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挤压处理与Ca添加对Mg-7Sn合金显微组织与耐蚀性的影响
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作者 李万东 黄丽丽 王兴华 《腐蚀与防护》 CAS CSCD 北大核心 2023年第7期46-51,共6页
利用金相显微镜(OM)、扫描电子显微镜(SEM)、X射线光电子能谱(XPS)、电化学试验与浸泡试验等研究了挤压处理与添加合金元素Ca对Mg-7Sn合金显微组织、耐蚀性及力学性能的影响。结果表明:添加Ca元素可以明显细化铸态Mg-7Sn合金的晶粒,并... 利用金相显微镜(OM)、扫描电子显微镜(SEM)、X射线光电子能谱(XPS)、电化学试验与浸泡试验等研究了挤压处理与添加合金元素Ca对Mg-7Sn合金显微组织、耐蚀性及力学性能的影响。结果表明:添加Ca元素可以明显细化铸态Mg-7Sn合金的晶粒,并在晶粒内部与晶界形成了棒状的CaMgSn相,同时,腐蚀过程中,添加Ca会使合金表面形成含Ca的化合物,阻止或延缓腐蚀的进行,提高合金的耐蚀性。挤压处理使得合金的平均晶粒尺寸由55.2μm减小到3.3μm,粗大棒状的CaMgSn相被破碎成细小的块状。挤压处理后Mg-7Sn-1Ca合金的耐蚀性出现轻微下降,但保证了较高的显微硬度。挤压态Mg-7Sn-1Ca合金兼具力学性能和耐蚀性。 展开更多
关键词 Mg-7Sn合金 ca添加 挤压处理 显微组织 耐腐蚀性能
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Ca/Fe添加剂对焦炭在H_(2)O+CO_(2)气氛中溶损反应的影响
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作者 窦明辉 韩嘉伟 +2 位作者 孙洋 孙章 梁英华 《工程科学学报》 EI CSCD 北大核心 2023年第11期1859-1867,共9页
为了探究富氢高炉内Ca/Fe基高反应性焦炭的溶损反应特性,以CO_(2)(N_(2))载带不同摩尔比例H_(2)O蒸气(0~30%)进行焦炭溶损实验,通过分析尾气中CO和H_(2)的含量,研究Ca/Fe添加剂对焦炭在H_(2)O+CO_(2)混合气氛下碳溶反应和水煤气反应的影... 为了探究富氢高炉内Ca/Fe基高反应性焦炭的溶损反应特性,以CO_(2)(N_(2))载带不同摩尔比例H_(2)O蒸气(0~30%)进行焦炭溶损实验,通过分析尾气中CO和H_(2)的含量,研究Ca/Fe添加剂对焦炭在H_(2)O+CO_(2)混合气氛下碳溶反应和水煤气反应的影响.研究表明,焦炭在H_(2)O+CO_(2)和H_(2)O+N_(2)两种气氛下的焦炭反应性随H_(2)O蒸气载带率增加呈线性关系,焦炭在H_(2)O+CO_(2)气氛中溶损反应的拟合斜率k值明显小于在H_(2)O+N2气氛中的k值,H_(2)O+CO_(2)混合气氛中H_(2)O和CO_(2)与焦炭反应存在竞争关系.而且基础焦炭(BC)反应性的实验与理论的差值明显小于Ca/Fe基焦炭(BC+Ca、BC+Fe)的差值,表明Ca/Fe添加剂影响了CO_(2)和H_(2)O与焦炭共同反应时的竞争关系.基于两种气氛下速率常数的差异提炼了两个抑制因子αCO_(2)/H_(2)O和αH_(2)O/CO_(2),αCO_(2)/H_(2)O定量表征CO_(2)对C+H_(2)O反应的抑制程度,αCO_(2)/H_(2)O定量表征H_(2)O对C+CO_(2)反应的抑制程度,BC、BC+Fe、BC+Ca三种焦炭的而提高了中催化活性物质为铁酸钙和硅铝酸钙,Ca/Fe元素在焦炭中赋存形式的不同导致了Ca/Fe添加剂对焦炭溶损反应催化效果的差异性. 展开更多
关键词 焦炭 ca/Fe添加 溶损反应 H_(2)O+CO_(2)混合气氛 催化 抑制因子
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Effect of calcium addition on microstructure and texture modification of Mg rolled sheets 被引量:9
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作者 丁汉林 张鹏 +1 位作者 程广萍 Shigeharu KAMADO 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第9期2875-2883,共9页
The mechanical properties and texture of AM60(Mg-6.0Al-0.3Mn,mass fraction %) and ZXM200(Mg-1.6Zn-0.5Ca-0.2Mn) Mg alloys subjected to multi-pass hot rolling were investigated.The finer recrystallized grains usuall... The mechanical properties and texture of AM60(Mg-6.0Al-0.3Mn,mass fraction %) and ZXM200(Mg-1.6Zn-0.5Ca-0.2Mn) Mg alloys subjected to multi-pass hot rolling were investigated.The finer recrystallized grains usually exhibit particular preferred orientations and then alter the total texture feature of rolled sheets.Ca solid solution into Mg matrix serves to the formation of texture component with c-axis rotated away from normal direction towards transverse direction and then weakens the overall texture intensity,resulting in a similar anisotropic characteristic to RE-containing Mg alloys. 展开更多
关键词 Mg sheets hot rolling dynamic recrystallization ca addition texture weakening
