为了降低Ca Ti O3-（La,Nd）Al O3（简称CT-LNA）陶瓷的烧结温度和提高其介电性能,研究纳米Al2O3对Ca Ti O3-（La,Nd）Al O3陶瓷的烧结温度和介电性能的影响。固相法制备粉料,采用XRD和SEM分析其晶相和显微结构,用网络分析测试样品的介...为了降低Ca Ti O3-（La,Nd）Al O3（简称CT-LNA）陶瓷的烧结温度和提高其介电性能,研究纳米Al2O3对Ca Ti O3-（La,Nd）Al O3陶瓷的烧结温度和介电性能的影响。固相法制备粉料,采用XRD和SEM分析其晶相和显微结构,用网络分析测试样品的介电参数,结果表明,纳米Al2O3可促进陶瓷烧结,在1320~1400℃范围内可烧结成瓷,并具有较好的微波介电性能。当纳米Al2O3含量为50 wt%时,陶瓷在1340℃烧结可获得优良的微波介电性能：介电常数为42.6,Q×f值高达34,000GHz,频率温度系数为＋4.8 ppm/℃。展开更多
According to time-dependent density functional theory(TDDFT),we study the interactions between ultra-fast laser pulses and two kinds of calcium titanate quantum dots(PCTO-QDs and MCTO-QDs).Under the action of localize...According to time-dependent density functional theory(TDDFT),we study the interactions between ultra-fast laser pulses and two kinds of calcium titanate quantum dots(PCTO-QDs and MCTO-QDs).Under the action of localized field effect,ultrafast laser can induce quantum dots to make the transition from insulator to metal.The PCTO-QDs are ultimately metallic,while the MCTO-QDs are still insulator after experiencing metal state.This is bacause the stability of the unsaturated atoms in the outermost layer of PCTO-QDs is weak and the geometric configuration of MCTO-QDs as a potential well will also reduce the damage of laser.Moreover,laser waveforms approaching to the intrinsic frequency of quantum dots tend to cause the highest electron levels to cross the Fermi surface.In this paper,it is reported that the insulating quantum dots can be transformed into metal by adjusting the intensity and frequency of laser.The importance of local morphology is emphasized by comparing two kinds of CTO-QDs.More importantly,it is an important step to identify the potential properties of perovskite materials.展开更多
In this paper, a detailed study was carried out on the PTFE reinforced with TiO2 and CaTiO3. The filler content of ceramic powder was a fixed value of 61 wt% and the content of CaTiO3 in PTFE matrix varied from 0 wt% ...In this paper, a detailed study was carried out on the PTFE reinforced with TiO2 and CaTiO3. The filler content of ceramic powder was a fixed value of 61 wt% and the content of CaTiO3 in PTFE matrix varied from 0 wt% to 16 wt% with a step size of 4 wt%. The effects of CaTiO3 loading on the density, moisture absorption, thermal expansion, microstructure and microwave dielectric properties were investigated. As CaTiO3 loading content increased from 0 wt% to 16 wt%, the thermal expansion initially displayed a sharp increase, and showed a slight enhancement when the content of CaTiO3 exceeded 12 wt%. The density experienced a continuous decrease with the addition of CaTiO3. The moisture absorption displayed a steady increase with the increasing CaTiO3 loading amount. The changing of dielectric constant (εr) and loss tangent (tanδ) were similar to that of the moisture absorption in a manner. Good dielectric properties with values of εr = 11.60, tanδ = 0.002 were obtained in the PTFE matrix with 16 wt% CaTiO3 and 45 wt% TiO2.展开更多
文摘为了降低Ca Ti O3-（La,Nd）Al O3（简称CT-LNA）陶瓷的烧结温度和提高其介电性能,研究纳米Al2O3对Ca Ti O3-（La,Nd）Al O3陶瓷的烧结温度和介电性能的影响。固相法制备粉料,采用XRD和SEM分析其晶相和显微结构,用网络分析测试样品的介电参数,结果表明,纳米Al2O3可促进陶瓷烧结,在1320~1400℃范围内可烧结成瓷,并具有较好的微波介电性能。当纳米Al2O3含量为50 wt%时,陶瓷在1340℃烧结可获得优良的微波介电性能：介电常数为42.6,Q×f值高达34,000GHz,频率温度系数为＋4.8 ppm/℃。
基金Project supported by the National Key Research and Development Program of China(Grant No.2017YFA0303600)the National Natural Science Foundation of China(Grant Nos.11974253 and 11774248).
文摘According to time-dependent density functional theory(TDDFT),we study the interactions between ultra-fast laser pulses and two kinds of calcium titanate quantum dots(PCTO-QDs and MCTO-QDs).Under the action of localized field effect,ultrafast laser can induce quantum dots to make the transition from insulator to metal.The PCTO-QDs are ultimately metallic,while the MCTO-QDs are still insulator after experiencing metal state.This is bacause the stability of the unsaturated atoms in the outermost layer of PCTO-QDs is weak and the geometric configuration of MCTO-QDs as a potential well will also reduce the damage of laser.Moreover,laser waveforms approaching to the intrinsic frequency of quantum dots tend to cause the highest electron levels to cross the Fermi surface.In this paper,it is reported that the insulating quantum dots can be transformed into metal by adjusting the intensity and frequency of laser.The importance of local morphology is emphasized by comparing two kinds of CTO-QDs.More importantly,it is an important step to identify the potential properties of perovskite materials.
文摘In this paper, a detailed study was carried out on the PTFE reinforced with TiO2 and CaTiO3. The filler content of ceramic powder was a fixed value of 61 wt% and the content of CaTiO3 in PTFE matrix varied from 0 wt% to 16 wt% with a step size of 4 wt%. The effects of CaTiO3 loading on the density, moisture absorption, thermal expansion, microstructure and microwave dielectric properties were investigated. As CaTiO3 loading content increased from 0 wt% to 16 wt%, the thermal expansion initially displayed a sharp increase, and showed a slight enhancement when the content of CaTiO3 exceeded 12 wt%. The density experienced a continuous decrease with the addition of CaTiO3. The moisture absorption displayed a steady increase with the increasing CaTiO3 loading amount. The changing of dielectric constant (εr) and loss tangent (tanδ) were similar to that of the moisture absorption in a manner. Good dielectric properties with values of εr = 11.60, tanδ = 0.002 were obtained in the PTFE matrix with 16 wt% CaTiO3 and 45 wt% TiO2.
