Highly Improved Microstructure and Properties of Poly(p-phenylene terephthalamide) Paper-based Materials via Hot Calendering Process

In this study,the effect of hot calendering process on the microstructure and properties of poly(p-phenylene terephthalamide)(PPTA) paper-based materials was investigated.The microstructures of the fracture surface,crystalline structure,and single fiber strength of the PPTA paperbased materials as well as the different bonding behaviors between the PPTA fibers and PPTA fibrids obtained before and after the hot calendering process were examined.The results indicated that a high linear pressure would result in a limited improvement of the strength owing to the unimproved paper structure.The optimal values of tensile index and dielectric strength of 56.6 N·m/g and 27.6 kV/mm,respectively,could only be achieved with a synergistic effects of hot calendering temperature and linear pressure(240℃ and 110 k N/m,respectively).This result suggested it was possible to achieve a significant reinforcement and improvement in the interfacial bonding of functional PPTA paper-based materials,and avoid the formation of unexpected pleats and cracks in PPTA paper-based materials during the hot calendering process.

Effects of calendering state on coupled electrochemical-mechanical performance of silicon based composite electrodes

The super volume changes and severe mechanical degradation have been a hindrance in the wide application of silicon based composite electrodes in commercial lithium-ion batteries(LIBs).Calendering,one procedure in producing LIBs'electrodes,is indispensable to ensure low porosity and energy density.However,the repercussions of the calendering process on the physical characteristics related to the behavior of silicon(Si)based electrodes during the electrochemical reaction have not been well understood.Thus,on account of the deformation characteristic of cantilever electrodes,an in-situ technique is employed to analyze the repercussions of calendering status on the coupled electro-chemo-mechanical performances.During the electrochemical cycling,Young's modulus and diffusion-induced stress in composite electrodes are quantified.The results show that the swelling strain,the stress and the modulus of the Si-based electrode and the calendering degree are positively correlated.Meanwhile,the stress induced by diffusion in the active layer tends to increase in the stage of lithiation and reverses during the delithiation process.Accompany with the SEM analysis,we conclude that the calendering process can induce larger stress,driving the formation of cracks in electrodes.These findings can help understand how the calendering process could affect the capacity dissipating and lifetime of Si based electrodes.

Simulation of the plasticizing behavior of composite modified doublebase(CMDB)propellant in grooved calendar based on adaptive grid technology

The frequent occurrence of safety accidents during the calendering process is caused by the flammable and explosive properties of composite modified double-base(CMDB)propellant.Optimization of process parameters with the aid of fluid simulation technology could effectively ensure the safety of the calendering process.To improve the accuracy of the simulation results,material parameters and model structure were corrected based on actual conditions,and adaptive grid technology was applied in the local mesh refinement.In addition,the rheological behavior,motion trajectories and heat transfer mechanisms of CMDB propellant slurry were studied with different gaps,rotational rates and temperatures of two rollers.The results indicated that the refined mesh could significantly improve the contour clarity of boundaries and simulate the characteristics of CMDB propellant slurry reflux movement caused by the convergent flow near the outlet.Compared with the gap,the increased rotational rate of roller could promote the reflux movement and intensify the shear flow of slurry inside the flow region by viscous shear dragging.Meanwhile,under the synergistic effect of contact heat transfer as well as convective heat exchange,heat accumulated near the outlet and diffused along the reflux movement,which led to the countercurrent heat dissipation behavior of CMDB propellant slurry.The plasticizing mechanism of slurry and the safety of calendering under different conditions were explored,which provided theoretical guidance and reference data for the optimization of calendering process conditions.Based on the simulation results,the safety of the CMDB propellant calendering process could be significantly improved with a few tests conducted during a short research and development cycle.

Engineering and Optimization of Silicon–Iron–Manganese Nanoalloy Electrode for Enhanced Lithium-Ion Battery

The electrochemical performance of a battery is considered to be primarily dependent on the electrode material. However, engineering and optimization of electrodes also play a crucial role, and the same electrode material can be designed to offer significantly improved batteries. In this work, Si–Fe–Mn nanomaterial alloy(Si/alloy) and graphite composite electrodes were densified at different calendering conditions of 3, 5, and 8 tons, and its influence on electrode porosity, electrolyte wettability, and long-term cycling was investigated. The active material loading was maintained very high(~2 mg cm^(-2)) to implement electrode engineering close to commercial loading scales. The densification was optimized to balance between the electrode thickness and wettability to enable the best electrochemical properties of the Si/alloy anodes.In this case, engineering and optimizing the Si/alloy composite electrodes to 3 ton calendering(electrode densification from 0.39 to 0.48 g cm^(-3)) showed enhanced cycling stability with a high capacity retention of ~100% over 100 cycles.

维美德最新研究成果和解决方案

新维美德自2014年成立至今,更加强化新技术研发,以其创新优势持续保持竞争力。本文介绍了维美德近期最新的、已验证的研究成果和解决方案,涵盖了从备浆系统到卷取设备的整条生产线。

Improving the Surface Performance of Electrospun Air Filter Paper Using Multi-walled Carbon Nanotubes

In this study,air filter base paper(P)was used as the receiving substrate,polyvinyl alcohol(PVA)and PVA/multi-walled carbon nanotube(MWCNT)spinning solutions were used to prepare electrospun air filter papers(P-PVA and P-PVA/MWCNT,respectively).Then,P-PVA/MWCNT was calendered under different pressures.The effect of MWCNTs on the surface performance of P-PVA/MWCNT was explored and the influence of calendering technology on their structure and filtration characteristics was analyzed.Electron scanning microscope observation showed that the PVA nanofibers on the surface of P-PVA/MWCNT had no beading,and MWCNTs weakened the surface electrostatic phenomenon and had a good micromorphology.During the calendering process,with an increase in pressure,the mean pore size and surface roughness of P-PVA/MWCNT decreased,the initial resistance increased,and the filtration efficiency changed slightly.

Advanced electrode processing of lithium ion batteries:A review of powder technology in battery fabrication

Lithium ion batteries have achieved extensive applications in portable electronics and recently in electronic vehicles since its commercialization in 1990s.The vast applications of lithium ion batteries are not only derived from the innovation in electrochemistry based on emerging energy materials and chemical engineering science,but also the technological advances in the powder technologies for electrode processing and cell fabrication.Revealing the effects of powder technology on electrode microstructure evolution during electrode processing is with critical value to realize the superior electrochemical performance.This review presents the progress in understanding the basic principles of the materials processing technologies for electrodes in lithium ion batteries.The impacts of slurry mixing and coating,electrode drying,and calendering on the electrode characteristics and electrochemical performance are comprehensively analyzed.Conclusion and outlook are drawn to shed fresh lights on the further development of efficient lithium ion batteries by advancing powder technologies and related advanced energy materials.