In recent years,more and more efforts are devoting to clean energy,renewable energies in particular to achieving net zero carbon dioxide emissions[1].However,renewable energies,like solar power and wind power,are gene...In recent years,more and more efforts are devoting to clean energy,renewable energies in particular to achieving net zero carbon dioxide emissions[1].However,renewable energies,like solar power and wind power,are generally intermittent and random,hindering their wide application[2,3].To address this problem,there is an urgent need in effective and reliable energy storage device.展开更多
1-(β-Hydroxyalkyl)-l,3,4-oxadiazole derivatives were synthesized via reductive addition reactions of 2-chloromethyl-l,3,4-oxadiazole with carbonyl compounds under mild conditions promoted by SmI2.
Al2O3 - SiC - C castables with pelletized graphite addition of 0. 2%, 4% or 6% (by mass, the same hereinafter ) were prepared using brown fused corundum (8 - 5, 5 - 3 and 3 - 1 mm ) , dense fused corundum ( ≤1 a...Al2O3 - SiC - C castables with pelletized graphite addition of 0. 2%, 4% or 6% (by mass, the same hereinafter ) were prepared using brown fused corundum (8 - 5, 5 - 3 and 3 - 1 mm ) , dense fused corundum ( ≤1 and 0. 045 mm) and SiC ( ≤1 and ≤0. 064 mm) its main starting materials with mass ratio of aggregate: matrix = 71: 29, 2% silicon powder and 0. 4% B4C as antioxidants, and pelletized graphite as carbon source, Effect of pelletized graphite addition on physical properties, oxidation resistance, slag resistance arid thermal shock resistance of Al2O3 -SiC- C eastables was researched. The results show that: with the in.crease of pelletized graphite addition, the required water amount of castables increases, the bulk density and strength reduce; with 4% pelletized graphite, the eastable performs the best oxidation resistance; the increase of graphite is beneficial to the improvement of slag penetration resistance and corrosion resistance; with 6% pelletized graphite, the thermal shock resistance is the best.展开更多
Five lightweight castables containing different TiO2 additions were prepared by using porous corundum - spinel ( MgAl2O4 ) ceramics as aggregate. Corrosion of the lightweight cstables by ladle slag was conducted u...Five lightweight castables containing different TiO2 additions were prepared by using porous corundum - spinel ( MgAl2O4 ) ceramics as aggregate. Corrosion of the lightweight cstables by ladle slag was conducted using a static crucible test. The effect of the TiO2 addition on the slag resistances of the lightweight corundum -spinel castables was investigated through SEM, EDS and Fact- Sage@ software, etc. h was found that TiO2 additi,ve t,vmoted the sintering degree of the castables, deereased the average pore .size, the apparent porosity, and the contact area between the casmbles and slag, and then en- hanced the corrosion resistance. However, TiO2 additive decreased the viscosity of the penetrated .slag simultane- ously, and then deteriorated the penetration resistance.展开更多
The influences of additives of NH_3,HCl,KOH and CH_3OH on the solvothermal synthesis of the Zn-based metal-organic frameworks(Zn-MOF_5s)were investigated.Powder X-ray diffraction(PXRD),thermal gravimetric analysis(TGA...The influences of additives of NH_3,HCl,KOH and CH_3OH on the solvothermal synthesis of the Zn-based metal-organic frameworks(Zn-MOF_5s)were investigated.Powder X-ray diffraction(PXRD),thermal gravimetric analysis(TGA),Fourier translation infrared spectroscope(FT-IR),N_2adsorption/desorption at 77 K and CO_2sorption measurements were used to characterize the as-prepared Zn-MOF_5s.The experimental results showthat additives of NH_3,CH_3OH,HCl and KOH in the synthesis of the Zn-MOF_5s do not change the underlying topology,but they are extremely sensitive to the pore textural properties,thus changing the CO_2adsorption capacity.Additives would lower the pore width and the surface area,and then lower the CO_2adsorption capacity of Zn-MOF_5s.展开更多
