Y^3＋-doped （Bi 1/2 Na 1/2） TiO 3-CaTiO 3-BaTiO 3 （BNCBT） positive temperature coefficient of resistivity （PTCR） ceramics sintered in air atmosphere were investigated in this study. （Bi 1/2 Na 1/2） TiO 3 （BNT...Y^3＋-doped （Bi 1/2 Na 1/2） TiO 3-CaTiO 3-BaTiO 3 （BNCBT） positive temperature coefficient of resistivity （PTCR） ceramics sintered in air atmosphere were investigated in this study. （Bi 1/2 Na 1/2） TiO 3 （BNT） component can remarkably increase the onset temperature T c of PTCR ceramics with the expense of the resistivity R 25 increase. CaTiO 3 （9–27 mol%） component can decrease the resistivity, and adjust the effects of BNT phase on the T c point. For the sample containing 3 mol% CaTiO 3 , T c raises from 122 ℃ to 153 ℃ when only 0.6 mol% BNT added, while for the ones with higher CaTiO 3 content （9–27 mol%）, T c is only increased by a rate of 8–9℃/1.0 mol% BNT. The effects of BNT and CaTiO 3 components on R25/Rmin （negative temperature coefficient effect） are also discussed.展开更多
We prepared (1-x)CaTiO3-xLaAlO3 (0 ≤x≤ 1) microwave dielectric ceramics using a conventional two-step solid-state reaction method,and investigated microwave dielectric properties of the ceramics in terms of A/B-site...We prepared (1-x)CaTiO3-xLaAlO3 (0 ≤x≤ 1) microwave dielectric ceramics using a conventional two-step solid-state reaction method,and investigated microwave dielectric properties of the ceramics in terms of A/B-site ionic-parameters.Ionic-parameters such as ionic polarizability,A-site bond valence,and ionic rattling were linked to the microwave dielectric properties.As the LaAlO3 content x in the (1-x)CaTiO3-xLaAlO3 ceramics increased from 0.3 to 0.7,the dielectric constant gradually decreased,which was attributed to the decrease of polarizability deviation and suppression of the cation rattling.The temperature coefficient of the resonant frequency decreased as the content of LaAlO3 increased because of the increase of A-site cation bond valence.The quality factor value (Q × f) increased as LaAlO3 content increased because of the enhancement of the order degree of B-site cation.A significant deterioration of the temperature coefficient of the resonant frequency and Q ×fvalue was observed at the composition x =0.5.These decreases were attributed to a phase transition from orthorhombic crystal (for x ≤ 0.5) to rhombohedral crystal (for x ＞ 0.5).展开更多
基金Project supported by the SPAT of Shanghai Committee of Chinese People's Political Consultative Conference and Shanghai Education Development Foundation (Grant No.2008012)
文摘Y^3＋-doped （Bi 1/2 Na 1/2） TiO 3-CaTiO 3-BaTiO 3 （BNCBT） positive temperature coefficient of resistivity （PTCR） ceramics sintered in air atmosphere were investigated in this study. （Bi 1/2 Na 1/2） TiO 3 （BNT） component can remarkably increase the onset temperature T c of PTCR ceramics with the expense of the resistivity R 25 increase. CaTiO 3 （9–27 mol%） component can decrease the resistivity, and adjust the effects of BNT phase on the T c point. For the sample containing 3 mol% CaTiO 3 , T c raises from 122 ℃ to 153 ℃ when only 0.6 mol% BNT added, while for the ones with higher CaTiO 3 content （9–27 mol%）, T c is only increased by a rate of 8–9℃/1.0 mol% BNT. The effects of BNT and CaTiO 3 components on R25/Rmin （negative temperature coefficient effect） are also discussed.
文摘We prepared (1-x)CaTiO3-xLaAlO3 (0 ≤x≤ 1) microwave dielectric ceramics using a conventional two-step solid-state reaction method,and investigated microwave dielectric properties of the ceramics in terms of A/B-site ionic-parameters.Ionic-parameters such as ionic polarizability,A-site bond valence,and ionic rattling were linked to the microwave dielectric properties.As the LaAlO3 content x in the (1-x)CaTiO3-xLaAlO3 ceramics increased from 0.3 to 0.7,the dielectric constant gradually decreased,which was attributed to the decrease of polarizability deviation and suppression of the cation rattling.The temperature coefficient of the resonant frequency decreased as the content of LaAlO3 increased because of the increase of A-site cation bond valence.The quality factor value (Q × f) increased as LaAlO3 content increased because of the enhancement of the order degree of B-site cation.A significant deterioration of the temperature coefficient of the resonant frequency and Q ×fvalue was observed at the composition x =0.5.These decreases were attributed to a phase transition from orthorhombic crystal (for x ≤ 0.5) to rhombohedral crystal (for x ＞ 0.5).
