A geochemical perspective on the genesis of Cenozoic basic volcanism in northeastern Turkey:an overview of metasomatism and heterogeneity of the sub-continental lithospheric mantle in a post-collisional setting

The post-collisional Cenozoic basic volcanic rocks in NE Turkey show temporal variations in whole-rock lithophile element and highly siderophile element(HSE)systematics that are mainly associated with the nature of sub-continental lithospheric mantle(SCLM)sources and parental melt generation.So far,the traditional whole-rock lithophile geochemical data of these basic volcanic rocks have provided important constraints on the nature of SCLM sources.Integrated lithophile element and HSE geochemical data of these basic volcanic rocks also reveal the heterogeneity of the SCLM source,which is principally related to variable metasomatism resulting from previous subduction(s)and post-collisional mantle-crust interactions in an extensional setting.Lithophile element geochemical features suggest that the parental magmas have derived from metasomatized spinel-to garnet-bearing SCLM sources for Eocene and Miocene basic volcanic rocks with subduction signatures whereas originated from spinel-to garnet-bearing SCLM sources for Mio-Pliocene and Plio-Quaternary basaltic volcanic rocks without the subduction signature.Lithophile element and HSE geo-chemistry also reveal that Eocene and Miocene basic vol-canic rocks were affected by more pronounced crustal contamination than the basaltic volcanic rocks of Mio-Pliocene and Quaternary.Furthermore,the integrated lithophile element and HSE compositions of these basic volcanic rocks,together with the regional asymmetric lithospheric delamination model,reveal that the compositional variation(especially due to metasomatism)was significant temporally in the heterogeneity of the SCLM sources from which parental magmas formed during the Cenozoic era.

Southern Hemisphere Volcanism Triggered Multi-year La Niñas during the Last Millennium

To explain the recent three-year La Niña event from 2020 to 2022,which has caused catastrophic weather events worldwide,Fasullo et al.(2023)demonstrated that the increase in biomass aerosol resulting from the 2019-20 Australian wildfire season could have triggered this multi-year La Niña.Here,we present compelling evidence from paleo-proxies,utilizing a substantial sample size of 26 volcanic eruptions in the Southern Hemisphere(SH),to support the hypothesis that ocean cooling in the SH can lead to a multi-year La Niña event.This research highlights the importance of focusing on the Southern Ocean,as current climate models struggle to accurately simulate the Pacific response driven by the Southern Ocean.

Late Jurassic Volcanism Deduced from Geochemical,Geochronological,and Sr-Nd-Hf Isotopic Composition Characteristics of the Nanyuan Formation,South China

The Nanyuan Formation contains information related to the Mesozoic tectonic transformation.In this study,three representative profiles were surveyed from the Nanyuan Formation,and multiple analyses were conducted.Zircon U-Pb dating yielded their ages as approximately 158–146 Ma.The volcanic rocks are enriched in Rb,Th,U,K,and Pb and depleted in Nb,Ta,P,and Ti,implying their affinity for I-type granites.TheεNd(t)values(-8.3 to-6.0),^(87)Sr/^(86)Sr)i values(0.7077–0.7094)of the volcanic rock,andεHf(t)values(-8.71 to 0.12)of the Mesozoic zircons suggest that the Nanyuan Formation magma originated in the lower crust with the involvement of depleted mantle materials.The parent rocks of the rhyolitic and dacitic volcanic rocks formed by partial melting of basement rocks in South China and the andesitic volcanic rocks were derived from partial melting of the metasomatites generated by slab-mantle interaction.The fractional crystallization also played an important role in later stage.Discrimination diagrams of the volcanic rocks indicated that they formed in a volcanic arc environment.Combined with previous data,the Nanyuan Formation recorded subduction of the Paleo-Pacific Plate before regional tectonic transformation.The compressive stress field endured until the end of the Late Jurassic.

