Temperature-swing adsorption(TSA)is an effective technique for CO_(2) capture,but the temperature swing procedure is energy-intensive.Herein,we report a low-energy-consumption system by combining passive radiative coo...Temperature-swing adsorption(TSA)is an effective technique for CO_(2) capture,but the temperature swing procedure is energy-intensive.Herein,we report a low-energy-consumption system by combining passive radiative cooling and solar heating for the uptake of CO_(2) on commercial activated carbons(CACs).During adsorption,the adsorbents are coated with a layer of hierarchically porous poly(vinylidene fluoride-co-hexafluoropropene)[P(VdF-HFP)HP],which cools the adsorbents to a low temperature under sunlight through radiative cooling.For desorption,CACs with broad absorption of the solar spectrum are exposed to light irradiation for heating.The heating and cooling processes are completely driven by solar energy.Adsorption tests under mimicked sunlight using the CACs show that the performance of this system is comparable to that of the traditional ones.Furthermore,under real sunlight irradiation,the adsorption capacity of the CACs can be well maintained after multiple cycles.The present work may inspire the development of new temperature swing procedures with little energy consumption.展开更多
Foam stability tests were performed using sodium dodecyl sulfate(SDS)surfactant and SiO2 nanoparticles as foaming system at different asphaltene concentrations,and the half-life of CO_(2) foam was measured.The mechani...Foam stability tests were performed using sodium dodecyl sulfate(SDS)surfactant and SiO2 nanoparticles as foaming system at different asphaltene concentrations,and the half-life of CO_(2) foam was measured.The mechanism of foam stability reduction in the presence of asphaltene was analyzed by scanning electron microscope(SEM),UV adsorption spectrophotometric concentration measurement and Zeta potential measurement.When the mass ratio of synthetic oil to foam-formation suspension was 1:9 and the asphaltene mass fraction increased from 0 to 15%,the half-life of SDS-stabilized foams decreased from 751 s to 239 s,and the half-life of SDS/silica-stabilized foams decreased from 912 s to 298 s.When the mass ratio of synthetic oil to foam-formation suspension was 2:8 and the asphaltene mass fraction increased from 0 to 15%,the half-life of SDS-stabilized foams decreased from 526 s to 171 s,and the half-life of SDS/silica-stabilized foams decreased from 660 s to 205 s.In addition,due to asphaltene-SDS/silica interaction in the aqueous phase,the absolute value of Zeta potential decreases,and the surface charges of particles reduce,leading to the reduction of repulsive forces between two interfaces of thin liquid film,which in turn,damages the foam stability.展开更多
New estimations of radiative forcing due to CO2 were calculated using updated concentration data of CO2 and a high-resolution radiative transfer model. The stratospheric adjusted radiative forcing （ARF） due to CO2 f...New estimations of radiative forcing due to CO2 were calculated using updated concentration data of CO2 and a high-resolution radiative transfer model. The stratospheric adjusted radiative forcing （ARF） due to CO2 from the year 1750 to the updated year of 2010 was found to have increased to 1.95 W m-2, which was 17% larger than that of the IPCC＇s 4th Assessment Report because of the rapid increase in CO2 concentrations since 2005. A new formula is proposed to accurately describe the relationship between the ARF of CO2 and its concentration. Furthermore, according to the relationship between the ARF and surface temperature change, possible changes in equilibrium surface temperature were estimated under the scenarios that the concentration of CO2 increases to 1.5, 2, 2.5, 3, 3.5 and 4 times that of the concentration in the year 2008. The result was values of ＋2.2℃, ＋3.8℃, ＋5.1℃, ＋6.2℃, ＋7.1℃ and ＋8.0℃ respectively, based on a middle-level climate sensitivity parameter of 0.8 K （W m 3）-1. Non-equilibrium surface temperature changes over the next 500 years were also calculated under two kinds of emission scenarios （pulsed and sustained emissions） as a comparison, according to the Absolute Global Temperature change Potential （AGTP） of CO2. Results showed that CO2 will likely continue to contribute to global warming if no emission controls are imposed, and the effect on the Earth-atmosphere system will be difficult to restore to its original level.展开更多
