The Co_(3)O_(4)nanoparticles,dominated by a catalytically active(110)lattice plane,were synthesized as a low-temperature NO_(x) adsorbent to control the cold start emissions from vehicles.These nanoparticles boast a s...The Co_(3)O_(4)nanoparticles,dominated by a catalytically active(110)lattice plane,were synthesized as a low-temperature NO_(x) adsorbent to control the cold start emissions from vehicles.These nanoparticles boast a substantial quantity of active chemisorbed oxygen and lattice oxygen,which exhibited a NO_(x) uptake capacity commensurate with Pd/SSZ-13 at 100℃.The primary NO_(x) release temperature falls within a temperature range of 200-350℃,making it perfectly suitable for diesel engines.The characterization results demonstrate that chemisorbed oxygen facilitate nitro/nitrites intermediates formation,contributing to the NO_(x) storage at 100℃,while the nitrites begin to decompose within the 150-200℃range.Fortunately,lattice oxygen likely becomes involved in the activation of nitrites into more stable nitrate within this particular temperature range.The concurrent processes of nitrites decomposition and its conversion to nitrates results in a minimal NO_(x) release between the temperatures of 150-200℃.The nitrate formed via lattice oxygen mainly induces the NO_(x) to be released as NO_(2) within a temperature range of 200-350℃,which is advantageous in enhancing the NO_(x) activity of downstream NH_(3)-SCR catalysts,by boosting the fast SCR reaction pathway.Thanks to its low cost,considerable NO_(x) absorption capacity,and optimal release temperature,Co_(3)O_(4)demonstrates potential as an effective material for passive NO_(x) adsorber applications.展开更多
Coal-fired power plants are a major carbon source in China. In order to assess the evaluation of China's carbon reduction progress with the promise made on the Paris Agreement, it is crucial to monitor the carbon ...Coal-fired power plants are a major carbon source in China. In order to assess the evaluation of China's carbon reduction progress with the promise made on the Paris Agreement, it is crucial to monitor the carbon flux intensity from coal-fired power plants. Previous studies have calculated CO_(2) emissions from point sources based on Orbiting Carbon Observatory-2 and-3(OCO-2 and OCO-3) satellite measurements, but the factors affecting CO_(2) flux estimations are uncertain. In this study, we employ a Gaussian Plume Model to estimate CO_(2) emissions from three power plants in China based on OCO-3 XCO_(2) measurements. Moreover, flux uncertainties resulting from wind information, background values,satellite CO_(2) measurements, and atmospheric stability are discussed. This study highlights the CO_(2) flux uncertainty derived from the satellite measurements. Finally, satellite-based CO_(2) emission estimates are compared to bottom-up inventories.The satellite-based CO_(2) emission estimates at the Tuoketuo and Nongliushi power plants are ~30 and ~10 kt d^(-1) smaller than the Open-Data Inventory for Anthropogenic Carbon dioxide(ODIAC) respectively, but ~10 kt d^(-1) larger than the ODIAC at Baotou.展开更多
Investing in projects that support environmental benefits,such as tree harvesting,has the potential to reduce air pollution levels in the atmosphere in the future.However,this kind of investment may increase the curre...Investing in projects that support environmental benefits,such as tree harvesting,has the potential to reduce air pollution levels in the atmosphere in the future.However,this kind of investment may increase the current level of emissions.Therefore,it is necessary to estimate how much the policy affects the current level of CO_(2) emissions.This makes sure the policy doesn’t increase the level of CO_(2) emis-sions.This study aims to analyze the effect of the One Bil-lion Trees program on CO_(2) emissions in New Zealand by employing the 2020 input–output table analysis.This inves-tigation examines the direct and indirect effects of policy on both the demand and supply sides across six regions of New Zealand.The results of this study for the first year of plantation suggest that the policy increases the level of CO_(2) emissions in all regions,especially in the Waikato region.The direct and indirect impact of the policy leads to 64 kt of CO_(2) emissions on the demand side and 270 kt of CO_(2) emis-sions on the supply side.These lead to 0.19 and 0.74%of total CO_(2) emissions being attributed to investment shocks.Continuing the policy is recommended,as it has a low effect on CO_(2) emissions.However,it is crucial to prioritize the use of low-carbon machinery that uses fossil fuels during the plantation process.展开更多
