO\|9 and 0.1% AES)>AEO\|9 (0.1%)>AES (0.2%)>water, and the ratio was 1∶0 84∶0 66∶0 06. Biodegradation experiments by growth cells and resting cells were carried out to evaluate the environmental acceptability of the test surfactants. The results have shown that the surfactants were able to serve as sole carbon source for strains Pseudomonos sp. 52 and Weeksella sp. 6 which were isolated from petroleum contaminated soil. More than 90% of the parent mixed surfactants disappeared in two weeks under growth cell conditions.展开更多
The analyses of water from four tributaries of Ikpa River: Afaha Nsai Stream (ANS), Ikot Ekpuk Stream (IES), Afaha Itam Stream(AIS) and Nduetong Stream (NDS) in International Telecommunication Union (ITU) Local Gover...The analyses of water from four tributaries of Ikpa River: Afaha Nsai Stream (ANS), Ikot Ekpuk Stream (IES), Afaha Itam Stream(AIS) and Nduetong Stream (NDS) in International Telecommunication Union (ITU) Local Government Area of Akawa Ibom State in Nigeria were carried out using standard analytical procedures. The parameters investigated were temperature(Temp.), hydrogen ion concentration(pH), total suspended solids (TSS), total dissolved solids (TDS), dissolved oxygen (DO) and biochemical oxygen demand (BOD). Correlation analysis carried out between pairs of variables showed that only the correlation coefficients between TDS and DO in ANS( p <0.05); Temp. and TDS in IES ( p <0.05) and between Temp. and TDS in AIS ( p <0.01) were significant. None of the pairs of the variables in NDS showed any significant correlation. The coefficients of variation for the parameters were also computed and used in determining their stability in the water. The possible effects of these variables on each other and on the aquatic ecosystem were discussed.展开更多
Tropical land snail (Achatina achatina) were collected from three areas viz.Nsit Ibom Local Government Area (NTB), Nsit Ubium Local Government Area (NTU) and Uyo Municipality (UYM), all in Akwa Ibom State to deter...Tropical land snail (Achatina achatina) were collected from three areas viz.Nsit Ibom Local Government Area (NTB), Nsit Ubium Local Government Area (NTU) and Uyo Municipality (UYM), all in Akwa Ibom State to determine the levels of Ni, Pb, Zn and Cr in their shells and muscles. Generally, the levels of all the metals in the muscles were comparatively higher than that in the shells. Correspondingly, the metals appear to have been more stable in the muscles with comparatively lower coefficients of variation than in the shells. Moreover while there was no significant correlation between the levels of all the metals in shells and muscles of NTU samples, Pb and Zn in NTB correlated very significantly. The correlation between levels of Cr in NTB samples and of Zn in UYM samples in shells and muscles were equally significant. On the whole, the levels of these metals were found to be much lower in both shells and muscles of NTU samples obtained from the “enclosed and restricted” environment than in NTB and UYM samples collected randomly from “open and unrestricted” environments.展开更多
The effluent from the pulping of E. urophylla by alkali sodium sulfite chemi mechanical process(AS-CMP) was characterized for its biodegradability by photosynthetic bacteria (PSB). Chemical coagulation post treat...The effluent from the pulping of E. urophylla by alkali sodium sulfite chemi mechanical process(AS-CMP) was characterized for its biodegradability by photosynthetic bacteria (PSB). Chemical coagulation post treatment of biotreated wastewater was also studied. One month continuous treatment in the laboratory indicated that the COD Cr , BOD 5 and SS removals in biotreatment stages reached 56%, 83% and 89% respectively, and the CH 2Cl 2 extractives decreased from 10.7 mg/L to 7.7 mg/L. In chemical coagulation post treatment stage, the effects of process conditions, such as coagulant dosage, pH value and the coordinated coagulation flocculation treatment of three kinds of coagulants on coagulation effectiveness were discussed. The optimum operating conditions were given.展开更多
Membrane fouling curtails severely the economical and practical implementation of membrane process. The fundamental principles and mechanisms of membrane fouling as well as factors affecting fouling have been summariz...Membrane fouling curtails severely the economical and practical implementation of membrane process. The fundamental principles and mechanisms of membrane fouling as well as factors affecting fouling have been summarized in this paper. It also has covered three fouling resistance models and four kinds of approaches to improve membrane performance. Membrane cleaning methods are also discussed including physical, chemical, physico\|chemical and biological methods. In the four groups of basic cleaning methods, biological cleaning has considerable advantages and potentials. Extensive research work should be carried out further to explore and develop new ideas and techniques in the field of membrane cleaning and restoration.展开更多