Volcanism Pacing Slumping Gravity Flow Deposits during the Late Carboniferous in the Southern Margin of the Junggar Basin,China

Deep-water gravity depositional processes and evolution in arc systems have become topics of intense research focus in recent years.This study discusses the co-evolution of volcanism and deep-water gravity flow deposits at the southern margin of the Junggar Basin,based on petrology,geochronology and geochemical analyses.The results show that a massive collapse of unstable sediments from the slope was triggered by volcanism,resulting in the formation of slumping gravity flows.The occurrence of volcanic beds in the slump deposits confirm that synchronous volcanism likely affected sediment instability,triggering gravity flows.The Th/Yb,Ta/Yb and Th/Ta elemental ratios,U-Pb ages of detrital zircons and paleocurrent directions indicate that the North Tianshan(NTS)island arc represents the provenance of the Qianxia Formation.Moreover,statistical data on the pyroclastic components in the gravity flow deposits reveal an intensity index of volcanism,indicating that volcanism is strongly related to gravity flow deposits,especially in terms of the type and distribution of the deposits.A model for volcanically-triggered deep-water gravity flow deposits is established,in order to provide a more in-depth understanding of the co-evolution of volcanism and gravity flow deposits within the depositional setting of the late Paleozoic NTS oceanic subduction margin in the Junggar Basin.

Petrological and Structural Approach to Understanding the Mechanism of Formation and Development of Paleoproterozoic Calc-Alkaline Volcanic Rocks of West Africa’s Craton: An Example of the Mako and Foulde Groups (Kedougou Inlier in Western Senegal)

The calc-alkaline volcanic formations in the western part of the Kedougou-Kenieba inlier crop out in three complexes: the Foulde in the North and the areas of Mako and Baniomba in the South. These complexes which either combine with the tholeiites or cut across the sedimentary formations are composed of thin veins and massive lava flows. They have many petrographic similarities and show chemical characteristics that resemble those of island-arc rocks. At the tectonic level, the D1 deformation phase preceding the formation of the basins and the transpressive tectonics including an oblique convergence may account for the structural evolution of the Mako volcanic belt. Its occurrence in different basins may be evidenced by the composition of some lithophilic components like the Sr, Ba, U, Rb and the composition of clinopyroxenes enriched in TiO2, FeO, Na2O in the Foulde calc-alkaline volcanic rocks that developed in a sedimentary environment.

Petrology of Spinel-Lherzolite Xenoliths from Mazéléand Others Northen Xenoliths Localities of Cameroon Volcanic Line: Exchange Reactions and Equilibrium State

The alkaline volcanism of the Cameroon Volcanic Line in its northern domain has raised many fresh enclaves of peridotites. The samples selected come from five (05) different localities (Liri, in the plateau of Kapsiki, Mazélé in the NE of Ngaoundéré, Tello and Ganguiré in the SE of Ngaoundéré and Likok, locality located in the west of Ngaoundé). The peridotite enclaves of the above localities show restricted mineralogical variation. Most are four-phase spinel-lherzolites, indicating that this is the main lithology that forms the lithospheric mantle below the shallow zone. No traces of garnet or primary plagioclase were detected, which strongly limits the depth range from which the rock fragments were sampled. The textures and the wide equilibrium temperatures (884˚C - 1115˚C) indicate also entrainment of lherzolite xenoliths from shallow depths within the lithosphere and the presence of mantle diapirism. The exchange reactions and equilibrium state established in this work make it possible to characterize the chemical composition of the upper mantle of each region and test the equilibrium state of the phases between them. Variations of major oxides and incompatible elemental concentrations in clinopyroxene indicate a primary control by partial melting. The absence of typical “metasomatic” minerals, low equilibration temperatures and enriched LREE patterns indicate that the upper mantle below septentrional crust of Cameroun underwent an event of cryptic metasomatic enrichment prior to partial melting. The distinctive chemical features, LREE enrichment, strong U, Ce and Pr, depletion relative to Ba, Nb, La, Pb, and T, fractionation of Zr and Hf and therefore ligh high Zr/Hf ratio, low La/Yb, Nb/La and Ti/Eu are all results of interaction of refractory peridotite residues with carbonatite melts.