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Effects of minor Ca on as-cast microstructures and mechanical properties of Mg-3Ce-1.2Mn-0.9Sc and Mg-4Y-1.2Mn-0.9Sc alloys 被引量:1
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作者 杨明波 段成宇 +1 位作者 吴德勇 潘复生 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第6期1698-1708,共11页
The effects of the addition of 0.6%Ca(mass fraction) on the as-cast microstructure and mechanical properties of the Mg-3Ce-1.2Mn-0.9Sc and Mg-4Y-1.2Mn-0.9Sc magnesium alloys were investigated and compared by optical... The effects of the addition of 0.6%Ca(mass fraction) on the as-cast microstructure and mechanical properties of the Mg-3Ce-1.2Mn-0.9Sc and Mg-4Y-1.2Mn-0.9Sc magnesium alloys were investigated and compared by optical microscopy and scanning electron microscopy,differential scanning calorimetry analysis,and tensile and creep tests.The results indicate that the addition of 0.6%Ca to the Mg-3Ce-1.2Mn-0.9Sc and Mg-4Y-1.2Mn-0.9Sc alloys can refine the grains of the two alloys.At the same time,the addition of 0.6%Ca to the Mg-3Ce-1.2Mn-0.9Sc and Mg-4Y-1.2Mn-0.9Sc alloys can effectively improve the tensile properties of the two alloys.In addition,the addition of 0.6%Ca can also improve the creep properties of the Mg-3Ce-1.2Mn-0.9Sc alloy but is not beneficial to the creep properties of the Mg-4Y-1.2Mn-0.9Sc alloy.The different effects of minor Ca on the creep properties of the Mg-3Ce-1.2Mn-0.9Sc and Mg-4Y-1.2Mn-0.9Sc alloys are possibly related to the difference in the solid solubilities of Ce and Y in Mg. 展开更多
关键词 magnesium alloys Mg-RE-Mn-Sc alloys ca addition
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Influence of trace Ca addition on texture and stretch formability of AM50 magnesium alloy sheet 被引量:9
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作者 Hong-liang ZHAO Yun-xiao HUA +2 位作者 Xiang-lei DONG Hui XING Yan-li LU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2020年第3期647-656,共10页
The AM50,AM50-0.1 Ca,AM50-0.3 Ca and AM50-0.5 Ca(wt.%) alloys were hot-rolled and their mechanical properties were determined for the purpose of investigating the effect of trace Ca addition on the texture and stretch... The AM50,AM50-0.1 Ca,AM50-0.3 Ca and AM50-0.5 Ca(wt.%) alloys were hot-rolled and their mechanical properties were determined for the purpose of investigating the effect of trace Ca addition on the texture and stretch formability of AM50 alloy.The results show that the addition of trace Ca can effectively modify the basal texture,which is characterized by the split of basal poles deviated from the normal direction(ND) after the hot rolling,while a broad spread of the basal planes toward the transverse direction(TD) after the annealing.Such change of the basal texture is related to the prior formation of massive compression twins and the decrease of the c/a ratio.Erichsen value increases from 2.25 to 4.21 mm with the increase of Ca content.The enhancement of stretch formability is ascribed to the weakened basal texture,which results in the increase of n-value and the decrease of r-value. 展开更多
