To solve the problem of only surface carbonation and realize high-efficiency carbonation of recycled coarse aggregate,the method of carbonated recycled coarse aggregate with nano materials pre-soaking was first put fo...To solve the problem of only surface carbonation and realize high-efficiency carbonation of recycled coarse aggregate,the method of carbonated recycled coarse aggregate with nano materials pre-soaking was first put forward.The carbonation effect of modified recycled coarse aggregate with three different carbonation methods was evaluated,and water absorption,apparent density and crush index of modified recycled coarse aggregate were measured.Combined with XRD,SEM,and MIP microscopic analysis,the high-efficiency carbonation strengthening mechanism of modified recycled coarse aggregate was revealed.The experimental results show that,compared with the non-carbonated recycled coarse aggregate,the physical and microscopic properties of carbonated recycled coarse aggregate are improved.The method of carbonation with nano-SiO_(2) pre-soaking can realize the high-efficiency carbonation of recycled coarse aggregate,for modified recycled coarse aggregate with the method,water absorption is reduced by 23.03%,porosity is reduced by 44.06%,and the average pore diameter is 21.82 nm.The high-efficiency carbonation strengthening mechanism show that the pre-socked nano-SiO_(2) is bound to the hydration product Ca(OH)_(2) of the old mortar with nano-scale C-S-H,which can improve the CO_(2) absorption rate,accelerate the carbonation reaction,generate more stable CaCO_(3) and nano-scale silica gel,and bond to the dense three-dimensional network structure to realize the bidirectional enhancement of nano-materials and pressurized carbonation.It is concluded that the method of carbonation with nano-SiO_(2) pre-soaking is a novel high-efficiency carbonation modification of recycled coarse aggregate.展开更多
The changes in austenite grain size of the specimens with coarse ferrite grains under different heat treatment process were investigated.The focus was on studying the effect of annealing on refining coarse ferrite gra...The changes in austenite grain size of the specimens with coarse ferrite grains under different heat treatment process were investigated.The focus was on studying the effect of annealing on refining coarse ferrite grains,as well as the influence of the ferrite grain size on the main technical indicators of gas carburizing.The results show that coarse ferrite grains may not necessarily cause the coarse austenite grains,but may result in mixed austenite grains.After annealing treatment,the coarse ferrite grains can be significantly refined and homogenized.Moreover,the coarse ferrite grains have no significant effects on hardnessand intergranular oxidationof gas carburizing.展开更多
With the emphasis on environmental issues,the recycling of waste concrete,even recycled concrete,has become a hot spot in the field of architecture.But the repeated recycling of waste concrete used in harsh environmen...With the emphasis on environmental issues,the recycling of waste concrete,even recycled concrete,has become a hot spot in the field of architecture.But the repeated recycling of waste concrete used in harsh environments is still a complex problem.This paper discusses the durability and recyclability of recycled aggregate concrete(RAC)as a prefabricated material in the harsh environment,the effect of high-temperature curing(60℃,80℃,and 100℃)on the frost resistance of RAC and physical properties of the second generation recycled coarse aggregate(RCA_(2))of RAC after 300 freeze-thaw cycles were studied.The frost resistance of RAC was characterized by compressive strength,relative dynamic elastic modulus,and mass loss.As the physical properties of RCA_(2),the apparent density,water absorption,and crushing value were measured.And the SEM images of RAC after 300 freeze-thaw cycles were shown.The results indicated that the frost resistance of RAC cured at 80℃ for 7 days was comparable to that cured in the standard condition(cured for 28 days at 20℃±2℃ and 95%humidity),and the RAC cured at 100℃ was slightly worse.However,the frost resistance of RAC cured at 60℃ deteriorated seriously.The RAC cured at 80℃ for 7 days is the best.Whether after the freeze-thaw cycle or not,the RCA that curd at 60℃,80℃,and 100℃ for 7 days can also meet the requirements of Grade III RCA and be used as the aggregate of non-bearing part of prefabricated concrete components.RCA_(2) which is cured at 80℃ for 7 days had the best physical properties.展开更多