High-temperature corrosion of sintered RE_(2)Si_(2)O_(7)(RE=Yb and Ho)environmental barrier coating materials by volcanic ash

Rare-earth silicates are promising environmental barrier coatings(EBCs)that can protect SiC_(f)/Si C_(m)substrates in next-genera tion gas turbine blades.Notably,RE_(2)Si_(2)O_(7)(RE=Yb and Ho)shows potential as an EBC due to its coefficient of thermal expansion(CTE)compatible with substrates and high resistance to water vapor corrosion.The target operating temperature for next-generation tur bine blades is 1400°C.Corrosion is inevitable during adhesion to molten volcanic ash,and thus,understanding the corrosion behavior o the material is crucial to its reliability.This study investigates the high-temperature corrosion behavior of sintered RE_(2)Si_(2)O_(7)(RE=Yb and Ho).Samples were prepared using a solid-state reaction and hot-press method.They were then exposed to volcanic ash at 1400°C for 224,and 48 h.After 48 h of exposure,volcanic ash did not react with Yb_(2)Si_(2)O_(7)but penetrated its interior,causing damage.Meanwhile Ho_(2)Si_(2)O_(7)was partially dissolved in the molten volcanic ash,forming a reaction zone that prevented volcanic ash melts from penetrating the interior.With increasing heat treatment time,the reaction zone expanded,and the thickness of the acicular apatite grains increased The Ca:Si ratios in the residual volcanic ash were mostly unchanged for Yb_(2)Si_(2)O_(7)but decreased considerably over time for Ho_(2)Si_(2)O_(7).Th Ca in volcanic ash was consumed and formed apatite,indicating that RE^(3+)ions with large ionic radii(Ho>Yb)easily precipitated apatit from the volcanic ash.

Geochemistry of volcanic glass from Mahanadi offshore region,eastern continental margin of India:Constraints on the contribution of latest Toba super-eruption

The tephra layers in multiple sediment cores from the offshore region of the Mahanadi basin in the northern Bay of Bengal were investigated for possible volcanic sources. The glass shards from those tephra layers were studied for size distribution, texture, and elemental geochemistry to establish chronostratigraphic markers for regional and global Quaternary correlation. The textural features of fine-grained(silty) volcanic glasses suggest the distal source of these tephra deposits. Major element composition with elevated SiO_(2) contents ranging between75%–76% and dominance of K_(2)O(> 4.5%) over CaO(< 0.9%) suggest ashes have originated from siliceous rhyolitic melts, similar to the petrographic composition of tephra from the Toba volcano. The bulk trace element compositions of the same glass shards were comparable with those reported in the youngest Toba tephra reported elsewhere. Likewise, the LREE-dominated chondrite normalized REE profiles of tephra from the Mahanadi basin closely resemble the characteristic REE patterns in Toba ash from other parts of the Indian Ocean and thus confirmed the contribution of the youngest Toba super-eruption for this ash layers.

Mineralogy and geochemistry of trachytic rocks from the Lichi Volcanics, Eastern Himalaya: insights into the Kerguelen mantle plume activity in the Eastern Himalayan Region

The Lichi volcanics are a suite of mafic-intermediate-felsic rocks and are considered coeval with the Abor volcanics(~132 Ma) of the Siang window in the Eastern Himalaya. Here, we present the first report of trachytic rocks from the Lichi volcanics, which are exposed in the Ranga valley, along the Kimin-Yazali road section in the Eastern Himalayan Region, Northeast India. The trachytes occur in close association with sandstones of the Gondwana Group of rocks and are characterised based on field, petrographical, and geochemical investigations.These fine-grained trachytes are composed of alkali feldspar, biotite, plagioclase, sodic-amphibole, apatite, illmenite, and titanite. The REE profiles of the evolved trachytic rocks(higher SiO_(2)content) display fractionated trends. The fractionation of accessory mineral phases, like apatite and titanite, was possibly responsible for the strongly fractionated REE patterns of the evolved samples.The trachytic rocks demonstrate high apatite saturation temperatures of 988 ± 14 ℃(1σ, n = 8). The Aluminium Saturation Index(< 1.1) and binary discrimination diagrams of these peralkaline trachytes define their affinity with A-type granitoids. Elemental ratios like Y/Nb, Nb/U,and Ce/Pb signify that the Lichi trachytes are differentiated products of mantle-derived ocean island basalts. Trace elemental discrimination diagrams Th/Yb versus Nb/Yb, Y versus Nb, and Y + Nb versus Rb reflect a within-plate tectonic regime for the trachytes. From the results presented in this work, we infer that the development of rifting events during the breakup of eastern Gondwana due to the onset of Kerguelen plume activity further led to underplating of basic magma in lower crustal levels. These parental basaltic magmas underwent fractionation processes forming differentiated trachyandesites and trachytes.Taking into consideration the similarities recorded between the Lichi volcanics and Abor volcanics, this study supports the idea that Kerguelen plume activities resulted in the emplacement of these volcanics in the Eastern Himalayas.

