A three-wave based laser polarimeter/interferometer and a CO_(2)laser dispersion interferometer are used to determine the electron and current density profiles on a Chinese fusion engineering test reactor(CFETR).Radia...A three-wave based laser polarimeter/interferometer and a CO_(2)laser dispersion interferometer are used to determine the electron and current density profiles on a Chinese fusion engineering test reactor(CFETR).Radiation shielding is designed for the combination of polarimeter/interferometer and CO_(2)dispersion interferometer.Furthermore,neutronics models of the two systems are developed based on the engineering-integrated design of CFETR polarimeter/interferometer and CO_(2)dispersion interferometer and the major material components of CFETR.The polarimeter/interferometer and CO_(2)dispersion interferometer's neutron and photon transport simulations were performed using the Monte Carlo neutral transport code to determine the energy deposition and neutron energy spectrum of the optical mirrors.The energy depositions of the first mirrors on the polarimeter/interferometer are reduced by three orders with the whole shielding.Since the mirrors of CO_(2)dispersion interferometer are very close to the diagnostic first wall,shielding space is limited and the CO_(2)dispersion interferometer energy deposition is higher than that of the polarimeter/interferometer.The dose rate after shutdown106s in the back-drawer structure has been estimated to be 83μSv h^(-1)when the radiation shield is filled in the diagnostic shielding modules,which is below the design threshold of 100μSv h^(-1).Radiation shielding design plays a key role in successfully applying polarimeter/interferometer and CO_(2)dispersive interferometer in CFETR.展开更多
水气分散体系驱油技术是针对低渗透油田采出程度低研发的新型提高采收率技术,目前已在长庆油田取得明显增油效果,但分散体系中微气泡与孔隙作用复杂,对其微观驱油机理的研究正逐步深入。根据低渗透、非均质岩心的特点,制作边长为1.5 cm...水气分散体系驱油技术是针对低渗透油田采出程度低研发的新型提高采收率技术,目前已在长庆油田取得明显增油效果,但分散体系中微气泡与孔隙作用复杂,对其微观驱油机理的研究正逐步深入。根据低渗透、非均质岩心的特点,制作边长为1.5 cm的玻璃刻蚀模型,在油藏温压条件下,进行CO_(2)-水分散体系渗流实验。通过观察微气泡与油、水、岩石相互作用过程,获取气泡吸附能力、推动油膜能力、气泡弹性能量等数据,进而定量表征分析驱油效果。实验结果表明:微气泡与油界面结合,具有特殊的吸附油膜现象,与水驱、气驱等作用机理显著不同。驱替过程相邻气泡间的合并也促进了油膜汇聚,同时微气泡的合并有助于气泡的流动,使吸附在气泡表面的油膜随气泡运移。微气泡运移时,气泡体积因压力降低而膨胀,所释放的弹性能量能够推动吸附在壁面的油膜运移。此外,采用Volume of Fluid多相流模型,对水气分散体系中微气泡推动油膜的运移过程进行模拟及分析,得到驱替油膜的主要因素是微气泡形变产生的弹性能量和微气泡自身的能量。气泡的能量作用在气泡前缘,通过与油膜表面接触产生推动作用。展开更多
Electrochemical carbon dioxide reduction reaction(CO_(2)RR)involves a variety of intermediates with highly correlated reaction and ad-desorption energies,hindering optimization of the catalytic activity.For example,in...Electrochemical carbon dioxide reduction reaction(CO_(2)RR)involves a variety of intermediates with highly correlated reaction and ad-desorption energies,hindering optimization of the catalytic activity.For example,increasing the binding of the*COOH to the active site will generally increase the*CO desorption energy.Breaking this relationship may be expected to dramatically improve the intrinsic activity of CO_(2)RR,but remains an unsolved challenge.Herein,we addressed this conundrum by constructing a unique atomic dispersed hetero-pair consisting of Mo-Fe di-atoms anchored on N-doped carbon carrier.This system shows an unprecedented CO_(2)RR intrinsic activity with TOF of 3336 h−1,high selectivity toward CO production,Faradaic efficiency of 95.96%at−0.60 V and excellent stability.Theoretical calculations show that the Mo-Fe diatomic sites increased the*COOH intermediate adsorption energy by bridging adsorption of*COOH intermediates.At the same time,d-d orbital coupling in the Mo-Fe di-atom results in electron delocalization and facilitates desorption of*CO intermediates.Thus,the undesirable correlation between these steps is broken.This work provides a promising approach,specifically the use of di-atoms,for breaking unfavorable relationships based on understanding of the catalytic mechanisms at the atomic scale.展开更多