The melting temperature and critical transition temperature Tc of YBa2Cu3O7-δ with deferent content additives of PbO and BaPbO3 were studied. When PbO was doped in YBa2Cu3O7-δ, the melting temperature of YBa2Cu3O7-...The melting temperature and critical transition temperature Tc of YBa2Cu3O7-δ with deferent content additives of PbO and BaPbO3 were studied. When PbO was doped in YBa2Cu3O7-δ, the melting temperature of YBa2Cu3O7-δ was reduced, however its superconductivity was weakened. From the XRD pattern of the sintered mixture of YBa2Cu3O7-δ and PbO, it was known that there was a reaction between YBa2Cu3O7-δ and PbO, and the product was BaPbO3. Hence different contents of BaPbO3 (10mass%, 20mass% and 30mass%) were added in YBa2Cu3O7-δ. It was proved that there were no reactions between YBa2Cu3O7-δ and BaPbO3. And the superconductivity of the mixtures was much better than that of the samples with PbO additive.展开更多
A growing demand for passenger and freight transportation, combined with limited capital to expand the United States (U.S.) rail infrastructure, is creating pressure for a more efficient use of the current line capa...A growing demand for passenger and freight transportation, combined with limited capital to expand the United States (U.S.) rail infrastructure, is creating pressure for a more efficient use of the current line capacity. This is further exacerbated by the fact that most passenger rail services operate on corridors that are shared with freight traffic. A capacity analysis is one alternative to address the situation and there are various approaches, tools, and methodologies available for application. As the U.S. continues to develop higher speed passenger services with similar characteristics to those in European shared-use lines, understanding the common methods and tools used on both continents grows in relevance. There has not as yet been a detailed investigation as to how each continent approaches capacity analysis, and whether any benefits could be gained from cross-pollination. This paper utilizes more than 50 past capacity studies from the U.S. and Europe to describe the different railroad capacity defini- tions and approaches, and then categorizes them, based on each approach. The capacity methods are commonly di- vided into analytical and simulation methods, but this paper also introduces a third, "combined simulation- analytical" category. The paper concludes that Europeanrail studies are more unified in terms of capacity, concepts, and techniques, while the U.S. studies represent a greater variation in methods, tools, and objectives. The majority of studies on both continents use either simulation or a combined simulation-analytical approach. However, due to the significant differences between operating philosophy and network characteristics of these two rail systems, European studies tend to use timetable-based simulation tools as opposed to the non-timetable-based tools commonly used in the U.S. rail networks. It was also found that validation of studies against actual operations was not typically completed or was limited to comparisons with a base model.展开更多
Chloro-propylene sulfite (CIPS) was employed as electrolyte additive of Li/S batteries for the first time. Linear potential sweep test showed that the CIPS keeps high electrochemical stability even under the voltage...Chloro-propylene sulfite (CIPS) was employed as electrolyte additive of Li/S batteries for the first time. Linear potential sweep test showed that the CIPS keeps high electrochemical stability even under the voltage of 5.0V. Being used as electrolyte additive in Li/S batteries, CIPS displayed an excellent property for self-discharge prohibition. With CIPS additive the Li/S cells initial discharge capacity was 856.2 mAh·g^-1 and 830.8 mAh·g^-1 at the current density of 15 mA.g and 30 mA·g^-1 , after 30 cycles the discharge capacities were contained at as high as 753.8 mAh.g and 715.6 mAh·g^-1. By means of infrared spectra, TG/DTA experiment and element conten analysis the speculated reason of CIPS's novel function as additive was proposed.展开更多
The microstructure of Ti-6-4 components produced by additive manufacturing suffers from the coarse and elongated prior-β grain,which leads to a decrease of the tensile behavior and the occurrence of anisotropy.To und...The microstructure of Ti-6-4 components produced by additive manufacturing suffers from the coarse and elongated prior-β grain,which leads to a decrease of the tensile behavior and the occurrence of anisotropy.To understand and control the grain evolution,a multiscale simulation is applied to investigate the relationship between the grain selection,growth orientation,and the molten pool morphology with the different deposition layer numbers and processing