Carbon emissions have become a critical concern in the global effort to combat climate change,with each country or region contributing differently based on its economic structures,energy sources,and industrial activit...Carbon emissions have become a critical concern in the global effort to combat climate change,with each country or region contributing differently based on its economic structures,energy sources,and industrial activities.The factors influencing carbon emissions vary across countries and sectors.This study examined the factors influencing CO_(2)emissions in the 7 South American countries including Argentina,Brazil,Chile,Colombia,Ecuador,Peru,and Venezuela.We used the Seemingly Unrelated Regression(SUR)model to analyse the relationship of CO_(2)emissions with gross domestic product(GDP),renewable energy use,urbanization,industrialization,international tourism,agricultural productivity,and forest area based on data from 2000 to 2022.According to the SUR model,we found that GDP and industrialization had a moderate positive effect on CO_(2)emissions,whereas renewable energy use had a moderate negative effect on CO_(2)emissions.International tourism generally had a positive impact on CO_(2)emissions,while forest area tended to decrease CO_(2)emissions.Different variables had different effects on CO_(2)emissions in the 7 South American countries.In Argentina and Venezuela,GDP,international tourism,and agricultural productivity significantly affected CO_(2)emissions.In Colombia,GDP and international tourism had a negative impact on CO_(2)emissions.In Brazil,CO_(2)emissions were primarily driven by GDP,while in Chile,Ecuador,and Peru,international tourism had a negative effect on CO_(2)emissions.Overall,this study highlights the importance of country-specific strategies for reducing CO_(2)emissions and emphasizes the varying roles of these driving factors in shaping environmental quality in the 7 South American countries.展开更多
Urban areas globally are escalating contributors to carbon dioxide(CO_(2))emissions,challenging sustainable development.This study proposes a novel micro-scale approach utilizing GIS to quantify CO_(2)emission spatial...Urban areas globally are escalating contributors to carbon dioxide(CO_(2))emissions,challenging sustainable development.This study proposes a novel micro-scale approach utilizing GIS to quantify CO_(2)emission spatial distribution,enhancing urban sustainability assessment.Employing a“bottom-up”methodology,emissions were calculated for various sources,revealing Isfahan’s urban area emits 13,855,525 tons of CO_(2)annually.Major contributors include stationary and mobile sources such as power plants(50.61%),road and rail transport(17.18%),and residential sectors(21.78%).Spatial distribution mapping showed that 81.68%of CO_(2)emissions originate from stationary sources,notably power plants.Furthermore,mobile sources,including road transport,contribute 17.16%,with emissions concentrated in main urban arteries.Agricultural machinery adds 1.14%of emissions,spatially distributed across Isfahan’s agricultural lands.Integration of emissions maps depicts the city’s total CO_(2)emissions,highlighting sectoral contributions.Despite limitations in data granularity,this study provides valuable insights into urban CO_(2)emissions dynamics,facilitating targeted mitigation strategies.Quantitative achievements include precise CO_(2)emission quantification and spatial distribution mapping,crucial for formulating effective urban sustainability policies.展开更多
基金supported by the National Natural Science Foundation of China(22006044,22006043)External Cooperation Program of Science and Technology Planning of Fujian Province(2023I0018)+2 种基金the Fujian Province Science and Technology Program Funds(2020H6013)the National Engineering Laboratory for Mobile Source Emission Control Technology(NELMS2020A03)the Scientific Research Funds of Huaqiao University(605-50Y200270001)。
文摘The Co_(3)O_(4)nanoparticles,dominated by a catalytically active(110)lattice plane,were synthesized as a low-temperature NO_(x) adsorbent to control the cold start emissions from vehicles.These nanoparticles boast a substantial quantity of active chemisorbed oxygen and lattice oxygen,which exhibited a NO_(x) uptake capacity commensurate with Pd/SSZ-13 at 100℃.The primary NO_(x) release temperature falls within a temperature range of 200-350℃,making it perfectly suitable for diesel engines.The characterization results demonstrate that chemisorbed oxygen facilitate nitro/nitrites intermediates formation,contributing to the NO_(x) storage at 100℃,while the nitrites begin to decompose within the 150-200℃range.Fortunately,lattice oxygen likely becomes involved in the activation of nitrites into more stable nitrate within this particular temperature range.The concurrent processes of nitrites decomposition and its conversion to nitrates results in a minimal NO_(x) release between the temperatures of 150-200℃.The nitrate formed via lattice oxygen mainly induces the NO_(x) to be released as NO_(2) within a temperature range of 200-350℃,which is advantageous in enhancing the NO_(x) activity of downstream NH_(3)-SCR catalysts,by boosting the fast SCR reaction pathway.Thanks to its low cost,considerable NO_(x) absorption capacity,and optimal release temperature,Co_(3)O_(4)demonstrates potential as an effective material for passive NO_(x) adsorber applications.