In this study,the decomposed fast and slow responses of clouds to an abruptly quadrupled CO_(2)concentration(approximately 1139 ppmv)in East Asia(EA)are obtained quantitatively by using a general circulation model,BCC...In this study,the decomposed fast and slow responses of clouds to an abruptly quadrupled CO_(2)concentration(approximately 1139 ppmv)in East Asia(EA)are obtained quantitatively by using a general circulation model,BCC–AGCM2.0.Our results show that in the total response,the total cloud cover(TCC),low cloud cover(LCC),and high cloud cover(HCC)all increased north of 40°N and decreased south of 40°N except in the Tibetan Plateau(TP).The mean changes of the TCC,LCC,and HCC in EA were–0.74%,0.38%,and–0.38%in the total response,respectively;1.05%,–0.03%,and 1.63%in the fast response,respectively;and–1.79%,0.41%,and–2.01%in the slow response,respectively.By comparison,we found that changes in cloud cover were dominated by the slow response in most areas in EA due to the changes in atmospheric temperature,circulation,and water vapor supply together.Overall,the changes in the cloud forcing over EA related to the fast and slow responses were opposite to each other,and the final cloud forcing was dominated by the slow response.The mean net cloud forcing(NCF)in the total response over EA was–1.80 W m^(–2),indicating a cooling effect which partially offset the warming effect caused by the quadrupled CO_(2).The total responses of NCF in the TP,south China(SC),and northeast China(NE)were–6.74 W m^(–2),6.11 W m^(–2),and–7.49 W m^(–2),respectively.Thus,the local effects of offsetting or amplifying warming were particularly obvious.展开更多
The Greenhouse Effect was simulated in a laboratory setup, consisting of a heated ground area and two chambers, one filled with air and one filled with air or CO2. While heating the gas the temperature and IR radiatio...The Greenhouse Effect was simulated in a laboratory setup, consisting of a heated ground area and two chambers, one filled with air and one filled with air or CO2. While heating the gas the temperature and IR radiation in both chambers were measured. IR radiation was produced by heating a metal plate mounted on the rear wall. Reduced IR radiation through the front window was observed when the air in the foremost chamber was exchanged with CO2. In the rear chamber, we observed increased IR radiation due to backscatter from the front chamber. Based on the Stefan Boltzmann’s law, this should increase the temperature of the air in the rear chamber by 2.4 to 4 degrees, but no such increase was found. A thermopile, made to increase the sensitivity and accuracy of the temperature measurements, showed that the temperature with CO2 increased slightly, about 0.5%.展开更多
基金supported by the National Science Fund for Distinguished Young Scholars(22125804)the National Natural Science Foundation of China(21808110,22078155,and 21878149).
文摘Temperature-swing adsorption(TSA)is an effective technique for CO_(2) capture,but the temperature swing procedure is energy-intensive.Herein,we report a low-energy-consumption system by combining passive radiative cooling and solar heating for the uptake of CO_(2) on commercial activated carbons(CACs).During adsorption,the adsorbents are coated with a layer of hierarchically porous poly(vinylidene fluoride-co-hexafluoropropene)[P(VdF-HFP)HP],which cools the adsorbents to a low temperature under sunlight through radiative cooling.For desorption,CACs with broad absorption of the solar spectrum are exposed to light irradiation for heating.The heating and cooling processes are completely driven by solar energy.Adsorption tests under mimicked sunlight using the CACs show that the performance of this system is comparable to that of the traditional ones.Furthermore,under real sunlight irradiation,the adsorption capacity of the CACs can be well maintained after multiple cycles.The present work may inspire the development of new temperature swing procedures with little energy consumption.
文摘Foam stability tests were performed using sodium dodecyl sulfate(SDS)surfactant and SiO2 nanoparticles as foaming system at different asphaltene concentrations,and the half-life of CO_(2) foam was measured.The mechanism of foam stability reduction in the presence of asphaltene was analyzed by scanning electron microscope(SEM),UV adsorption spectrophotometric concentration measurement and Zeta potential measurement.When the mass ratio of synthetic oil to foam-formation suspension was 1:9 and the asphaltene mass fraction increased from 0 to 15%,the half-life of SDS-stabilized foams decreased from 751 s to 239 s,and the half-life of SDS/silica-stabilized foams decreased from 912 s to 298 s.When the mass ratio of synthetic oil to foam-formation suspension was 2:8 and the asphaltene mass fraction increased from 0 to 15%,the half-life of SDS-stabilized foams decreased from 526 s to 171 s,and the half-life of SDS/silica-stabilized foams decreased from 660 s to 205 s.In addition,due to asphaltene-SDS/silica interaction in the aqueous phase,the absolute value of Zeta potential decreases,and the surface charges of particles reduce,leading to the reduction of repulsive forces between two interfaces of thin liquid film,which in turn,damages the foam stability.