关键词 magnesium alloy ca addition TEXTURE stretch formability mechanical properties
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Effect of Ca addition on microstructure and impression creep behavior of cast AZ61 magnesium alloy 被引量:7
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作者 B.NAMI S.M.MIRESMAEILI +1 位作者 F.JAMSHIDI I.KHOUBROU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2019年第10期2056-2065,共10页
Microstructure and creep properties of AZ61 alloy containing 1 and 3 wt.% Ca were investigated. The creep properties were examined using impression method under different stresses between 200 and 500 MPa at the temper... Microstructure and creep properties of AZ61 alloy containing 1 and 3 wt.% Ca were investigated. The creep properties were examined using impression method under different stresses between 200 and 500 MPa at the temperature ranging from 423 to 491 K. The microstructure of AZ61 alloy contains α(Mg) matrix and Mg17 Al12 intermetallic phases. It is shown that adding Ca to AZ61 alloy reduces the amount of Mg17 Al12 phase via forming(Mg,Al)2 Ca phase;furthermore, increasing the Ca content to 3 wt.% leads to the formation of(Mg,Al)2 Ca phase, as well as the elimination of the Mg17 Al12 phase. Creep properties of AZ61 alloy are improved with the Ca addition. The improvement in creep properties is attributed to the reduction in the amount of Mg17 Al12 phase and the formation of(Mg,Al)2 Ca phase with high thermal stability. According to the obtained creep data, it is concluded that the pipe diffusion-climb controlled dislocation creep is the dominant creep mechanism and Ca addition has no influence on this mechanism. The effect of pre-deformation on the creep properties of AZ61+3%Ca alloy reveals that the creep resistance of the alloy depends on the continuity of(Mg,Al)2 Ca phase. It is decreased by reducing the phase continuity. 展开更多
关键词 impression creep magnesium alloy ca addition dislocation creep phase continuity
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Ca对Mg-Gd-Y-Zn-Zr合金热变形行为及热加工性能的影响 被引量:2
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作者 王玉娇 江海涛 +5 位作者 柳超敏 张韵 郭文启 康强 徐哲 王盼盼 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2020年第5期1650-1656,共7页
利用Gleeble3500热模拟试验机研究了Ca对Mg-Gd-Y-Zn-Zr合金在变形温度573~723 K,应变速率0.001~1 s-1的热变形行为及热加工性能的影响。结果表明:Ca增大了合金的流变应力及变形激活能,扩宽了加工安全区及最佳加工区范围,但降低了最大功... 利用Gleeble3500热模拟试验机研究了Ca对Mg-Gd-Y-Zn-Zr合金在变形温度573~723 K,应变速率0.001~1 s-1的热变形行为及热加工性能的影响。结果表明:Ca增大了合金的流变应力及变形激活能,扩宽了加工安全区及最佳加工区范围,但降低了最大功率耗散因子及动态再结晶程度。结合激光共聚焦显微镜分析了合金热压缩后组织,验证了热加工图的准确性,并制定了合理的热加工工艺,Mg-Gd-Y-Zn-Zr合金的最佳加工区域为:应变速率0.001~0.01 s-1,温度623~723 K。根据最佳加工工艺参数获得了表面质量良好,无变形缺陷的等温锻造合金。 展开更多
关键词 Mg-Gd-Y-Zn-Zr ca添加 热变形行为 本构方程 热加工图
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