Warming and nitrogen(N)deposition are two important drivers of global climate changes.Coarse woody debris(CWD)contains a large proportion of the carbon(C)in the total global C pool.The composition of soil microbial co...Warming and nitrogen(N)deposition are two important drivers of global climate changes.Coarse woody debris(CWD)contains a large proportion of the carbon(C)in the total global C pool.The composition of soil microbial communities and environmental changes(i.e.,N deposition and warming)are the key drivers of CWD decomposition,but the interactive impact between N deposition and warming on the composition of soil microbial communities and CWD decomposition is still unclear.In a laboratory experiment,we study and simulate respiration during decomposition of the CWD(C 98)of Cryptomeria japonica(CR)and Platycarya strobilacea(PL)in response to warming and N deposition over 98 days.Resuts show that either warming or N addition signifi cantly accelerated the C 98 of the two tree species by altering the soil microbial community(bacterial:fungi and G+:G–).The combined treatment(warming+N)resulted in a decomposition eff ect equal to the sum of the individual eff ects.In addition,the species composition of bacteria and fungi was obviously aff ected by warming.However,N deposition had a remarkable infl uence on G+:G–.Our results indicated that N deposition and warming will observably alter the composition and growth of the microbial community and thus work synergistically to accelerate CWD decomposition in forest ecosystems.We also present evidence that N deposition and warming infl uenced the composition and balance of soil microbial communities and biogeochemical cycling of forest ecosystems.展开更多
The 3D reconstruction and quantitative characterization of drainage channels and coarse tailings particles in a bed were conducted in this study.The influence of variations in the azimuthal angle(θ)and polar angle(φ...The 3D reconstruction and quantitative characterization of drainage channels and coarse tailings particles in a bed were conducted in this study.The influence of variations in the azimuthal angle(θ)and polar angle(φ)of coarse particles on drainage channel structure was analyzed,and the drainage mechanism of the bed was studied.Results showed that water discharge in the bed reduced the size of pores and throat channels,increasing slurry concentration.The throat channel structure was a key component of the drainage process.Theφandθof particles changed predominantly along the length direction.The changes inφhad a cumulative plugging effect on the drainage channel and increased the difficulty of water discharge.The rake and rod formed a shear ring in the tailings bed with shear,and theθdistribution of particles changed from disorderly to orderly during the rotation process.The drainage channel was squeezed during the shearing process with the change inθ,which broke the channel structure,encouraged water discharge in the bed,and facilitated a further increase in slurry concentration.The findings of this work are expected to offer theoretical guidance for preparing high-concentration underflow in the tailings thickening process.展开更多
基金Funded by Joint Funds of the National Natural Science Foundation of China(No.U1904188)the Jiangxi Provincial Department of Education Science and Technology Project(Nos.GJJ171079,GJJ181023,and GJJ181022)。
文摘To solve the problem of only surface carbonation and realize high-efficiency carbonation of recycled coarse aggregate,the method of carbonated recycled coarse aggregate with nano materials pre-soaking was first put forward.The carbonation effect of modified recycled coarse aggregate with three different carbonation methods was evaluated,and water absorption,apparent density and crush index of modified recycled coarse aggregate were measured.Combined with XRD,SEM,and MIP microscopic analysis,the high-efficiency carbonation strengthening mechanism of modified recycled coarse aggregate was revealed.The experimental results show that,compared with the non-carbonated recycled coarse aggregate,the physical and microscopic properties of carbonated recycled coarse aggregate are improved.The method of carbonation with nano-SiO_(2) pre-soaking can realize the high-efficiency carbonation of recycled coarse aggregate,for modified recycled coarse aggregate with the method,water absorption is reduced by 23.03%,porosity is reduced by 44.06%,and the average pore diameter is 21.82 nm.The high-efficiency carbonation strengthening mechanism show that the pre-socked nano-SiO_(2) is bound to the hydration product Ca(OH)_(2) of the old mortar with nano-scale C-S-H,which can improve the CO_(2) absorption rate,accelerate the carbonation reaction,generate more stable CaCO_(3) and nano-scale silica gel,and bond to the dense three-dimensional network structure to realize the bidirectional enhancement of nano-materials and pressurized carbonation.It is concluded that the method of carbonation with nano-SiO_(2) pre-soaking is a novel high-efficiency carbonation modification of recycled coarse aggregate.
基金the Shaanxi Innovation Talent Promotion Plan-Youth Science and Technology New Star Project(Talent).Project No.:2023KJXX-121。
文摘The changes in austenite grain size of the specimens with coarse ferrite grains under different heat treatment process were investigated.The focus was on studying the effect of annealing on refining coarse ferrite grains,as well as the influence of the ferrite grain size on the main technical indicators of gas carburizing.The results show that coarse ferrite grains may not necessarily cause the coarse austenite grains,but may result in mixed austenite grains.After annealing treatment,the coarse ferrite grains can be significantly refined and homogenized.Moreover,the coarse ferrite grains have no significant effects on hardnessand intergranular oxidationof gas carburizing.
基金This research was funded by the National Natural Science Foundation of China(52078068)Practice Innovation Program of Jiangsu Province(KYCX22_3082).