Based on geographical and hydrological extents delimited, four principles are identified, as the bases for delineating the ranges of the source regions of the Yangtze and Yellow rivers in the paper....Based on geographical and hydrological extents delimited, four principles are identified, as the bases for delineating the ranges of the source regions of the Yangtze and Yellow rivers in the paper. According to the comprehensive analysis of topographical characteristics, climate conditions, vegetation distribution and hydrological features, the source region ranges for eco-environmental study are defined. The eastern boundary point is Dari hydrological station in the upper reach of the Yellow River. The watershed above Dari hydrological station is the source region of the Yellow River which drains an area of 4.49×10 4 km 2 . Natural environment is characterized by the major topographical types of plateau lakes and marshland, gentle landforms, alpine cold semi-arid climate, and steppe and meadow vegetation in the source region of the Yellow River. The eastern boundary point is the convergent site of the Nieqiaqu and the Tongtian River in the upstream of the Yangtze River. The watershed above the convergent site is the source region of the Yangtze River, with a watershed area of 12.24×10 4 km 2 . Hills and alpine plain topography, gentle terrain, alpine cold arid and semi-arid climate, and alpine cold grassland and meadow are natural conditions in the source region of the Yangtze River.展开更多
In order to study the feasibility of treating petro chemical wastewater by the combination of anaerobic and aerobic biological process, a research of treating wastewater in UASB reactor and aeration basin has been co...In order to study the feasibility of treating petro chemical wastewater by the combination of anaerobic and aerobic biological process, a research of treating wastewater in UASB reactor and aeration basin has been conducted. The test results shows that under moderate temperature, with 5\^2 kgCOD/(m\+3·d) volumetric load of COD Cr in the UASB reactor and 24h of HRT, 85% removal rate of BOD 5 and 83% of COD \{Cr\} and 1\^34 m\+3/(m\+3·d) volumetric gas production rate can be obtained respectively. The aerobic bio degradability can be increased by 20%—30% after the petro chemical wastewater has been treated by anaerobic process. As Ns=0\^45 kgCOD/(kgMLSS·d), HRT=4h in the aeration tank, 94% removal rate of BOD 5, 93% of COD \{Cr\}, 98\^8% total removal rate of COD \{Cr\} and 99% removal rate of BOD 5 can be reached.展开更多
Destruction of trichloro ethylene (C 2HCl 3) by pulsed corona discharge reactor packed with alumina pellets and in absence of packing was investigated. Higher conversion of C 2HCl 3 was observed in presence of alu...Destruction of trichloro ethylene (C 2HCl 3) by pulsed corona discharge reactor packed with alumina pellets and in absence of packing was investigated. Higher conversion of C 2HCl 3 was observed in presence of alumina than in absence of packing. Furthermore CO/CO 2 ratio in the by products was found to shift in favor of CO 2 by alumina compared with absence of packing. Influence of catalyst porosity on C 2HCl 3 destruction and on by product ozone generation during the processing was also studied. Both alumina Ⅰ and alumina Ⅱ show similar improvement in C 2HCl 3 destruction. However, more important observation was that alumina Ⅰ produces higher by product ozone, while, alumina Ⅱ produces lower by product ozone, than in the case of no packing. The catalyst porosity effect was also investigated for destruction of toluene and was found to be similar. Intermediates of C 2HCl 3 destruction, as identified by GC MS, were COCl 2, CH 2Cl 2CHCl 3, CCl 4 and C 2HCl 5. In presence of alumina the amount of these intermediates was much reduced, indicating the catalytic function of alumina.展开更多
文摘The additives such as phosphoric acid, calcium phosphate, calcium super phosphate, calcium over super phosphate, calcium carbonate, sodium hydrosulphite, etc. were used to produce furfural from the straw by hydrolysis with sulfuric acid. The effect of amount of the additives, the content of the added substance and the conditions of distillation on the acidity of the residues were studied. The experiment results showed that the all residues became neutral complex fertilizer, and the productivity of furfural increases under the following conditions: sulfuric acid concentration is 20% (by weight), the ratio of liquid to solid is 3∶1—4∶1 (by weight), the ratio of the additives to straw is suitable.
文摘The acidic wastewater containing manganese and other heavy metal ions came from the plant which produce titanium dioxide in the method of the sulfuric acid digestion was disposed under the processes of the pre\|neutralization with the mineral containing phosphorus and calcium, alkaline precipitation and re\|regulating pH with the raw wastewater. The removal ratio of manganese and ferrous were higher than 99% and 98%, respectively, when the concentration of manganese and ferrous were 46 mg/L and 2000 mg/L. More than 5800 mg/L of SO\+\{2-\}\-4 were neutralized also. The effluent pH was the range between 6 and 9, the concentration of other pollution substances were all very lower even have not discoveried.