parameters.The accuracy of the simulation is validated by experiments in both qualitative and quantitative ways.Results show that when the grain with unfavorable orientation loses the competitive growth with its neighbors,there will be a great chance that the blocked grain is eliminated in the following layer-and-layer deposition,which leads to the increase of the grain width.The size of the molten pool increases remarkably as the layer number increases,which lays a heavy burden on the stability of the molten pool.The analytical relationship between the molten pool morphology and the grain growth orientation is also deduced.The flat molten pool causes the grains with the <001> direction close to the building direction to have greater survival potential.Besides,decreasing the line power energy shows little effect on the stability of the molten pool and the grain growth orientation,especially when the deposited layer number is large.The revealing mechanisms will help in understanding and further controlling the grain evolution.展开更多
The heat capacities of 3-( 2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylic acid (a racemic mixture, molar ratio of cis-/trans-structure is 35/65) in a temperature range from 78 to 389 K were measured with ...The heat capacities of 3-( 2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylic acid (a racemic mixture, molar ratio of cis-/trans-structure is 35/65) in a temperature range from 78 to 389 K were measured with a precise automatic adiabatic calorimeter. The sample was prepared with a purity of 98.75% ( molar fraction). A solid-liquid fusion phase transition was observed in the experimental temperature range. The melting point, Tm, enthalpy and en- tropy of fusion, △fusHm, △fusSm, of the acid were determined to be (331.48±0.03 ) K, (16.321±0.031) kJ/mol, and (49.24±0.19) J/( K·mol), respectively. The thermodynamic functions of the sample, Ht-H298.15, Sr-S298.15 and Gr-G298.15, were reported at a temperature intervals of 5 K. The thermal decomposition of the sample was studied using thermogravimetric(TG) analytic technique, the thermal decomposition starts at ca. 418 K and ends at ca. 544 K, the maximum decomposition rate was obtained at 510 K. The order of reaction, preexponential factor and activation energy are n =0.23, A =7.3 ×10^7 min^-1 , E =70.64 kJ/mol, respectively.展开更多
This paper reports that low-temperature heat capacities of 4-(2-aminoethyl)-phenol (C8H11NO) are measured by a precision automated adiabatic calorimeter over the temperature range from 78 to 400 K. A polynomial eq...This paper reports that low-temperature heat capacities of 4-(2-aminoethyl)-phenol (C8H11NO) are measured by a precision automated adiabatic calorimeter over the temperature range from 78 to 400 K. A polynomial equation of heat capacities as a function of the temperature was fitted by the least square method. Based on the fitted polynomial, the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15K were calculated and tabulated at the interval of 5K. The energy equivalent, εcalor, of the oxygen-bomb combustion calorimeter has been determined from 0.68g of NIST 39i benzoic acid to be εcalor=(14674.69±17.49)J·K^-1. The constant-volume energy of combustion of the compound at T=298.15 K was measured by a precision oxygen-bomb combustion calorimeter to be ΔcU=-(32374.25±12.93)J·g^-1. The standard molar enthalpy of combustion for the compound was calculated to be ΔcHm = -(4445.47 ± 1.77) kJ·mol^-1 according to the definition of enthalpy of combustion and other thermodynamic principles. Finally, the standard molar enthalpy of formation of the compound was derived to be ΔfHm(C8H11NO, s)=-(274.68 ±2.06) kJ·mol^-1, in accordance with Hess law.展开更多
The molar heat capacities of La2Mo209 and La1.9Sr0.1MO209-δ were obtained using the differential scanning calorimetry (DSC) technique in a temperature range from 298 to 1473 K. The DSC curve of La2Mo209 showed an e...The molar heat capacities of La2Mo209 and La1.9Sr0.1MO209-δ were obtained using the differential scanning calorimetry (DSC) technique in a temperature range from 298 to 1473 K. The DSC curve of La2Mo209 showed an endothermal peak around 834 K corresponding to a first-order monoclinic-cubic phase transition, and the enthalpy change accompanying this phase transition is 5.99 kJ/mol. No evident endothermal peak existed in the DSC curve of La1.9Sr0.1MO209-δ, but a broad thermal anomaly existed in its heat capacity curve at around 832 K. In addition, the heat capacity values of La2Mo209 and La1.9Sr0.1MO209-δ began to decrease at 1196 and 1330 K, respectively. The non-transitional heat capacity values of La2Mo209 and La1.9Sr0.1MO209-δ were formulated using multiple regression analysis in two temperature ranges.展开更多