文摘With the emphasis on environmental issues,the recycling of waste concrete,even recycled concrete,has become a hot spot in the field of architecture.But the repeated recycling of waste concrete used in harsh environments is still a complex problem.This paper discusses the durability and recyclability of recycled aggregate concrete(RAC)as a prefabricated material in the harsh environment,the effect of high-temperature curing(60℃,80℃,and 100℃)on the frost resistance of RAC and physical properties of the second generation recycled coarse aggregate(RCA_(2))of RAC after 300 freeze-thaw cycles were studied.The frost resistance of RAC was characterized by compressive strength,relative dynamic elastic modulus,and mass loss.As the physical properties of RCA_(2),the apparent density,water absorption,and crushing value were measured.And the SEM images of RAC after 300 freeze-thaw cycles were shown.The results indicated that the frost resistance of RAC cured at 80℃ for 7 days was comparable to that cured in the standard condition(cured for 28 days at 20℃±2℃ and 95%humidity),and the RAC cured at 100℃ was slightly worse.However,the frost resistance of RAC cured at 60℃ deteriorated seriously.The RAC cured at 80℃ for 7 days is the best.Whether after the freeze-thaw cycle or not,the RCA that curd at 60℃,80℃,and 100℃ for 7 days can also meet the requirements of Grade III RCA and be used as the aggregate of non-bearing part of prefabricated concrete components.RCA_(2) which is cured at 80℃ for 7 days had the best physical properties.
基金supported by the National Natural Science Foundation of China(3196140162).
文摘Warming and nitrogen(N)deposition are two important drivers of global climate changes.Coarse woody debris(CWD)contains a large proportion of the carbon(C)in the total global C pool.The composition of soil microbial communities and environmental changes(i.e.,N deposition and warming)are the key drivers of CWD decomposition,but the interactive impact between N deposition and warming on the composition of soil microbial communities and CWD decomposition is still unclear.In a laboratory experiment,we study and simulate respiration during decomposition of the CWD(C 98)of Cryptomeria japonica(CR)and Platycarya strobilacea(PL)in response to warming and N deposition over 98 days.Resuts show that either warming or N addition signifi cantly accelerated the C 98 of the two tree species by altering the soil microbial community(bacterial:fungi and G+:G–).The combined treatment(warming+N)resulted in a decomposition eff ect equal to the sum of the individual eff ects.In addition,the species composition of bacteria and fungi was obviously aff ected by warming.However,N deposition had a remarkable infl uence on G+:G–.Our results indicated that N deposition and warming will observably alter the composition and growth of the microbial community and thus work synergistically to accelerate CWD decomposition in forest ecosystems.We also present evidence that N deposition and warming infl uenced the composition and balance of soil microbial communities and biogeochemical cycling of forest ecosystems.
基金financially supported by the National Key R&D Program of China(No.2022YFC2903803)National Natural Science Foundation of China(No.52130404)+4 种基金Guangdong Basic and Applied Basic Research Foundation(No.2021A1515110161)ANID(Chile)through Fondecyt project 1210610Centro de Modelamiento Matemático(BASAL funds for Centers of Excellence FB210005)CRHIAM project ANID/FONDAP/15130015Anillo project ANID/ACT210030。
文摘The 3D reconstruction and quantitative characterization of drainage channels and coarse tailings particles in a bed were conducted in this study.The influence of variations in the azimuthal angle(θ)and polar angle(φ)of coarse particles on drainage channel structure was analyzed,and the drainage mechanism of the bed was studied.Results showed that water discharge in the bed reduced the size of pores and throat channels,increasing slurry concentration.The throat channel structure was a key component of the drainage process.Theφandθof particles changed predominantly along the length direction.The changes inφhad a cumulative plugging effect on the drainage channel and increased the difficulty of water discharge.The rake and rod formed a shear ring in the tailings bed with shear,and theθdistribution of particles changed from disorderly to orderly during the rotation process.The drainage channel was squeezed during the shearing process with the change inθ,which broke the channel structure,encouraged water discharge in the bed,and facilitated a further increase in slurry concentration.The findings of this work are expected to offer theoretical guidance for preparing high-concentration underflow in the tailings thickening process.
文摘通过焊接热模拟研究了在超大线能量下焊接时Al元素、Mg元素和Ti元素含量对EH36高强船板钢热影响区粗晶区组织、性能的影响规律,采用Thermo-Calc热力学计算与SEM,EDS测试相结合的方法揭示了Al元素、Mg元素和Ti元素含量与母材中氧化物类型、尺寸、数量及粗晶区相变的关系.结果表明,Al_(2)O_(3)无法诱导针状铁素体相变,当Al元素质量分数低于0.005%时,钢中可形成Mg元素、Ti元素或其复合氧化物,可促进粗晶区针状铁素体相变.Mg元素和Ti元素联合添加时,当Mg元素质量分数由0.0042%降低为0.0013%,氧化物类型由MgO转变为Mg_(2)TiO_(4),经统计20个视场内的氧化物数量由408个提高到503个,平均直径由1.37μm减小到1.10μm,显著提高了非均匀形核的比表面积,抑制了晶界铁素体的形成,使t8/5=300 s时粗晶区热模拟试样-20℃冲击吸收能量由43 J提升到127 J.