Facies logging identification of intermediate-basic volcanic rocks in Huoshiling Formation of Songliao Basin

Volcanic oil and gas reservoirs are generally buried deep,which leads to a high whole-well coring cost,and the degree of development and size of reservoirs are controlled by volcanic facies.Therefore,accurately identifying volcanic facies by logging curves not only provides the basis of volcanic reservoir prediction but also saves costs during exploration.The Songliao Basin is a‘fault-depression superimposed’composite basin with a typical binary filling structure.Abundant types of volcanic lithologies and facies are present in the Lishu fault depression.Volcanic activity is frequent during the sedimentary period of the Huoshiling Formation.Through systematic petrographic identification of the key exploratory well(SN165C)of the Lishu fault-depression,which is a whole-well core,it is found that the Huoshiling Formation in SN165C contains four facies and six subfacies,including the volcanic conduit facies(crypto explosive breccia subfacies),explosive facies(pyroclastic flow and thermal wave base subfacies),effusive facies(upper and lower subfacies),and volcanogenic sedimentary facies(pyroclastic sedimentary subfacies).Combining core,thin section,and logging data,the authors established identification markers and petrographic chart logging phases,and also interpreted the longitudinal variation in volcanic petro-graphic response characteristics to make the charts more applicable to this area's volcanic petrographic interpretation of the Huoshiling Formation.These charts can provide a basis for the further exploration and development of volcanic oil and gas in this area.

Carboniferous Post-collisional Rift Volcanism of the Tianshan Mountains, Northwestern China

The Tianshan Carboniferous post-collisional rift volcanic rocks occur in northwestern China as a large igneous province. Based on petrogeochemical data, the Tianshan Carboniferous post-collisional rift basic lavas can be classified into two major magma types: (1) the low-Ti/Y type situated in the eastern-central Tianshan area, which exhibits low Ti/Y (<500), Ce/Yb (<15) and SiO2 (43-55%), and relatively high Fe2O3T (6.4-11.5%); (2) the high-Ti/Y type situated in the western Tianshan area, which has high Ti/Y (>500), Ce/Yb (>11) and SiO2 (49-55%), and relatively low Fe2O3T (5.8-7.8%). Elemental data suggest that chemical variations of the low-Ti/Y and high-Ti/Y lavas cannot be explained by fractional crystallization from a common parental magma. The Tianshan Carboniferous basic lavas originated most likely from an OIB-like asthenospheric mantle source (87Sr/86Sr(t) ≈ 0.703-0.705, eNd(0 = +4 to +7). The crustal contamination and continental lithospheric mantle have also contributed significantly to the formation of the basic lavas of the Tianshan Carboniferous post-collisional rift. The silicic lavas were probably generated by partial melting of the crust. The data of this study show that spatial petrogeochemical variations exist in the Carboniferous post-collisional rift volcanics province in the Tianshan region. Occurrence of the thickest volcanics dominated by tholeiitic lavas may imply that the center of the mantle-melting anomaly (mantle plume) was in the eastern Tianshan area at that time. The basic volcanic magmas in the eastern Tianshan area were generated by a relatively high degree of partial melting of the mantle source around the spinel-garnet transition zone, whereas the alkaline basaltic lavas are of the dominant magma type in the western Tianshan area, which were generated by a low degree of partial melting of the mantle source within the stable garnet region, thus the basic lavas of the western Tianshan area might have resulted from relatively thick lithosphere and low geothermal gradient.