为揭示外加电解质离子强度对重金属离子吸附的影响规律与内在机制,制备了膨润土/木质素磺酸钠接枝丙烯酰胺-马来酸酐复合吸附树脂(BLPAMA),研究了外加电解质离子强度对BLPAMA吸附单一和二元Pb2+/Cu2+的影响规律,以及有、无外加0.2 mol/L...为揭示外加电解质离子强度对重金属离子吸附的影响规律与内在机制,制备了膨润土/木质素磺酸钠接枝丙烯酰胺-马来酸酐复合吸附树脂(BLPAMA),研究了外加电解质离子强度对BLPAMA吸附单一和二元Pb2+/Cu2+的影响规律,以及有、无外加0.2 mol/L Na NO3时BLPAMA对二元Pb2+/Cu2+的吸附等温线、吸附热力学及吸附动力学。结果表明,在单一Pb2+或Cu2+溶液中,随离子强度增加,Pb2+和Cu2+吸附量降低;在二元Pb2+/Cu2+溶液中,随离子强度增加,Pb2+吸附量降低而Cu2+吸附量提高。展开更多
基金financially supported by the National Natural Science Foundation of China(Grant No.21935003 and 21908217)DICP I201928+1 种基金the China Postdoctoral Science Foundation(No.2019M651158)the CAS Engineering Laboratory for Electrochemical Energy Storage。
文摘In recent years,more and more efforts are devoting to clean energy,renewable energies in particular to achieving net zero carbon dioxide emissions[1].However,renewable energies,like solar power and wind power,are generally intermittent and random,hindering their wide application[2,3].To address this problem,there is an urgent need in effective and reliable energy storage device.
基金the National Natural Science Foundation of China(Project No.20072033)the NSF of Zhejiang Province for financial support.
文摘1-(β-Hydroxyalkyl)-l,3,4-oxadiazole derivatives were synthesized via reductive addition reactions of 2-chloromethyl-l,3,4-oxadiazole with carbonyl compounds under mild conditions promoted by SmI2.
文摘Al2O3 - SiC - C castables with pelletized graphite addition of 0. 2%, 4% or 6% (by mass, the same hereinafter ) were prepared using brown fused corundum (8 - 5, 5 - 3 and 3 - 1 mm ) , dense fused corundum ( ≤1 and 0. 045 mm) and SiC ( ≤1 and ≤0. 064 mm) its main starting materials with mass ratio of aggregate: matrix = 71: 29, 2% silicon powder and 0. 4% B4C as antioxidants, and pelletized graphite as carbon source, Effect of pelletized graphite addition on physical properties, oxidation resistance, slag resistance arid thermal shock resistance of Al2O3 -SiC- C eastables was researched. The results show that: with the in.crease of pelletized graphite addition, the required water amount of castables increases, the bulk density and strength reduce; with 4% pelletized graphite, the eastable performs the best oxidation resistance; the increase of graphite is beneficial to the improvement of slag penetration resistance and corrosion resistance; with 6% pelletized graphite, the thermal shock resistance is the best.
基金The National Natural Science Foundation of China(Grant No.51302201)
文摘Five lightweight castables containing different TiO2 additions were prepared by using porous corundum - spinel ( MgAl2O4 ) ceramics as aggregate. Corrosion of the lightweight cstables by ladle slag was conducted using a static crucible test. The effect of the TiO2 addition on the slag resistances of the lightweight corundum -spinel castables was investigated through SEM, EDS and Fact- Sage@ software, etc. h was found that TiO2 additi,ve t,vmoted the sintering degree of the castables, deereased the average pore .size, the apparent porosity, and the contact area between the casmbles and slag, and then en- hanced the corrosion resistance. However, TiO2 additive decreased the viscosity of the penetrated .slag simultane- ously, and then deteriorated the penetration resistance.
基金Fujian Province Natural Science Foundation of China(No.2017J01673)
文摘The influences of additives of NH_3,HCl,KOH and CH_3OH on the solvothermal synthesis of the Zn-based metal-organic frameworks(Zn-MOF_5s)were investigated.Powder X-ray diffraction(PXRD),thermal gravimetric analysis(TGA),Fourier translation infrared spectroscope(FT-IR),N_2adsorption/desorption at 77 K and CO_2sorption measurements were used to characterize the as-prepared Zn-MOF_5s.The experimental results showthat additives of NH_3,CH_3OH,HCl and KOH in the synthesis of the Zn-MOF_5s do not change the underlying topology,but they are extremely sensitive to the pore textural properties,thus changing the CO_2adsorption capacity.Additives would lower the pore width and the surface area,and then lower the CO_2adsorption capacity of Zn-MOF_5s.