基金supported by the Shanghai Sailing Program (Grant No. 22YF1442000)the Key Laboratory of Middle Atmosphere and Global Environment Observation(Grant No. LAGEO-2021-07)+1 种基金the National Natural Science Foundation of China (Grant No. 41975035)Jiaxing University (Grant Nos. 00323027AL and CD70522035)。
文摘Coal-fired power plants are a major carbon source in China. In order to assess the evaluation of China's carbon reduction progress with the promise made on the Paris Agreement, it is crucial to monitor the carbon flux intensity from coal-fired power plants. Previous studies have calculated CO_(2) emissions from point sources based on Orbiting Carbon Observatory-2 and-3(OCO-2 and OCO-3) satellite measurements, but the factors affecting CO_(2) flux estimations are uncertain. In this study, we employ a Gaussian Plume Model to estimate CO_(2) emissions from three power plants in China based on OCO-3 XCO_(2) measurements. Moreover, flux uncertainties resulting from wind information, background values,satellite CO_(2) measurements, and atmospheric stability are discussed. This study highlights the CO_(2) flux uncertainty derived from the satellite measurements. Finally, satellite-based CO_(2) emission estimates are compared to bottom-up inventories.The satellite-based CO_(2) emission estimates at the Tuoketuo and Nongliushi power plants are ~30 and ~10 kt d^(-1) smaller than the Open-Data Inventory for Anthropogenic Carbon dioxide(ODIAC) respectively, but ~10 kt d^(-1) larger than the ODIAC at Baotou.
基金Open Access funding enabled and organized by CAUL and its Member Institutions
文摘Investing in projects that support environmental benefits,such as tree harvesting,has the potential to reduce air pollution levels in the atmosphere in the future.However,this kind of investment may increase the current level of emissions.Therefore,it is necessary to estimate how much the policy affects the current level of CO_(2) emissions.This makes sure the policy doesn’t increase the level of CO_(2) emis-sions.This study aims to analyze the effect of the One Bil-lion Trees program on CO_(2) emissions in New Zealand by employing the 2020 input–output table analysis.This inves-tigation examines the direct and indirect effects of policy on both the demand and supply sides across six regions of New Zealand.The results of this study for the first year of plantation suggest that the policy increases the level of CO_(2) emissions in all regions,especially in the Waikato region.The direct and indirect impact of the policy leads to 64 kt of CO_(2) emissions on the demand side and 270 kt of CO_(2) emis-sions on the supply side.These lead to 0.19 and 0.74%of total CO_(2) emissions being attributed to investment shocks.Continuing the policy is recommended,as it has a low effect on CO_(2) emissions.However,it is crucial to prioritize the use of low-carbon machinery that uses fossil fuels during the plantation process.
文摘Carbon emissions have become a critical concern in the global effort to combat climate change,with each country or region contributing differently based on its economic structures,energy sources,and industrial activities.The factors influencing carbon emissions vary across countries and sectors.This study examined the factors influencing CO_(2)emissions in the 7 South American countries including Argentina,Brazil,Chile,Colombia,Ecuador,Peru,and Venezuela.We used the Seemingly Unrelated Regression(SUR)model to analyse the relationship of CO_(2)emissions with gross domestic product(GDP),renewable energy use,urbanization,industrialization,international tourism,agricultural productivity,and forest area based on data from 2000 to 2022.According to the SUR model,we found that GDP and industrialization had a moderate positive effect on CO_(2)emissions,whereas renewable energy use had a moderate negative effect on CO_(2)emissions.International tourism generally had a positive impact on CO_(2)emissions,while forest area tended to decrease CO_(2)emissions.Different variables had different effects on CO_(2)emissions in the 7 South American countries.In Argentina and Venezuela,GDP,international tourism,and agricultural productivity significantly affected CO_(2)emissions.In Colombia,GDP and international tourism had a negative impact on CO_(2)emissions.In Brazil,CO_(2)emissions were primarily driven by GDP,while in Chile,Ecuador,and Peru,international tourism had a negative effect on CO_(2)emissions.Overall,this study highlights the importance of country-specific strategies for reducing CO_(2)emissions and emphasizes the varying roles of these driving factors in shaping environmental quality in the 7 South American countries.
文摘Urban areas globally are escalating contributors to carbon dioxide(CO_(2))emissions,challenging sustainable development.This study proposes a novel micro-scale approach utilizing GIS to quantify CO_(2)emission spatial distribution,enhancing urban sustainability assessment.Employing a“bottom-up”methodology,emissions were calculated for various sources,revealing Isfahan’s urban area emits 13,855,525 tons of CO_(2)annually.Major contributors include stationary and mobile sources such as power plants(50.61%),road and rail transport(17.18%),and residential sectors(21.78%).Spatial distribution mapping showed that 81.68%of CO_(2)emissions originate from stationary sources,notably power plants.Furthermore,mobile sources,including road transport,contribute 17.16%,with emissions concentrated in main urban arteries.Agricultural machinery adds 1.14%of emissions,spatially distributed across Isfahan’s agricultural lands.Integration of emissions maps depicts the city’s total CO_(2)emissions,highlighting sectoral contributions.Despite limitations in data granularity,this study provides valuable insights into urban CO_(2)emissions dynamics,facilitating targeted mitigation strategies.Quantitative achievements include precise CO_(2)emission quantification and spatial distribution mapping,crucial for formulating effective urban sustainability policies.
