Advances in Capillary Chromatography

Capillary columns are used in both capillary liquid chromatography and capillary electrochromatography. The design for capillary liquid chromatography is discussed in comparison with capillary gas chromatography. The difference of diffusion coefficient in gas and liquid phase is a key role. The study for obtaining a high performance capillary liquid chromatography is discussed. Capillary electrochromatography is recently interesting for its instinct ability to realize a high performance chromatography. Capillary electrochromatography with and without pressurized flow is reviewed briefly. Instrumentation for capillary electrochromatography with pressurized flow is discussed. The port of splitting, and gradient elution of both solution and potential are described. The new findings of both the variation of column resistance and capacity factor according to the value of applied electric voltage are also discussed.

致密油藏微量气气水交替注入参数的设计方法

致密油藏中孔喉狭小,且非均质性很强,油水两相间形成较高的毛管阻力,水驱过程中水相将首先突破毛管压力较小的大孔道。随着大孔道的连续性被突破,一个水窜通道将逐渐形成,之后注入的水将沿着水窜通道流动而失去驱油作用,若储层中存在微裂缝该现象更明显。研究致密油藏储层孔隙结构及水驱过程可能的毛管压力分布,针对气水交替中油气水毛管压力压降特征,提出了注入微量气段塞及大量水段塞调堵致密油藏天然裂缝及较大孔隙的气水交替法,设计了一种新的微量气注入实验,并且从注入强度、注入周期和注入次数3个方面进行优化,预测采收率的变化。研究表明,采用微量气气水交替法对致密油藏水驱水窜后提高开发效果是有效的。

毛细管电色谱中进样时间对柱效的影响

毛细管电色谱是近年发展起来的一种新型微分离技术 ,它结合了高效液相色谱和毛细管电泳的特点 ,具有高效、快速、高选择性。其有关理论研究和应用越来越深入。