A new CO2 laser dispersion interferometer has been developed in the HL-2 M tokamak to measure the electron density.In order to meet the needs of high-precision measurement,a data acquisition system with real-time sign...A new CO2 laser dispersion interferometer has been developed in the HL-2 M tokamak to measure the electron density.In order to meet the needs of high-precision measurement,a data acquisition system with real-time signal conditioning(RSC)method is proposed.It can eliminate part of the impacts of environmental factors,such as mechanical vibration,light path changes,and plasma refraction effect during experiments.In harsh environments,the system can measure the line-integrated density with a high precision of 2×10^18 m^-2 with the RSC method.The system has been tested in a recent HL-2 A experimental campaign,and the results show that the RSC method plays an important role in the plasma electron density measurement.展开更多
CO_(2)emission mitigation is one of the most critical research frontiers.As a promising option of carbon capture,utilization and storage(CCUS),CO_(2)storage with enhanced gas recovery(CSEGR)can reduce CO_(2)emission b...CO_(2)emission mitigation is one of the most critical research frontiers.As a promising option of carbon capture,utilization and storage(CCUS),CO_(2)storage with enhanced gas recovery(CSEGR)can reduce CO_(2)emission by sequestrating it into gas reservoirs and simultaneously enhance natural gas production.Over the past decades,the displacement behaviour of CO_(2)—natural gas has been extensively studied and demonstrated to play a key role on both CO_(2)geologic storage and gas recovery performance.This work thoroughly and critically reviews the experimental and numerical simulation studies of CO_(2)displacing natural gas,along with both CSEGR research and demonstration projects at various scales.The physical property difference between CO_(2)and natural gas,especially density and viscosity,lays the foundation of CSEGR.Previous experiments on displacement behaviour and dispersion characteristics of CO_(2)/natural gas revealed the fundamental mixing characteristics in porous media,which is one key factor of gas recovery efficiency and warrants further study.Preliminary numerical simulations demonstrated that it is technically and economically feasible to apply CSEGR in depleted gas reservoirs.However,CO_(2)preferential flow pathways are easy to form(due to reservoir heterogeneity)and thus adversely compromise CSEGR performance.This preferential flow can be slowed down by connate or injected water.Additionally,the optimization of CO_(2)injection strategies is essential for improving gas recovery and CO_(2)storage,which needs further study.The successful K12—B pilot project provides insightful field-scale knowledge and experience,which paves a good foundation for commercial application.More experiments,simulations,research and demonstration projects are needed to facilitate the maturation of the CSEGR technology.展开更多
基金the National MCF Energy R&D Program of China(Nos.2019YFE03040003 and 2017YFE0301205)Key Program of Research and Development of Hefei Science Center,CAS(No.2019HSC-KPRD001)supported in part by the Collaborative Research Program of the Research Institute for Applied Mechanics,Kyushu University。
文摘A three-wave based laser polarimeter/interferometer and a CO_(2)laser dispersion interferometer are used to determine the electron and current density profiles on a Chinese fusion engineering test reactor(CFETR).Radiation shielding is designed for the combination of polarimeter/interferometer and CO_(2)dispersion interferometer.Furthermore,neutronics models of the two systems are developed based on the engineering-integrated design of CFETR polarimeter/interferometer and CO_(2)dispersion interferometer and the major material components of CFETR.The polarimeter/interferometer and CO_(2)dispersion interferometer's neutron and photon transport simulations were performed using the Monte Carlo neutral transport code to determine the energy deposition and neutron energy spectrum of the optical mirrors.The energy depositions of the first mirrors on the polarimeter/interferometer are reduced by three orders with the whole shielding.Since the mirrors of CO_(2)dispersion interferometer are very close to the diagnostic first wall,shielding space is limited and the CO_(2)dispersion interferometer energy deposition is higher than that of the polarimeter/interferometer.The dose rate after shutdown106s in the back-drawer structure has been estimated to be 83μSv h^(-1)when the radiation shield is filled in the diagnostic shielding modules,which is below the design threshold of 100μSv h^(-1).Radiation shielding design plays a key role in successfully applying polarimeter/interferometer and CO_(2)dispersive interferometer in CFETR.
