Fe-Al/Cr3C2 coatings were sprayed on low steel by high velocity arc spraying（HVAS） technology. The influences of oxides on erosion, corrosion and wear behavior for high velocity arc sprayed Fe-Al/Cr3C2 coatings were...Fe-Al/Cr3C2 coatings were sprayed on low steel by high velocity arc spraying（HVAS） technology. The influences of oxides on erosion, corrosion and wear behavior for high velocity arc sprayed Fe-Al/Cr3C2 coatings were studied. The results show that HVAS-sprayed Fe-Al/Cr3C2 coatings have good erosion, heat corrosion and wear resistance. The erosion resistance improves with the increase of the temperature. On one hand, the ferrous oxides are incompact, so they peel off the surface of the coatings easily during the high temperature erosion. On the other hand, compact Al2O3 films on the surface can protect the coatings.展开更多
New chiral C_2-symmetrical bis(oxazoline) compounds bearing one isobutyl-, secbutyl-, benzyl- or isopropyl-substituent at the 4-position have been prepared and characterized.
The kinetics of CO hydrogenation for the synthesis of C_2 oxygenates overRh-Mn-Li-Fe/SiO_2 was investigated. Kinetic parameters for the formation of ethanol, acetaldehyde,C'2 oxygenates, methanol and methane were ...The kinetics of CO hydrogenation for the synthesis of C_2 oxygenates overRh-Mn-Li-Fe/SiO_2 was investigated. Kinetic parameters for the formation of ethanol, acetaldehyde,C'2 oxygenates, methanol and methane were obtained. The activation energy. H_2 and CO dependenceorders for ethanol and acetaldehyde formation differed greatly, the large difference seemed to implythat they were formed through different intermediates.展开更多
Direct conversion of methane to C_2 hydrocarbons via cold plasma reactionwith catalysts has been studied at room temperature and atmospheric pressure. Methane can beconverted into C_2 hydrocarbons in different selecti...Direct conversion of methane to C_2 hydrocarbons via cold plasma reactionwith catalysts has been studied at room temperature and atmospheric pressure. Methane can beconverted into C_2 hydrocarbons in different selectivity depending on the form of the reactor, powerof plasma, flow rate of methane, ratio of N_2/CH_4 and nature of the catalysts. The selectivity toC_2 hydrocarbons can reach as high as 98.64%, and the conversion of methane as high as 60% and theyield of C_2 hydrocarbons as high as 50% are obtained. Coking can be minimized under the conditionsof: proper selection of the catalysts, appropriate high flow rate of inlet methane and suitableratio of N_2 to CH_4. The catalyst surface provides active sites for radical recombination.展开更多
文摘Fe-Al/Cr3C2 coatings were sprayed on low steel by high velocity arc spraying（HVAS） technology. The influences of oxides on erosion, corrosion and wear behavior for high velocity arc sprayed Fe-Al/Cr3C2 coatings were studied. The results show that HVAS-sprayed Fe-Al/Cr3C2 coatings have good erosion, heat corrosion and wear resistance. The erosion resistance improves with the increase of the temperature. On one hand, the ferrous oxides are incompact, so they peel off the surface of the coatings easily during the high temperature erosion. On the other hand, compact Al2O3 films on the surface can protect the coatings.
基金the Foundation for Academic Leader by the Education Department of Hunan province.
文摘New chiral C_2-symmetrical bis(oxazoline) compounds bearing one isobutyl-, secbutyl-, benzyl- or isopropyl-substituent at the 4-position have been prepared and characterized.
基金This work was financially by the Chinese Science and Technology Ministry (Grant No.G1999022404)
文摘The kinetics of CO hydrogenation for the synthesis of C_2 oxygenates overRh-Mn-Li-Fe/SiO_2 was investigated. Kinetic parameters for the formation of ethanol, acetaldehyde,C'2 oxygenates, methanol and methane were obtained. The activation energy. H_2 and CO dependenceorders for ethanol and acetaldehyde formation differed greatly, the large difference seemed to implythat they were formed through different intermediates.
文摘Direct conversion of methane to C_2 hydrocarbons via cold plasma reactionwith catalysts has been studied at room temperature and atmospheric pressure. Methane can beconverted into C_2 hydrocarbons in different selectivity depending on the form of the reactor, powerof plasma, flow rate of methane, ratio of N_2/CH_4 and nature of the catalysts. The selectivity toC_2 hydrocarbons can reach as high as 98.64%, and the conversion of methane as high as 60% and theyield of C_2 hydrocarbons as high as 50% are obtained. Coking can be minimized under the conditionsof: proper selection of the catalysts, appropriate high flow rate of inlet methane and suitableratio of N_2 to CH_4. The catalyst surface provides active sites for radical recombination.