基金supported by the National Basic Research Program of China (Grant Nos. 2010CB955703 and 2011CB403405)the Public Meteorology Special Foundation of MOST (Grant No. GYHY200906020)
文摘New estimations of radiative forcing due to CO2 were calculated using updated concentration data of CO2 and a high-resolution radiative transfer model. The stratospheric adjusted radiative forcing （ARF） due to CO2 from the year 1750 to the updated year of 2010 was found to have increased to 1.95 W m-2, which was 17% larger than that of the IPCC＇s 4th Assessment Report because of the rapid increase in CO2 concentrations since 2005. A new formula is proposed to accurately describe the relationship between the ARF of CO2 and its concentration. Furthermore, according to the relationship between the ARF and surface temperature change, possible changes in equilibrium surface temperature were estimated under the scenarios that the concentration of CO2 increases to 1.5, 2, 2.5, 3, 3.5 and 4 times that of the concentration in the year 2008. The result was values of ＋2.2℃, ＋3.8℃, ＋5.1℃, ＋6.2℃, ＋7.1℃ and ＋8.0℃ respectively, based on a middle-level climate sensitivity parameter of 0.8 K （W m 3）-1. Non-equilibrium surface temperature changes over the next 500 years were also calculated under two kinds of emission scenarios （pulsed and sustained emissions） as a comparison, according to the Absolute Global Temperature change Potential （AGTP） of CO2. Results showed that CO2 will likely continue to contribute to global warming if no emission controls are imposed, and the effect on the Earth-atmosphere system will be difficult to restore to its original level.
基金supported by the National Key R&D Program of China(2017YFA0603502)the National Natural Science Foundation of China(Grant No.41905081)S&T Development Fund of CAMS(2021KJ004&2022KJ019).
文摘In this study,the decomposed fast and slow responses of clouds to an abruptly quadrupled CO_(2)concentration(approximately 1139 ppmv)in East Asia(EA)are obtained quantitatively by using a general circulation model,BCC–AGCM2.0.Our results show that in the total response,the total cloud cover(TCC),low cloud cover(LCC),and high cloud cover(HCC)all increased north of 40°N and decreased south of 40°N except in the Tibetan Plateau(TP).The mean changes of the TCC,LCC,and HCC in EA were–0.74%,0.38%,and–0.38%in the total response,respectively;1.05%,–0.03%,and 1.63%in the fast response,respectively;and–1.79%,0.41%,and–2.01%in the slow response,respectively.By comparison,we found that changes in cloud cover were dominated by the slow response in most areas in EA due to the changes in atmospheric temperature,circulation,and water vapor supply together.Overall,the changes in the cloud forcing over EA related to the fast and slow responses were opposite to each other,and the final cloud forcing was dominated by the slow response.The mean net cloud forcing(NCF)in the total response over EA was–1.80 W m^(–2),indicating a cooling effect which partially offset the warming effect caused by the quadrupled CO_(2).The total responses of NCF in the TP,south China(SC),and northeast China(NE)were–6.74 W m^(–2),6.11 W m^(–2),and–7.49 W m^(–2),respectively.Thus,the local effects of offsetting or amplifying warming were particularly obvious.
基金The study was supported by the National Natural Science Foundation of China[grant numbers 41831175 and 41530425]the Strategic Priority Research Program of the Chinese Academy of Sciences[grant number XDA20060501]+1 种基金the Key Deployment Project of the Centre for Ocean Mega-Research of Science,Chinese Academy of Sciences[grant number COMS2019Q03]the Second Tibetan Plateau Scientific Expedition and Research(STEP)program[grant number 2019QZKK0102].
文摘The Greenhouse Effect was simulated in a laboratory setup, consisting of a heated ground area and two chambers, one filled with air and one filled with air or CO2. While heating the gas the temperature and IR radiation in both chambers were measured. IR radiation was produced by heating a metal plate mounted on the rear wall. Reduced IR radiation through the front window was observed when the air in the foremost chamber was exchanged with CO2. In the rear chamber, we observed increased IR radiation due to backscatter from the front chamber. Based on the Stefan Boltzmann’s law, this should increase the temperature of the air in the rear chamber by 2.4 to 4 degrees, but no such increase was found. A thermopile, made to increase the sensitivity and accuracy of the temperature measurements, showed that the temperature with CO2 increased slightly, about 0.5%.
