C_(4)F_(7)N/CO_(2)/O_(2)混合气体以其优异的环保和绝缘性能成为目前最具潜力替代SF6应用于电力工业的气体绝缘介质。尽管O_(2)的加入可以在一定程度上提升C_(4)F_(7)N/CO_(2)混合气体的绝缘性能和化学稳定性,但O_(2)加入及其体积分数...C_(4)F_(7)N/CO_(2)/O_(2)混合气体以其优异的环保和绝缘性能成为目前最具潜力替代SF6应用于电力工业的气体绝缘介质。尽管O_(2)的加入可以在一定程度上提升C_(4)F_(7)N/CO_(2)混合气体的绝缘性能和化学稳定性,但O_(2)加入及其体积分数变化对混合气体局部放电(partial discharge,PD)作用下气体和固体副产物生成特性的影响规律尚不清楚。因此通过针–板电极模拟设备内的金属突出物缺陷开展C_(4)F_(7)N/CO_(2)/O_(2)96 h PD及其分解特性试验。研究发现C_(4)F_(7)N/CO_(2)混合气体中加入体积分数2%~4%的O_(2)可以显著抑制大部分副产物的生成,O_(2)体积分数大于6%时每秒累积放电量和平均放电量急剧增加,导致混合气体分解加剧;C_(4)F_(7)N/CO_(2)/O_(2)在长时间PD作用下板电极表面中心区域出现较为明显的圆环状固体析出物,主要成分包括金属氧化物(CuO)、氟化物(CuF、CFx)、碳氧化合物(CO、CO_(2))和氮氧化合物(NO、NO_(2));体积分数4%的O_(2)加入对PD固体析出物的元素组成及其价态影响较小,但可以一定程度上减少其生成量,混合气体中O_(2)对金属导体的腐蚀作用弱于C_(4)F_(7)N。展开更多
The dynamics of negative surface discharges in c-C_(4)F_(8)/CF_(3)I/CO_(2) gas mixture is investigated here with a 2D fuid model.The distributions of ion concentration,electric field strength and photon flux during th...The dynamics of negative surface discharges in c-C_(4)F_(8)/CF_(3)I/CO_(2) gas mixture is investigated here with a 2D fuid model.The distributions of ion concentration,electric field strength and photon flux during the propagation of the streamer are obtained by solving the drift-diffusion equations of particles and Poisson's equation,and the photon flux variation function during the propagation is also fitted.It is found that the streamer branches occur when the streamer transitions from the upper surface of the insulator to the side surface,and then when the streamer approaches the plane electrode,the photon flux will increase significantly.On this basis,the positive and negative surface discharge models are compared in terms of streamer characteristics,particle characteristics and streamer branches.It is found that the streamer has a higher electron concentration and electric field in the positive model.The streamer develops“floating”in the positive surface discharge,while it is close to the surface of the insulator in the negative model.In addition,the negative streamer branch has a wider width and develops further.展开更多
高压断路器分合闸过程中触头间隙介质的绝缘强度及其变化是断路器结构设计的重要性能指标。搭建高压断路器触头间隙介质绝缘特性实验回路,测量C_(4)F_(7)N/CO_(2)混合气体断路器空载分合闸过程中不同压强、不同C4F7N含量时触头间隙介质...高压断路器分合闸过程中触头间隙介质的绝缘强度及其变化是断路器结构设计的重要性能指标。搭建高压断路器触头间隙介质绝缘特性实验回路,测量C_(4)F_(7)N/CO_(2)混合气体断路器空载分合闸过程中不同压强、不同C4F7N含量时触头间隙介质的动态击穿电压,研究C_(4)F_(7)N/CO_(2)混合气体断路器的关合预击穿特性和分闸绝缘特性。实验发现,断路器空载分合闸过程中C_(4)F_(7)N/CO_(2)混合气体动态击穿电压存在“低电压击穿”现象;合闸过程中,动态击穿电压分散性较大,C_(4)F_(7)N/CO_(2)混合气体断路器的关合预击穿特性显著劣于SF6断路器,增大压强或增加C4F7N含量对混合气体动态击穿电压分散性的改善不大;正、负极性条件下0.7MPa时9%C_(4)F_(7)N/91%CO_(2)混合气体的分闸平均绝缘强度上升率(rate of rise of dielectric strength,RRDS)分别为49.8kV/ms和42.7kV/ms,具有“反极性”效应;分闸过程中,“低电压击穿”现象主要出现在刚分后2ms(开距约6mm)范围以内,断路器若在此时间(开距)范围内熄弧,极易发生弧后重击穿现象,因此,C_(4)F_(7)N/CO_(2)混合气体断路器结构设计时应避免在此范围内熄弧。展开更多
