The rapid development and widespread use of ZnO nanoparticles(nZnO) in various industries have raised concerns about their potential environmental impact.Therefore,understanding the fate and role of nZnO in the natura...The rapid development and widespread use of ZnO nanoparticles(nZnO) in various industries have raised concerns about their potential environmental impact.Therefore,understanding the fate and role of nZnO in the natural environment is crucial for mitigating their hazardous effects on the environment and human safety.The purpose of the present study was to provide scientific support for understanding and eliminating the joint risk of nanoparticle and heavy metal pollution in the soil environment by revealing the co-transport characteristics of Cd(Ⅱ) and ZnO nanoparticles(nZnO) in soil under different ionic strength(IS) and pH.The impacts of different IS and pH on the co-transport of Cd(Ⅱ) and nZnO in a20 cm long with an inner diameter of 2.5 cm acrylic column packed with 10 cm high soil samples were investigated in the present study.In the above system,a500 μg L^(-1) Cd(Ⅱ) loaded nZnO suspension pulse with varying IS or pH was introduced into the soil column for leaching over 5 PVs,followed up by 5 PVs background solutions without nZnO.The IS was 1,10,or 50 mM NaCl,with pH6,or the pH was 6,7 or 8 with 1 mM NaCl.Meanwhile,Sedimentation experiments for nZnO,adsorption of Cd(Ⅱ) on soil,and nZnO,DLVO theory calculation for the same background condition were conducted.The presence of nZnO significantly increased the mobility of Cd(Ⅱ) as a result of its strong adsorption capacity for nZnO-associated Cd(Ⅱ).However,with the increase of IS,the co-transport of nZnO and Cd(Ⅱ) was decreased and the retention of nZnO in the soil column due to more nZnO attended to aggregate and sediment during the transport and the decrease in the adsorption capacity of nZnO for Cd(Ⅱ) by competition of Na^(+).When pH was 6,7,and 8,the co-transport of nZnO and Cd(Ⅱ) increased with higher pH due to the lower electrostatic attraction between nZnO and soil under higher pH.Meanwhile,the DLVO theory was fitted to describe the above co-transport process of nZnO and Cd(Ⅱ).More attention should be paid to the presence of nZnO on the migration of Cd(Ⅱ) in the natural soil to control the potential risk of nanoparticles and heavy metals to the environment.The risk of co-transport of nZnO and Cd(Ⅱ) might be controlled by adjusting IS and pH in the soil solution.展开更多
A novel redox-active bipyridinium ligand N-（3-carboxyphenyl）-4,4＇-bipyridinium chloride （HCPBPyC1） and its coordination polymer {[Cd2（CPBPy）2（BDC）（H2O）2Cl2]·6H2O}n 1 （H2BDC = benzene-1,4-dicarboxylic ...A novel redox-active bipyridinium ligand N-（3-carboxyphenyl）-4,4＇-bipyridinium chloride （HCPBPyC1） and its coordination polymer {[Cd2（CPBPy）2（BDC）（H2O）2Cl2]·6H2O}n 1 （H2BDC = benzene-1,4-dicarboxylic acid） were synthesized and characterized. Crystallographic data for 1： C42H44Cd2Cl2N4O16, Mr = 1156.51, monoclinic, space group C2/c, a = 21.046（3）, b = 11.0036（15）, c = 20.012（3）A, β = 98.694（8）°, Z = 4, V = 4581.1（11）A3, Dc = 1.677 g/cm^3, F（000） = 2280 and μ = 1.120 mm^-1. Complex 1 possesses a thick and undulated two-dimensional layer with （6,3） topology, which interpenetrates with two others （above and below） to extend into a three-dimensional supramolecular framework.展开更多
Owing to exploring the biosorption mechanism of Fusarium oxysporum to Cd,the adsorption capacities of live and dead biomass of F.oxysporum strain KF2 were detected.The result showed both the live and dead biomass of s...Owing to exploring the biosorption mechanism of Fusarium oxysporum to Cd,the adsorption capacities of live and dead biomass of F.oxysporum strain KF2 were detected.The result showed both the live and dead biomass of strain KF2 could tolerate the Cd concentration up to 200 mg/L,and had the largest adsorption capacities for Cd,at 2.21 and 1.86 mg/g,respectively,with the inoculation amount of 3 g,the pH at 6,and the initial Cd concentration of 100 mg/L.The pseudo-second-order kinetic model(live biomass r^(2)>0.99,dead biomass r^(2)>0.90)was more suitable for describing the adsorption process of strain KF2.It indicated that the physicochemical adsorption on the cell surface might be the main pattern for Cd removal.Furthermore,the FTIR results showed that the main functional groups for cell wall to bind Cd were carboxyl,hydroxyl,amino,and phosphate.展开更多
以钙基蒙脱石原材料为空白对照,通过细胞活性实验和小鼠急性毒性实验对制备的土壤重金属钝化剂蒙脱石-OR-SH复合材料进行环境风险评价,结果显示,在受试样品浸出物浓度为8 mg/100 m L及以下时,蒙脱石-OR-SH及饱和吸附Cd的蒙脱石-OR-SH对K...以钙基蒙脱石原材料为空白对照,通过细胞活性实验和小鼠急性毒性实验对制备的土壤重金属钝化剂蒙脱石-OR-SH复合材料进行环境风险评价,结果显示,在受试样品浸出物浓度为8 mg/100 m L及以下时,蒙脱石-OR-SH及饱和吸附Cd的蒙脱石-OR-SH对K562细胞、人脐带间充质干细胞和人肝细胞的活性无显著性影响;小鼠毒性实验结果显示,其毒性分级1级,实际无毒性作用.蒙脱石-OR-SH修复Cd污染土壤的长效性盆栽研究显示,第一季的钝化效果显著,虽然之后效果依次递减,但在连续种植了四季盆栽后,蒙脱石-ORSH对土壤中的Cd仍保持显著的钝化效果.展开更多