文摘Azo dye cationic blue X GRL, which is non biodegradable toxic organic compound, is decolorized and subsequently mineralized by UV/H 2O 2/N 2 or UV/H 2O 2/air (O 2) system. The effects of initial solution concentration, initial solution pH, and some ions produced during the degradation on the rate of decolorization of cationic blue X GRL were investigated. The photodegradation of cationic blue X GRL approximately follows first order kinetics. The regression curve of the natural logarithm of concentration verus reaction time becomes less linear with initial concentration increasing. Oxygen and appropriate OH\+· generator can accelerate reaction rate. The effect of reaction atmosphere, initial concentration, light intensity on the optimal dosage of H 2O 2 were studied. It was found that the optimal H 2O 2 dosage was determined by UV light intensity. These intermediates of cationic blue X GRL decolorization are biodegradable.
文摘A solid phase extraction procedure of methomyl and thiodicarb from environmental water was presented. This method utilizes a 40—60 mesh activated carbon cartridge and high performance liquid chromatography (HPLC). The 40—60 mesh activated carbon works faster and yield higher adsorption efficiency. Detection limits of methomyl and thiodicarb in environmental water are 0 1 μg/L and 0 2 μg/L, respectively. Average recoveries of fortified methomyl and thiodicarb in water are in the range of 90 7%—98 8% and 88 9%—103 6%, respectively. The relative standard deviations are lower than 7%. This method is simple, rapid, accurate and precise.
文摘A laboratory study was conducted to evaluate the suitability of a mixed surfactant for washing oil from soils in the unsaturated zone. The commercial surfactant used for making mixed surfactant were alcohol polyethoxylate (AEO\|9, nonionic) and sodium alcohol polyethoxylated ethers sulfate (AES, anionic). Based on the properties (critical micelle concentration, hydrophilic/ lipophilic balance and surface tension) of individual surfactants and the mixed surfactant, the preferred composition of an aqueous mixed surfactant solution was determined which consisted of 0 5% AEO\|9 and 0 1% AES. The batch washing experiments have shown that the removal efficiency of oil from soils with mixed surfactant was higher than that with individual surfactants. Soil column washing results have shown that the sequence of oil removal efficiency was mixed surfactant (0.5% AEO\|9 and 0.1% AES)>AEO\|9 (0.1%)>AES (0.2%)>water, and the ratio was 1∶0 84∶0 66∶0 06. Biodegradation experiments by growth cells and resting cells were carried out to evaluate the environmental acceptability of the test surfactants. The results have shown that the surfactants were able to serve as sole carbon source for strains Pseudomonos sp. 52 and Weeksella sp. 6 which were isolated from petroleum contaminated soil. More than 90% of the parent mixed surfactants disappeared in two weeks under growth cell conditions.
文摘The analyses of water from four tributaries of Ikpa River: Afaha Nsai Stream (ANS), Ikot Ekpuk Stream (IES), Afaha Itam Stream(AIS) and Nduetong Stream (NDS) in International Telecommunication Union (ITU) Local Government Area of Akawa Ibom State in Nigeria were carried out using standard analytical procedures. The parameters investigated were temperature(Temp.), hydrogen ion concentration(pH), total suspended solids (TSS), total dissolved solids (TDS), dissolved oxygen (DO) and biochemical oxygen demand (BOD). Correlation analysis carried out between pairs of variables showed that only the correlation coefficients between TDS and DO in ANS( p <0.05); Temp. and TDS in IES ( p <0.05) and between Temp. and TDS in AIS ( p <0.01) were significant. None of the pairs of the variables in NDS showed any significant correlation. The coefficients of variation for the parameters were also computed and used in determining their stability in the water. The possible effects of these variables on each other and on the aquatic ecosystem were discussed.
文摘Tropical land snail (Achatina achatina) were collected from three areas viz.Nsit Ibom Local Government Area (NTB), Nsit Ubium Local Government Area (NTU) and Uyo Municipality (UYM), all in Akwa Ibom State to determine the levels of Ni, Pb, Zn and Cr in their shells and muscles. Generally, the levels of all the metals in the muscles were comparatively higher than that in the shells. Correspondingly, the metals appear to have been more stable in the muscles with comparatively lower coefficients of variation than in the shells. Moreover while there was no significant correlation between the levels of all the metals in shells and muscles of NTU samples, Pb and Zn in NTB correlated very significantly. The correlation between levels of Cr in NTB samples and of Zn in UYM samples in shells and muscles were equally significant. On the whole, the levels of these metals were found to be much lower in both shells and muscles of NTU samples obtained from the “enclosed and restricted” environment than in NTB and UYM samples collected randomly from “open and unrestricted” environments.