文摘C_(4)F_(7)N/CO_(2)/O_(2)混合气体以其优异的环保和绝缘性能成为目前最具潜力替代SF6应用于电力工业的气体绝缘介质。尽管O_(2)的加入可以在一定程度上提升C_(4)F_(7)N/CO_(2)混合气体的绝缘性能和化学稳定性,但O_(2)加入及其体积分数变化对混合气体局部放电(partial discharge,PD)作用下气体和固体副产物生成特性的影响规律尚不清楚。因此通过针–板电极模拟设备内的金属突出物缺陷开展C_(4)F_(7)N/CO_(2)/O_(2)96 h PD及其分解特性试验。研究发现C_(4)F_(7)N/CO_(2)混合气体中加入体积分数2%~4%的O_(2)可以显著抑制大部分副产物的生成,O_(2)体积分数大于6%时每秒累积放电量和平均放电量急剧增加,导致混合气体分解加剧;C_(4)F_(7)N/CO_(2)/O_(2)在长时间PD作用下板电极表面中心区域出现较为明显的圆环状固体析出物,主要成分包括金属氧化物(CuO)、氟化物(CuF、CFx)、碳氧化合物(CO、CO_(2))和氮氧化合物(NO、NO_(2));体积分数4%的O_(2)加入对PD固体析出物的元素组成及其价态影响较小,但可以一定程度上减少其生成量,混合气体中O_(2)对金属导体的腐蚀作用弱于C_(4)F_(7)N。
基金the National Natural Science Foundation of China(No.62075045)。
文摘The dynamics of negative surface discharges in c-C_(4)F_(8)/CF_(3)I/CO_(2) gas mixture is investigated here with a 2D fuid model.The distributions of ion concentration,electric field strength and photon flux during the propagation of the streamer are obtained by solving the drift-diffusion equations of particles and Poisson's equation,and the photon flux variation function during the propagation is also fitted.It is found that the streamer branches occur when the streamer transitions from the upper surface of the insulator to the side surface,and then when the streamer approaches the plane electrode,the photon flux will increase significantly.On this basis,the positive and negative surface discharge models are compared in terms of streamer characteristics,particle characteristics and streamer branches.It is found that the streamer has a higher electron concentration and electric field in the positive model.The streamer develops“floating”in the positive surface discharge,while it is close to the surface of the insulator in the negative model.In addition,the negative streamer branch has a wider width and develops further.
文摘高压断路器分合闸过程中触头间隙介质的绝缘强度及其变化是断路器结构设计的重要性能指标。搭建高压断路器触头间隙介质绝缘特性实验回路,测量C_(4)F_(7)N/CO_(2)混合气体断路器空载分合闸过程中不同压强、不同C4F7N含量时触头间隙介质的动态击穿电压,研究C_(4)F_(7)N/CO_(2)混合气体断路器的关合预击穿特性和分闸绝缘特性。实验发现,断路器空载分合闸过程中C_(4)F_(7)N/CO_(2)混合气体动态击穿电压存在“低电压击穿”现象;合闸过程中,动态击穿电压分散性较大,C_(4)F_(7)N/CO_(2)混合气体断路器的关合预击穿特性显著劣于SF6断路器,增大压强或增加C4F7N含量对混合气体动态击穿电压分散性的改善不大;正、负极性条件下0.7MPa时9%C_(4)F_(7)N/91%CO_(2)混合气体的分闸平均绝缘强度上升率(rate of rise of dielectric strength,RRDS)分别为49.8kV/ms和42.7kV/ms,具有“反极性”效应;分闸过程中,“低电压击穿”现象主要出现在刚分后2ms(开距约6mm)范围以内,断路器若在此时间(开距)范围内熄弧,极易发生弧后重击穿现象,因此,C_(4)F_(7)N/CO_(2)混合气体断路器结构设计时应避免在此范围内熄弧。
