The enrichment behavior of phosphorus in CaO-SiO2-FeOx-P2O5 slag was studied by making an investigation on the distribution of phosphorous content in the CaO-SiO2-FeOx-P2O5 molten slag.The research results showed that...The enrichment behavior of phosphorus in CaO-SiO2-FeOx-P2O5 slag was studied by making an investigation on the distribution of phosphorous content in the CaO-SiO2-FeOx-P2O5 molten slag.The research results showed that the 2CaO·SiO2 solid particles existing in molten slag were the condensation sites for the phosphorus enrichment.The enrichment process of phosphorus in the molten slag can be recognized as three substeps：mass transfer of phosphorus from bulk slag to the surface of 2CaO·SiO2 particle,superficial solid solution reaction of phosphorus around the 2CaO·SiO2 particle,and diffusion of phosphorus through the product layer of 2CaO·SiO2-3CaO·P2O5 solid solution to the inner of 2CaO·SiO2 particle.Moreover,higher temperature is favorable to the phosphorous enrichment from molten bulk slag to the 2CaO·SiO2 particles.展开更多
The O_(2)-CaO jet with shrouding combustion flame demonstrates some advantages in quick melting and effective slag foaming by delivering lime powder deeply into the molten bath.Combining the discrete particle model an...The O_(2)-CaO jet with shrouding combustion flame demonstrates some advantages in quick melting and effective slag foaming by delivering lime powder deeply into the molten bath.Combining the discrete particle model and the eddy dissipation concept model with the detailed chemical kinetic mechanisms(GRI-Mech 3.0),computational fluid dynamics models of the O_(2)-CaO jet with different shrouding fuel mediums injection were developed.Firstly,the results of the numerical simulation were validated by the measured data of cold test for O_(2)-CaO injection.Then,the interaction between the particles and the gas jet of the O_(2)-CaO jet and the effect of shrouding fuel medium species on the fluid flow characteristics of the O_(2)-CaO jet were analyzed.Results show that the CaO particles can be effectively heated by the shrouding high-temperature combustion flame and compared with the O_(2)-CaO jet without shrouding gas,the potential core length was increased about 2.5,3.3 and 4.3 times by the shrouding flame generated from CO,CH_(4) and C_(3)H_(8).And with shrouding CH_(4) and C_(3)H_(8) injection,the CaO particles can be clustered together in a long distance,which would be helpful to improve the utilization efficiency of CaO particles.展开更多
基金Item Sponsored by National Natural Science Foundation of China/Joint Fund for Iron and Steel Research(50874130)National Natural Science Foundation of China(50974034)
文摘The enrichment behavior of phosphorus in CaO-SiO2-FeOx-P2O5 slag was studied by making an investigation on the distribution of phosphorous content in the CaO-SiO2-FeOx-P2O5 molten slag.The research results showed that the 2CaO·SiO2 solid particles existing in molten slag were the condensation sites for the phosphorus enrichment.The enrichment process of phosphorus in the molten slag can be recognized as three substeps：mass transfer of phosphorus from bulk slag to the surface of 2CaO·SiO2 particle,superficial solid solution reaction of phosphorus around the 2CaO·SiO2 particle,and diffusion of phosphorus through the product layer of 2CaO·SiO2-3CaO·P2O5 solid solution to the inner of 2CaO·SiO2 particle.Moreover,higher temperature is favorable to the phosphorous enrichment from molten bulk slag to the 2CaO·SiO2 particles.
基金the Fundamental Research Funds for the Central Universities(FRF-TP-19-031A1)the China Post Postdoctoral Science Foundation(2020T130053,2019M660459)the National Natural Science Foundation of China(No.51734003).
文摘The O_(2)-CaO jet with shrouding combustion flame demonstrates some advantages in quick melting and effective slag foaming by delivering lime powder deeply into the molten bath.Combining the discrete particle model and the eddy dissipation concept model with the detailed chemical kinetic mechanisms(GRI-Mech 3.0),computational fluid dynamics models of the O_(2)-CaO jet with different shrouding fuel mediums injection were developed.Firstly,the results of the numerical simulation were validated by the measured data of cold test for O_(2)-CaO injection.Then,the interaction between the particles and the gas jet of the O_(2)-CaO jet and the effect of shrouding fuel medium species on the fluid flow characteristics of the O_(2)-CaO jet were analyzed.Results show that the CaO particles can be effectively heated by the shrouding high-temperature combustion flame and compared with the O_(2)-CaO jet without shrouding gas,the potential core length was increased about 2.5,3.3 and 4.3 times by the shrouding flame generated from CO,CH_(4) and C_(3)H_(8).And with shrouding CH_(4) and C_(3)H_(8) injection,the CaO particles can be clustered together in a long distance,which would be helpful to improve the utilization efficiency of CaO particles.
