The temperature distribution under shear with a high strain rate and the cooling rate of the shear bands of Al, Cu and 0.06C steel have been calculated using a computer. The results show that the temperature of shear ...The temperature distribution under shear with a high strain rate and the cooling rate of the shear bands of Al, Cu and 0.06C steel have been calculated using a computer. The results show that the temperature of shear band increases with the increase of the average strain rate (_o). When _o is in the range 8×10~5 to 10~6 1/s, the structure of the adiabatic shear band in a 0.06C steel is martensite but it becomes metallic glass if _o=10~6 1/s. As to A1 and Cu, the structure of the adiabatic shear bands can also be of metallic glass if _o is greater than 1.8×10~6 and 5.5×10~7 1/s respectively. It explains that Cu tends most difficultly to form adiabatic shear band, while 0.06C steel most readily among the three metals.展开更多
After the electron transfers from the metal electrode to the Fe3+(H2O)(6) ion, the free energy of activation of this electron transfer reaction is calculated, then using the transition probability which is calculated ...After the electron transfers from the metal electrode to the Fe3+(H2O)(6) ion, the free energy of activation of this electron transfer reaction is calculated, then using the transition probability which is calculated by the perturbed degeneration theory and the Fermi golden rule,, the rate constant is gotten. Compared with the experimental results, it is satisfactory.展开更多
To research the correlation between vibrational energy transition rates and acoustic relaxation processes in excitable gases, the vibrational relaxation theory provided by Tanczos [J. Chem. Phy3. 25, 439 （1956）] is ...To research the correlation between vibrational energy transition rates and acoustic relaxation processes in excitable gases, the vibrational relaxation theory provided by Tanczos [J. Chem. Phy3. 25, 439 （1956）] is applied to calculate the energy transition rates of Vibrational- Vibrational （V-V） and Vibrational-Translational （V-T） energy transfer in gas mixtures. The results of calculation for the multi-relaxation processes in various gas mixtures, consisting of carbon dioxide, methane, chlorine, nitrogen, and oxygen at room temperature, demonstrate that the acoustic energy stagnated in every vibrational mode is coupled with each other through V-V energy exchanges. The vibrational excitation energy will relax through the V-T de-excitation path of the lowest mode because of its fastest V-T transition rate, resulting in that only one absorption peak can be measured for most of excitable gas mixtures. Thus, an effective model is provided to analyze how the vibrational energy transition rates affect the characteristics of acoustic relaxation processes and acoustic propagation in excitable gas mixtures.展开更多
文摘The temperature distribution under shear with a high strain rate and the cooling rate of the shear bands of Al, Cu and 0.06C steel have been calculated using a computer. The results show that the temperature of shear band increases with the increase of the average strain rate (_o). When _o is in the range 8×10~5 to 10~6 1/s, the structure of the adiabatic shear band in a 0.06C steel is martensite but it becomes metallic glass if _o=10~6 1/s. As to A1 and Cu, the structure of the adiabatic shear bands can also be of metallic glass if _o is greater than 1.8×10~6 and 5.5×10~7 1/s respectively. It explains that Cu tends most difficultly to form adiabatic shear band, while 0.06C steel most readily among the three metals.
文摘After the electron transfers from the metal electrode to the Fe3+(H2O)(6) ion, the free energy of activation of this electron transfer reaction is calculated, then using the transition probability which is calculated by the perturbed degeneration theory and the Fermi golden rule,, the rate constant is gotten. Compared with the experimental results, it is satisfactory.
基金supported by the National Natural Science Foundation of China(61461008,61371139,61571201,61540051)the China Scholarship Council Project(201708525058)+1 种基金the National Science Foundation of Guizhou Province,China(Qian Ke He J Zi[2015]2065),Qian Ke He LH Zi[2014]7361)the Recruitment Program of Guizhou Institute of Technology(XJGC20140601,XJGC20150107)
文摘To research the correlation between vibrational energy transition rates and acoustic relaxation processes in excitable gases, the vibrational relaxation theory provided by Tanczos [J. Chem. Phy3. 25, 439 （1956）] is applied to calculate the energy transition rates of Vibrational- Vibrational （V-V） and Vibrational-Translational （V-T） energy transfer in gas mixtures. The results of calculation for the multi-relaxation processes in various gas mixtures, consisting of carbon dioxide, methane, chlorine, nitrogen, and oxygen at room temperature, demonstrate that the acoustic energy stagnated in every vibrational mode is coupled with each other through V-V energy exchanges. The vibrational excitation energy will relax through the V-T de-excitation path of the lowest mode because of its fastest V-T transition rate, resulting in that only one absorption peak can be measured for most of excitable gas mixtures. Thus, an effective model is provided to analyze how the vibrational energy transition rates affect the characteristics of acoustic relaxation processes and acoustic propagation in excitable gas mixtures.