U-Pb geochronology and geochemistry of late Palaeozoic volcanism in Sardinia(southern Variscides)

The latest Carboniferous to lower Permian volcanism of the southern Variscides in Sardinia developed in a regional continental transpressive and subsequent transtensile tectonic regime.Volcanism produced a wide range of intermediate-silicic magmas including medium-to high-K calc-alkaline andesites,dacites,and rhyolites.A thick late Palaeozoic succession is well exposed in the four most representative Sardinian continental basins(Nurra,Perdasdefogu,Escalaplano,and Seui-Seulo),and contains substantial stratigraphic,geochemical,and geochronological evidence of the area's complex geological evolution from the latest Carboniferous to the beginning of the Triassic.Based on major and trace element data and LA-ICP-MS U-Pb zircon dating,it is possible to reconstruct the timing of postVariscan volcanism.This volcanism records active tectonism between the latest Carboniferous and Permian,and post-dates the unroofing and erosion of nappes in this segment of the southern Variscides.In particular,igneous zircon grains from calc-alkaline silicic volcanic rocks yielded ages between299±1 and 288±3 Ma,thereby constraining the development of continental strike-slip faulting from south(Escalaplano Basin)to north(Nurra Basin).Notably,andesites emplaced in medium-grade metamorphic basement(Mt.Cobingius,Ogliastra)show a cluster of older ages at 332±12 Ma.Despite the large uncertainty,this age constrains the onset of igneous activity in the mid-crust.These new radiometric ages constitute:(1)a consistent dataset for different volcanic events;(2)a precise chronostratigraphic constraint which fits well with the biostratigraphic data and(3)insights into the plate reorganization between Laurussia and Gondwana during the late Palaeozoic evolution of the Variscan chain.

Mesozoic Volcanism Surrounding Songliao Basin,China: Implication for the Relationship with Evolution of Basin

esozoic volcanic rocks developed on the basement of the Precambrian block and Hercynina orogenic belt surrounding Songliao basin. The volcanism was actived from Early Jurassic to Late Cretaceous with its peak time in J3-K1 and the rock types are dominated by high K calcalkaline series, partly consisting of shoshonitic and calcalkaline series. Mesozoic volcanism of studied area may result from decompression melting accompanying uneven extension wide spread at a large area corresponding to the formation of grabens without contemporaneous subduction in J3-K1. The basic volcanics and their differentiates came from an enriched lithospheric mantle. While in K2 the extensional center concentrated at Songliao basin and the equivalent products are basalts rich in Na and poor in K and the magma generated from the top of asthenosphere about 60 km. During this time large Songliao depression was developed.

Cenozoic Volcanism in South China Sea and Its Vicinity and South China Sea Spreading

The rock series, rock types and Sr Nd isotopic dating of the Cenozoic volcanic rocks in the South China Sea are similar to those in its vicinity. On the basis of the spreading age of the South China Sea, the Cenozoic volcanic rocks are divided into three stages: the pre spreading stage, the spreading stage and the post spreading stage. The deep process characteristics of the asthenosphere and lithosphere may be inferred from the study on primary basaltic magma. The top layers of the asthenosphere both in the spreading stage and in the pre spreading stage are closer to the earth surface than that in the post spreading stage. From the pre spreading stage to the spreading stage, the top layer of the asthenosphere decreased in depth, while the amount of interstitial partial melts increased. The evolution of the primary basaltic magma shows a progressive evolution sequence of the rifting volcanism and a faster lithospheric spreading velocity. From the spreading stage to the post spreading stage, the top layer of the asthenosphere gradually increased in depth, but the amount of interstitial partial melts decreased. The evolution of primary basaltic magma shows a retrogressive evolution sequence of the rifting volcanism and a gradual decrease in the lithospheric spreading velocity. The depth recognized by the study on the Cenozoic volcanism demonstrates the deep environment for the formation and evolution of the South China Sea.

Ore-forming Response to Syndepositional Submarine Volcanism in Langshan-Zhaertai Mesoproterozoic SEDEX Ore Belt, Inner Mongolia, China