文摘The melting temperature and critical transition temperature Tc of YBa2Cu3O7-δ with deferent content additives of PbO and BaPbO3 were studied. When PbO was doped in YBa2Cu3O7-δ, the melting temperature of YBa2Cu3O7-δ was reduced, however its superconductivity was weakened. From the XRD pattern of the sintered mixture of YBa2Cu3O7-δ and PbO, it was known that there was a reaction between YBa2Cu3O7-δ and PbO, and the product was BaPbO3. Hence different contents of BaPbO3 (10mass%, 20mass% and 30mass%) were added in YBa2Cu3O7-δ. It was proved that there were no reactions between YBa2Cu3O7-δ and BaPbO3. And the superconductivity of the mixtures was much better than that of the samples with PbO additive.
文摘A growing demand for passenger and freight transportation, combined with limited capital to expand the United States (U.S.) rail infrastructure, is creating pressure for a more efficient use of the current line capacity. This is further exacerbated by the fact that most passenger rail services operate on corridors that are shared with freight traffic. A capacity analysis is one alternative to address the situation and there are various approaches, tools, and methodologies available for application. As the U.S. continues to develop higher speed passenger services with similar characteristics to those in European shared-use lines, understanding the common methods and tools used on both continents grows in relevance. There has not as yet been a detailed investigation as to how each continent approaches capacity analysis, and whether any benefits could be gained from cross-pollination. This paper utilizes more than 50 past capacity studies from the U.S. and Europe to describe the different railroad capacity defini- tions and approaches, and then categorizes them, based on each approach. The capacity methods are commonly di- vided into analytical and simulation methods, but this paper also introduces a third, "combined simulation- analytical" category. The paper concludes that Europeanrail studies are more unified in terms of capacity, concepts, and techniques, while the U.S. studies represent a greater variation in methods, tools, and objectives. The majority of studies on both continents use either simulation or a combined simulation-analytical approach. However, due to the significant differences between operating philosophy and network characteristics of these two rail systems, European studies tend to use timetable-based simulation tools as opposed to the non-timetable-based tools commonly used in the U.S. rail networks. It was also found that validation of studies against actual operations was not typically completed or was limited to comparisons with a base model.
文摘Chloro-propylene sulfite (CIPS) was employed as electrolyte additive of Li/S batteries for the first time. Linear potential sweep test showed that the CIPS keeps high electrochemical stability even under the voltage of 5.0V. Being used as electrolyte additive in Li/S batteries, CIPS displayed an excellent property for self-discharge prohibition. With CIPS additive the Li/S cells initial discharge capacity was 856.2 mAh·g^-1 and 830.8 mAh·g^-1 at the current density of 15 mA.g and 30 mA·g^-1 , after 30 cycles the discharge capacities were contained at as high as 753.8 mAh.g and 715.6 mAh·g^-1. By means of infrared spectra, TG/DTA experiment and element conten analysis the speculated reason of CIPS's novel function as additive was proposed.
基金supported by the National Key Research and Development Program of China (No. 2017YFB1103700)the National Natural Science Foundation of China (No. 51575304 and No. 51674153)。
文摘The microstructure of Ti-6-4 components produced by additive manufacturing suffers from the coarse and elongated prior-β grain,which leads to a decrease of the tensile behavior and the occurrence of anisotropy.To understand and control the grain evolution,a multiscale simulation is applied to investigate the relationship between the grain selection,growth orientation,and the molten pool morphology with the different deposition layer numbers and processing parameters.The accuracy of the simulation is validated by experiments in both qualitative and quantitative ways.Results show that when the grain with unfavorable orientation loses the competitive growth with its neighbors,there will be a great chance that the blocked grain is eliminated in the following layer-and-layer deposition,which leads to the increase of the grain width.The size of the molten pool increases remarkably as the layer number increases,which lays a heavy burden on the stability of the molten pool.The analytical relationship between the molten pool morphology and the grain growth orientation is also deduced.The flat molten pool causes the grains with the <001> direction close to the building direction to have greater survival potential.Besides,decreasing the line power energy shows little effect on the stability of the molten pool and the grain growth orientation,especially when the deposited layer number is large.The revealing mechanisms will help in understanding and further controlling the grain evolution.
