Conductive polymer composites(CPCs) as the thermo-sensitive materials have attracted much attention in thermal control field due to their reliable self-regulating behaviors, high efficiency and mechanical flexibility....Conductive polymer composites(CPCs) as the thermo-sensitive materials have attracted much attention in thermal control field due to their reliable self-regulating behaviors, high efficiency and mechanical flexibility. However, the development of these materials needs to manage the normal conflicting requirements, such as effective heating performance and good self-regulating capability. This paper presents a series of novel CPCs material having different amounts of hybrid fillers of multi-walled carbon nanotubes(CNTs) and carbon black(CB). The positive temperature coefficient intensity is enhanced to 105.2, and the roomtemperature resistivity is optimized to 320 ? cm. Besides, the Curie temperatures are regulated to room-temperature range by incorporating the low-melting-point blend matrix into the poly(ethylene-co-vinyl acetate)/CNTs/CB composite. The thermalcontrol experiment demonstrates that CPCs-heating elements can adjust the equilibrium temperature of controlled equipment near their Curie temperatures without any control methods. Compared with the ordinary resistor, the CPCs materials have the remarkable adaptive thermal control behavior. Furthermore, the temperature control capability is particularly prominent in the changing environment temperature. The CPCs as a safe and reliable adaptive heating element is potential to replace the conventional active thermal control means.展开更多
基金supported by the National Natural Science Foundation of China (Grant No. 51225602)。
文摘Conductive polymer composites(CPCs) as the thermo-sensitive materials have attracted much attention in thermal control field due to their reliable self-regulating behaviors, high efficiency and mechanical flexibility. However, the development of these materials needs to manage the normal conflicting requirements, such as effective heating performance and good self-regulating capability. This paper presents a series of novel CPCs material having different amounts of hybrid fillers of multi-walled carbon nanotubes(CNTs) and carbon black(CB). The positive temperature coefficient intensity is enhanced to 105.2, and the roomtemperature resistivity is optimized to 320 ? cm. Besides, the Curie temperatures are regulated to room-temperature range by incorporating the low-melting-point blend matrix into the poly(ethylene-co-vinyl acetate)/CNTs/CB composite. The thermalcontrol experiment demonstrates that CPCs-heating elements can adjust the equilibrium temperature of controlled equipment near their Curie temperatures without any control methods. Compared with the ordinary resistor, the CPCs materials have the remarkable adaptive thermal control behavior. Furthermore, the temperature control capability is particularly prominent in the changing environment temperature. The CPCs as a safe and reliable adaptive heating element is potential to replace the conventional active thermal control means.