Ore forming process of the Dongshengmiao, Huogeqi, Tanyaokou and Jiashengpan deposits in Langshan Zhaertai Mesoproterozoic SEDEX metallogenic belt is closely related to the syndepositional volcanic activities based on the following facts: (1) The Sm Nd isochron age of the basic volcanic rocks varies from 1 491 Ma to 1 824 Ma (more than or close to the model age of the lead isotope of all sulfide minerals) in these deposits, with ε (Nd, t ) =(3.48-6.40)±0.80, whose REE composition is enriched in LREE and depleted in HREE, indicating that these volcanic rocks were derived from the mantle or lower crust. (2) The REE composition of some Pb Zn Py ores is also enriched in LREE and depleted in HREE. The chondrite normalized REE patterns are similar to those of the basic volcanic rocks. (3) In the lead isotope composition diagram of Doe and Zartman, most of sphalerite, galena, pyrite, pyrrhotite and chalcopyrite are plotted on both sides of the line for the mantle or between the lines for the mantle and lower crust. (4) Cobalt content of some pyrites is much higher than their nickel content ( w (Co)/ w (Ni)= 11.91- 12.19). (5) Some volcanic blocks and debrises have been picked out from some pyrite and pyrrhotite ores. (6) All Zn Pb Cu Fe sulfide orebodies in these deposits occur in the strata overlying the metamorphic volcanic rocks in the only second ore bearing formation. The Jiashengpan deposit lacks in syndepositional volcanic rocks in the host succession, only Pb and Zn occur without Cu, but the Dongshengmiao, Tanyaokou and Huogeqi deposits with syndepositonal volcanic rocks in the host succession contain Cu, indicating the relatively high ore forming temperatures, besides Pb and Zn. The syndepositional volcanic eruption directly supplied some ore forming metals and resulted in the secular geothermal anomaly favorable for the circulation of the submarine convective hydrothermal system, and in the precipitation of deep mineralizing fluids exhaling into the anoxide basins along the syndepositional fault system in the Langshan Zhaertai rift.

Geochemistry and petrogenesis of Quaternary volcanism from the islets in the eastern Beibu Gulf: evidence for Hainan plume

Some of the islets in the eastern Beibu Gulf are covered by Quaternary volcano strata. The rock samples from these islets mainly consist of quartz tholeiites （at Shenjiandao）, olivine tholeiites （at Linshidao and Xieyang- dao） and alkali basalts （at Yangpubi and Jianshidao）, and basically represent four periods of the Quaternary volcanism of Hainan Island and its adjacent regions. Except for the samples from Shenjiandao, most of the Quaternary volcanics of these islets belong to alkali magma series. The trace element characteristics of all of these samples show they are OIB （oceanic island basalt） -like, which implies that their deep geodynamic setting may be related to a mantle plume. The Sr-Nd-Pb isotopic compositions show that the mantle source beneath the Quaternary strata can be regarded as a result of binary mixing between a depleted, DMM （de- pleted MORB mantle）-like source and an enriched mantle type 2 （EM2）. The EM2 may be originated from the Hainan mantle plume, and has been metasomatized by carbonaceous fluids released from ancient re- cycled oceanic crust at an asthenospheric mantle level. These features, together with typical trace element ratios, reflect that the parent magma was not subjected to crustal contamination during its ascent to the surface. This study provides further petrological and geochemical evidence for the existence of the Hainan mantle plume.

Volcanism in Sanjiang Tethyan Orogenic Belt:New Facts and Concepts

Sanjiang area in Southwestern China is tectonically situated at the east end of Himalaya-Tethys tectonic domain and at the conjunction of Tethyan Mountain Chain and Circum-Pacific Mountain Chain. It is one of the key areas to understand the global tectonics and also one of gigantic metallogenic provinces in China and even in the world . Volcanism had occurred during the period of time from Proterozoic to Cenozoic . The most important and active periods of volcanism , however , are Carboniferous , Permian and Triassic . The pattern of spatial distribution of Sanjiang volcanic rocks and ophiolites can essentially be described as that several intra - continental micro-massif volcanic districts are respectively sandwiched between each two of four coupling ophioh'te - arc volcanic belts , which are successively from west to east : Dingqing - Nujiang belt , Lancangjiang belt , Jinshajiang belt and Ganzi-Litang belt . Four tectono - magma tic types of volcanic rocks have been rec-ognized in Sanjiang area as follows: mid -ocean- ridge/ para - mid - ocean - ridge type , arc type , collision type and intra - continent type . The petrotectonic assemblages within suture zones , such as oceanic assemblage , subduction - related assemblage , collision - related assemblage etc ., have been paid more attention to because of their significant importance in reconstruction of the history of Sanjiang Tethyan orogenic belt and plate tectonics .Couph'ng ophiolite - arc volcanic belt, para-mid - ocean - ridge volcanism and volcanic rocks, post -collision arc volcanism and volcanic rocks and tensional volcanic arc are newly defined in the present work . These new facts and concepts will be greatly beneficial to understanding the history of Sanjiang Tethyan plate tectonics and the complexity of the volcanism in orogenic belts and of the evolution of the continental lithosphere . A preliminary model of the evolution of Sanjiang Tethys under petrotectonic constraints was presented . It consists of the following four successive stages : (1) Late Paleozoic ocean spreading - dominant stage , (2 ) Early Mesozoic subduction and closing - dominant stage , (3) Late Mesozoic collisional orogenic stage characterized by crust shortening and compression , and (4 ) Cenozoic intra - continent orogenic stage characterized by crustal slipping - out and strike - slipping .