基金Supported by the Education Bureau Science Foundation of Liaoning Province,China(No.20040261).
文摘The heat capacities of 3-( 2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylic acid (a racemic mixture, molar ratio of cis-/trans-structure is 35/65) in a temperature range from 78 to 389 K were measured with a precise automatic adiabatic calorimeter. The sample was prepared with a purity of 98.75% ( molar fraction). A solid-liquid fusion phase transition was observed in the experimental temperature range. The melting point, Tm, enthalpy and en- tropy of fusion, △fusHm, △fusSm, of the acid were determined to be (331.48±0.03 ) K, (16.321±0.031) kJ/mol, and (49.24±0.19) J/( K·mol), respectively. The thermodynamic functions of the sample, Ht-H298.15, Sr-S298.15 and Gr-G298.15, were reported at a temperature intervals of 5 K. The thermal decomposition of the sample was studied using thermogravimetric(TG) analytic technique, the thermal decomposition starts at ca. 418 K and ends at ca. 544 K, the maximum decomposition rate was obtained at 510 K. The order of reaction, preexponential factor and activation energy are n =0.23, A =7.3 ×10^7 min^-1 , E =70.64 kJ/mol, respectively.
基金supported by the National Natural Science Foundation of China (Grant No 20673050)
文摘This paper reports that low-temperature heat capacities of 4-(2-aminoethyl)-phenol (C8H11NO) are measured by a precision automated adiabatic calorimeter over the temperature range from 78 to 400 K. A polynomial equation of heat capacities as a function of the temperature was fitted by the least square method. Based on the fitted polynomial, the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15K were calculated and tabulated at the interval of 5K. The energy equivalent, εcalor, of the oxygen-bomb combustion calorimeter has been determined from 0.68g of NIST 39i benzoic acid to be εcalor=(14674.69±17.49)J·K^-1. The constant-volume energy of combustion of the compound at T=298.15 K was measured by a precision oxygen-bomb combustion calorimeter to be ΔcU=-(32374.25±12.93)J·g^-1. The standard molar enthalpy of combustion for the compound was calculated to be ΔcHm = -(4445.47 ± 1.77) kJ·mol^-1 according to the definition of enthalpy of combustion and other thermodynamic principles. Finally, the standard molar enthalpy of formation of the compound was derived to be ΔfHm(C8H11NO, s)=-(274.68 ±2.06) kJ·mol^-1, in accordance with Hess law.
基金This work was financially supported by the National Natural Science Foundation of China (No.50604002).
文摘The molar heat capacities of La2Mo209 and La1.9Sr0.1MO209-δ were obtained using the differential scanning calorimetry (DSC) technique in a temperature range from 298 to 1473 K. The DSC curve of La2Mo209 showed an endothermal peak around 834 K corresponding to a first-order monoclinic-cubic phase transition, and the enthalpy change accompanying this phase transition is 5.99 kJ/mol. No evident endothermal peak existed in the DSC curve of La1.9Sr0.1MO209-δ, but a broad thermal anomaly existed in its heat capacity curve at around 832 K. In addition, the heat capacity values of La2Mo209 and La1.9Sr0.1MO209-δ began to decrease at 1196 and 1330 K, respectively. The non-transitional heat capacity values of La2Mo209 and La1.9Sr0.1MO209-δ were formulated using multiple regression analysis in two temperature ranges.
文摘为揭示外加电解质离子强度对重金属离子吸附的影响规律与内在机制,制备了膨润土/木质素磺酸钠接枝丙烯酰胺-马来酸酐复合吸附树脂(BLPAMA),研究了外加电解质离子强度对BLPAMA吸附单一和二元Pb2+/Cu2+的影响规律,以及有、无外加0.2 mol/L Na NO3时BLPAMA对二元Pb2+/Cu2+的吸附等温线、吸附热力学及吸附动力学。结果表明,在单一Pb2+或Cu2+溶液中,随离子强度增加,Pb2+和Cu2+吸附量降低;在二元Pb2+/Cu2+溶液中,随离子强度增加,Pb2+吸附量降低而Cu2+吸附量提高。