文摘水气分散体系驱油技术是针对低渗透油田采出程度低研发的新型提高采收率技术,目前已在长庆油田取得明显增油效果,但分散体系中微气泡与孔隙作用复杂,对其微观驱油机理的研究正逐步深入。根据低渗透、非均质岩心的特点,制作边长为1.5 cm的玻璃刻蚀模型,在油藏温压条件下,进行CO_(2)-水分散体系渗流实验。通过观察微气泡与油、水、岩石相互作用过程,获取气泡吸附能力、推动油膜能力、气泡弹性能量等数据,进而定量表征分析驱油效果。实验结果表明:微气泡与油界面结合,具有特殊的吸附油膜现象,与水驱、气驱等作用机理显著不同。驱替过程相邻气泡间的合并也促进了油膜汇聚,同时微气泡的合并有助于气泡的流动,使吸附在气泡表面的油膜随气泡运移。微气泡运移时,气泡体积因压力降低而膨胀,所释放的弹性能量能够推动吸附在壁面的油膜运移。此外,采用Volume of Fluid多相流模型,对水气分散体系中微气泡推动油膜的运移过程进行模拟及分析,得到驱替油膜的主要因素是微气泡形变产生的弹性能量和微气泡自身的能量。气泡的能量作用在气泡前缘,通过与油膜表面接触产生推动作用。
基金the National Natural Science Foundation of China(22279044,12034002,and 22202080)the Project for Self-Innovation Capability Construction of Jilin Province Development and Reform Commission(2021C026)+1 种基金Jilin Province Science and Technology Development Program(20210301009GX)the Fundamental Research Funds for the Central Universities.
文摘Electrochemical carbon dioxide reduction reaction(CO_(2)RR)involves a variety of intermediates with highly correlated reaction and ad-desorption energies,hindering optimization of the catalytic activity.For example,increasing the binding of the*COOH to the active site will generally increase the*CO desorption energy.Breaking this relationship may be expected to dramatically improve the intrinsic activity of CO_(2)RR,but remains an unsolved challenge.Herein,we addressed this conundrum by constructing a unique atomic dispersed hetero-pair consisting of Mo-Fe di-atoms anchored on N-doped carbon carrier.This system shows an unprecedented CO_(2)RR intrinsic activity with TOF of 3336 h−1,high selectivity toward CO production,Faradaic efficiency of 95.96%at−0.60 V and excellent stability.Theoretical calculations show that the Mo-Fe diatomic sites increased the*COOH intermediate adsorption energy by bridging adsorption of*COOH intermediates.At the same time,d-d orbital coupling in the Mo-Fe di-atom results in electron delocalization and facilitates desorption of*CO intermediates.Thus,the undesirable correlation between these steps is broken.This work provides a promising approach,specifically the use of di-atoms,for breaking unfavorable relationships based on understanding of the catalytic mechanisms at the atomic scale.
文摘A new CO2 laser dispersion interferometer has been developed in the HL-2 M tokamak to measure the electron density.In order to meet the needs of high-precision measurement,a data acquisition system with real-time signal conditioning(RSC)method is proposed.It can eliminate part of the impacts of environmental factors,such as mechanical vibration,light path changes,and plasma refraction effect during experiments.In harsh environments,the system can measure the line-integrated density with a high precision of 2×10^18 m^-2 with the RSC method.The system has been tested in a recent HL-2 A experimental campaign,and the results show that the RSC method plays an important role in the plasma electron density measurement.
基金financially supported by the National Natural Science Foundation of China(51906256 and 52074337)Fundamental Research Funds for the Central Universities(21CX06033A)
文摘CO_(2)emission mitigation is one of the most critical research frontiers.As a promising option of carbon capture,utilization and storage(CCUS),CO_(2)storage with enhanced gas recovery(CSEGR)can reduce CO_(2)emission by sequestrating it into gas reservoirs and simultaneously enhance natural gas production.Over the past decades,the displacement behaviour of CO_(2)—natural gas has been extensively studied and demonstrated to play a key role on both CO_(2)geologic storage and gas recovery performance.This work thoroughly and critically reviews the experimental and numerical simulation studies of CO_(2)displacing natural gas,along with both CSEGR research and demonstration projects at various scales.The physical property difference between CO_(2)and natural gas,especially density and viscosity,lays the foundation of CSEGR.Previous experiments on displacement behaviour and dispersion characteristics of CO_(2)/natural gas revealed the fundamental mixing characteristics in porous media,which is one key factor of gas recovery efficiency and warrants further study.Preliminary numerical simulations demonstrated that it is technically and economically feasible to apply CSEGR in depleted gas reservoirs.However,CO_(2)preferential flow pathways are easy to form(due to reservoir heterogeneity)and thus adversely compromise CSEGR performance.This preferential flow can be slowed down by connate or injected water.Additionally,the optimization of CO_(2)injection strategies is essential for improving gas recovery and CO_(2)storage,which needs further study.The successful K12—B pilot project provides insightful field-scale knowledge and experience,which paves a good foundation for commercial application.More experiments,simulations,research and demonstration projects are needed to facilitate the maturation of the CSEGR technology.