Paleosubmarine Volcanism and Mineralization from North Qilian Mountains

This paper summarizes the history of tectono magmatic evolution, the types and backgrounds of mineralization prior to the orogenic period of North Qilian Mountains. It points out that: during the process of Paleozoic ocean basin opening and closing, the large scale marine volcanism and massive sulfide deposits controlled by sea floor hydrothermal circulation systems are the two sharpest features in the geological developing history of the orogenic belt, which are also the most two important aspects related to each other and should be given a special attention in the geological studies in the region.

Petrogenesis of the Langdu High-K Calc-Alkaline Intrusions in Yunnan Province: Constraints from Geochemistry and Sr-Nd Isotopes

The Langdu high-K calc-alkaline intrusions are located in the Zhongdian area, which is the southern part of the Yidun island arc. These intrusive rocks consist mainly of monzonite porphyry, granodiorite, and diorite porphyry. The K20 content of majority of these rocks is greater than 3%, and, in the K20-SiO2 diagram, all the samples fall into the high-K calc-alkaline to shoshonitic fields. They are enriched in light rare earth elements （LREEs） and depleted in heavy rare earth elements （HREEs; LaN/YbN = 14.3-21.2）, and show slightly negative Eu anomalies （6Eu = 0.77-1.00）. These rocks have high K, Rb, Sr, and Ba contents; moderate to high enrichment of compatible elements （Cr = 36.7-79.9 ppm, Co = 9.6-16.4 ppm, and MgO = 2.2%-3.4%）; low Nb, Ta, and Ti contents, and characteristic of low high field strength elements（HFSEs） versus incompatible elements ratios （Nb/Th = 0.75, Nb/La = 0.34） and incompatible elements ratios （Nb/U = 3.0 and Ce/Pb = 5.1, Ba/Rb = 12.0）. These rocks exhibit restricted Sr and Nd isotopic compositions, with （87Sr/S6Sr）i values ranging from 0.7044 to 0.7069 and ENd（t） values from -2.8 to -2.2. The Sr-Nd isotope systematic and specific trace element ratios suggest that Langdu high-K calc-alkaline intrusive rocks derived from a metasomatized mantle source. The unique geochemical feature of intrusive rocks can be modeled successfully using different members of a slightly enriched mantle, a slab-derived fluid, and terrigenous sediments. It can be inferred that the degree of partial melting and the presence of specific components are temporally related to the tectonic evolution of the Zhongdian island arc. Formation of these rocks can be explained by the various degrees of melting within an ascending region of the slightly enriched mantle, triggered by the subduction of the Garz^--Litang ocean, and an interaction between the slab-derived fluid and the terrigenous sediments.

Volcanism and Tectonic Evolution in the North Qilian Mountains during Ordovician Period

The Ordovician marine volcanic rocks in the north Qilian mountains are discussed in this paper. According to geology, petrotectonic assemblage and geochemistry, a new model about plate tectonic evolution of the north Qilian mountains is set up. The Ordovician marine volcanic rocks in the north Qilian mountains which characterized by the geological features of tectonic melange of continent to continent collision underwent complicated tectonic movement, and can be classified into three main kinds of petrotectonic assemblages. During Ordovician period, north Qilian area was a polyisland ocean which consisted of three ocean basins separated by the middle microcontinental blocks.