文摘The effluent from the pulping of E. urophylla by alkali sodium sulfite chemi mechanical process(AS-CMP) was characterized for its biodegradability by photosynthetic bacteria (PSB). Chemical coagulation post treatment of biotreated wastewater was also studied. One month continuous treatment in the laboratory indicated that the COD Cr , BOD 5 and SS removals in biotreatment stages reached 56%, 83% and 89% respectively, and the CH 2Cl 2 extractives decreased from 10.7 mg/L to 7.7 mg/L. In chemical coagulation post treatment stage, the effects of process conditions, such as coagulant dosage, pH value and the coordinated coagulation flocculation treatment of three kinds of coagulants on coagulation effectiveness were discussed. The optimum operating conditions were given.
文摘Membrane fouling curtails severely the economical and practical implementation of membrane process. The fundamental principles and mechanisms of membrane fouling as well as factors affecting fouling have been summarized in this paper. It also has covered three fouling resistance models and four kinds of approaches to improve membrane performance. Membrane cleaning methods are also discussed including physical, chemical, physico\|chemical and biological methods. In the four groups of basic cleaning methods, biological cleaning has considerable advantages and potentials. Extensive research work should be carried out further to explore and develop new ideas and techniques in the field of membrane cleaning and restoration.
基金Knowledge Innovation Project of CAS No. KZCX1-10-06
文摘Based on geographical and hydrological extents delimited, four principles are identified, as the bases for delineating the ranges of the source regions of the Yangtze and Yellow rivers in the paper. According to the comprehensive analysis of topographical characteristics, climate conditions, vegetation distribution and hydrological features, the source region ranges for eco-environmental study are defined. The eastern boundary point is Dari hydrological station in the upper reach of the Yellow River. The watershed above Dari hydrological station is the source region of the Yellow River which drains an area of 4.49×10 4 km 2 . Natural environment is characterized by the major topographical types of plateau lakes and marshland, gentle landforms, alpine cold semi-arid climate, and steppe and meadow vegetation in the source region of the Yellow River. The eastern boundary point is the convergent site of the Nieqiaqu and the Tongtian River in the upstream of the Yangtze River. The watershed above the convergent site is the source region of the Yangtze River, with a watershed area of 12.24×10 4 km 2 . Hills and alpine plain topography, gentle terrain, alpine cold arid and semi-arid climate, and alpine cold grassland and meadow are natural conditions in the source region of the Yangtze River.
文摘In order to study the feasibility of treating petro chemical wastewater by the combination of anaerobic and aerobic biological process, a research of treating wastewater in UASB reactor and aeration basin has been conducted. The test results shows that under moderate temperature, with 5\^2 kgCOD/(m\+3·d) volumetric load of COD Cr in the UASB reactor and 24h of HRT, 85% removal rate of BOD 5 and 83% of COD \{Cr\} and 1\^34 m\+3/(m\+3·d) volumetric gas production rate can be obtained respectively. The aerobic bio degradability can be increased by 20%—30% after the petro chemical wastewater has been treated by anaerobic process. As Ns=0\^45 kgCOD/(kgMLSS·d), HRT=4h in the aeration tank, 94% removal rate of BOD 5, 93% of COD \{Cr\}, 98\^8% total removal rate of COD \{Cr\} and 99% removal rate of BOD 5 can be reached.
文摘Destruction of trichloro ethylene (C 2HCl 3) by pulsed corona discharge reactor packed with alumina pellets and in absence of packing was investigated. Higher conversion of C 2HCl 3 was observed in presence of alumina than in absence of packing. Furthermore CO/CO 2 ratio in the by products was found to shift in favor of CO 2 by alumina compared with absence of packing. Influence of catalyst porosity on C 2HCl 3 destruction and on by product ozone generation during the processing was also studied. Both alumina Ⅰ and alumina Ⅱ show similar improvement in C 2HCl 3 destruction. However, more important observation was that alumina Ⅰ produces higher by product ozone, while, alumina Ⅱ produces lower by product ozone, than in the case of no packing. The catalyst porosity effect was also investigated for destruction of toluene and was found to be similar. Intermediates of C 2HCl 3 destruction, as identified by GC MS, were COCl 2, CH 2Cl 2CHCl 3, CCl 4 and C 2HCl 5. In presence of alumina the amount of these intermediates was much reduced, indicating the catalytic function of alumina.