基金supported by the National Key Research and Development Project of Chinathe National Natural Science Fund of China (Grant number 2018YFC1800403, 41571226)。
文摘The rapid development and widespread use of ZnO nanoparticles(nZnO) in various industries have raised concerns about their potential environmental impact.Therefore,understanding the fate and role of nZnO in the natural environment is crucial for mitigating their hazardous effects on the environment and human safety.The purpose of the present study was to provide scientific support for understanding and eliminating the joint risk of nanoparticle and heavy metal pollution in the soil environment by revealing the co-transport characteristics of Cd(Ⅱ) and ZnO nanoparticles(nZnO) in soil under different ionic strength(IS) and pH.The impacts of different IS and pH on the co-transport of Cd(Ⅱ) and nZnO in a20 cm long with an inner diameter of 2.5 cm acrylic column packed with 10 cm high soil samples were investigated in the present study.In the above system,a500 μg L^(-1) Cd(Ⅱ) loaded nZnO suspension pulse with varying IS or pH was introduced into the soil column for leaching over 5 PVs,followed up by 5 PVs background solutions without nZnO.The IS was 1,10,or 50 mM NaCl,with pH6,or the pH was 6,7 or 8 with 1 mM NaCl.Meanwhile,Sedimentation experiments for nZnO,adsorption of Cd(Ⅱ) on soil,and nZnO,DLVO theory calculation for the same background condition were conducted.The presence of nZnO significantly increased the mobility of Cd(Ⅱ) as a result of its strong adsorption capacity for nZnO-associated Cd(Ⅱ).However,with the increase of IS,the co-transport of nZnO and Cd(Ⅱ) was decreased and the retention of nZnO in the soil column due to more nZnO attended to aggregate and sediment during the transport and the decrease in the adsorption capacity of nZnO for Cd(Ⅱ) by competition of Na^(+).When pH was 6,7,and 8,the co-transport of nZnO and Cd(Ⅱ) increased with higher pH due to the lower electrostatic attraction between nZnO and soil under higher pH.Meanwhile,the DLVO theory was fitted to describe the above co-transport process of nZnO and Cd(Ⅱ).More attention should be paid to the presence of nZnO on the migration of Cd(Ⅱ) in the natural soil to control the potential risk of nanoparticles and heavy metals to the environment.The risk of co-transport of nZnO and Cd(Ⅱ) might be controlled by adjusting IS and pH in the soil solution.
基金the National Natural Science Foundation of China (No. 20671090/5037206)the Key Project from CAS (No. KJCX2. YW.H01)
文摘A novel redox-active bipyridinium ligand N-（3-carboxyphenyl）-4,4＇-bipyridinium chloride （HCPBPyC1） and its coordination polymer {[Cd2（CPBPy）2（BDC）（H2O）2Cl2]·6H2O}n 1 （H2BDC = benzene-1,4-dicarboxylic acid） were synthesized and characterized. Crystallographic data for 1： C42H44Cd2Cl2N4O16, Mr = 1156.51, monoclinic, space group C2/c, a = 21.046（3）, b = 11.0036（15）, c = 20.012（3）A, β = 98.694（8）°, Z = 4, V = 4581.1（11）A3, Dc = 1.677 g/cm^3, F（000） = 2280 and μ = 1.120 mm^-1. Complex 1 possesses a thick and undulated two-dimensional layer with （6,3） topology, which interpenetrates with two others （above and below） to extend into a three-dimensional supramolecular framework.
基金Sponsored by University-Enterprise Science and Technology Cooperation Project between Hubei Polytechnic University and Huangshi Branch of Hubei West Hubei Geological Survey and Design Institute Co.,Ltd.(KY2022-160)。
文摘Owing to exploring the biosorption mechanism of Fusarium oxysporum to Cd,the adsorption capacities of live and dead biomass of F.oxysporum strain KF2 were detected.The result showed both the live and dead biomass of strain KF2 could tolerate the Cd concentration up to 200 mg/L,and had the largest adsorption capacities for Cd,at 2.21 and 1.86 mg/g,respectively,with the inoculation amount of 3 g,the pH at 6,and the initial Cd concentration of 100 mg/L.The pseudo-second-order kinetic model(live biomass r^(2)>0.99,dead biomass r^(2)>0.90)was more suitable for describing the adsorption process of strain KF2.It indicated that the physicochemical adsorption on the cell surface might be the main pattern for Cd removal.Furthermore,the FTIR results showed that the main functional groups for cell wall to bind Cd were carboxyl,hydroxyl,amino,and phosphate.
文摘以钙基蒙脱石原材料为空白对照,通过细胞活性实验和小鼠急性毒性实验对制备的土壤重金属钝化剂蒙脱石-OR-SH复合材料进行环境风险评价,结果显示,在受试样品浸出物浓度为8 mg/100 m L及以下时,蒙脱石-OR-SH及饱和吸附Cd的蒙脱石-OR-SH对K562细胞、人脐带间充质干细胞和人肝细胞的活性无显著性影响;小鼠毒性实验结果显示,其毒性分级1级,实际无毒性作用.蒙脱石-OR-SH修复Cd污染土壤的长效性盆栽研究显示,第一季的钝化效果显著,虽然之后效果依次递减,但在连续种植了四季盆栽后,蒙脱石-ORSH对土壤中的Cd仍保持显著的钝化效果.
