In this contribution, the template assisted synthesis of porous carbons by chemical vapor deposition in porous concrete templates has been described for the first time. Porous concrete made templates can be obtained i...In this contribution, the template assisted synthesis of porous carbons by chemical vapor deposition in porous concrete templates has been described for the first time. Porous concrete made templates can be obtained in almost any geometrical shape and are therefore attractive templates to prepare porous carbon monoliths. The carbon deposition process in porous concrete follows a three-stage-course consisting in an initial period, a period of fast carbon deposition and a period of slow carbon deposition. The carbon growth within the template pores occurs obviously plug-like from the inner to the outer sphere. Any continuous covering of the template pore walls by carbon could not be observed. In difference to porous concrete, the carbon deposition in silica gel is strongly accompanied by mass transfer limitations. For porous concrete, such strong effect has not been observed obviously due to its hierarchical pore system. The template materials have been loaded with carbon by chemical vapor deposition in a flow reactor. The process of the template pore filling has been characterized by the time dependence of the template mass gain. The materials have been characterized by means of X-ray tomography and nitrogen adsorption at 77 K, respectively.展开更多
As the increasing need of the steels with both high strength and hydrogen embrittlement resistance ability, carbide precipitation and element distribution in high Co-Ni secondary hardening steel were concerned. Carbid...As the increasing need of the steels with both high strength and hydrogen embrittlement resistance ability, carbide precipitation and element distribution in high Co-Ni secondary hardening steel were concerned. Carbide precipitation and element distribution in M54 were observed using carbon replicas method. Both simulation and observation results showed that MC and M2C formed in the steel. MC was round particle, which would act as grain refiners. And MzC was needle-like phase, which would be remarkable strengthening phases. Nb and V were main metallic elements in MC phase. Mo and Cr were main metallic elements in MzC phase. W, Co, and Ni were probably mainly dissolved in the matrix. As the carbide precipitation in AerMetl00 was M2C, which had similar size and shape with M2C in M54, the tensile strength and yield strength of AerMetl00 and M54 were similar. Compared with traditional high Co-Ni secondary hardening steel, M54 had higher hydrogen embrittlement resistance ability, probably because of element W in the matrix.展开更多
To give a further research on strengthening mechanism of binary Fe-Cu alloys dur- ing the aging process, the compositions, size distributions and volume fractions of precipitates were investigated by carbon extraction...To give a further research on strengthening mechanism of binary Fe-Cu alloys dur- ing the aging process, the compositions, size distributions and volume fractions of precipitates were investigated by carbon extraction replicas. Both the size and the volume fraction of precipitates increase with the aging time prolonged. The precip- itate sizes are corresponding with Weibull distribution. The stability of the sample aged for 35 rain is worse than that aged for 1800 min and 18000 min. The precipi- tate is Cu-rich phase in the early aging process, and Cu content increases with the prolonging aging time. Before aging peak, the precipitation of Cu-rich phase plays a dominant role in strengthening. The growth and the change in crystal structure of the precipitate particles are the main factors leading to the decrease in strengthening after the aging peak.展开更多
文摘In this contribution, the template assisted synthesis of porous carbons by chemical vapor deposition in porous concrete templates has been described for the first time. Porous concrete made templates can be obtained in almost any geometrical shape and are therefore attractive templates to prepare porous carbon monoliths. The carbon deposition process in porous concrete follows a three-stage-course consisting in an initial period, a period of fast carbon deposition and a period of slow carbon deposition. The carbon growth within the template pores occurs obviously plug-like from the inner to the outer sphere. Any continuous covering of the template pore walls by carbon could not be observed. In difference to porous concrete, the carbon deposition in silica gel is strongly accompanied by mass transfer limitations. For porous concrete, such strong effect has not been observed obviously due to its hierarchical pore system. The template materials have been loaded with carbon by chemical vapor deposition in a flow reactor. The process of the template pore filling has been characterized by the time dependence of the template mass gain. The materials have been characterized by means of X-ray tomography and nitrogen adsorption at 77 K, respectively.
基金This work was financially supported by National Basic Research Programs of China （No. 2015CB654802）. The authors greatly acknowledge the financial support provided by the National Natural Science Foundation of China （Grant No. 51471094） and the assistance of Engineers Li-jing Hao and Yang Meng in Shougang Research Institute of Technology with the preparation of carbon replica samples and TEM observation.
文摘As the increasing need of the steels with both high strength and hydrogen embrittlement resistance ability, carbide precipitation and element distribution in high Co-Ni secondary hardening steel were concerned. Carbide precipitation and element distribution in M54 were observed using carbon replicas method. Both simulation and observation results showed that MC and M2C formed in the steel. MC was round particle, which would act as grain refiners. And MzC was needle-like phase, which would be remarkable strengthening phases. Nb and V were main metallic elements in MC phase. Mo and Cr were main metallic elements in MzC phase. W, Co, and Ni were probably mainly dissolved in the matrix. As the carbide precipitation in AerMetl00 was M2C, which had similar size and shape with M2C in M54, the tensile strength and yield strength of AerMetl00 and M54 were similar. Compared with traditional high Co-Ni secondary hardening steel, M54 had higher hydrogen embrittlement resistance ability, probably because of element W in the matrix.
基金supported by the National Natural Science Foundation of China(No. 50671012)
文摘To give a further research on strengthening mechanism of binary Fe-Cu alloys dur- ing the aging process, the compositions, size distributions and volume fractions of precipitates were investigated by carbon extraction replicas. Both the size and the volume fraction of precipitates increase with the aging time prolonged. The precip- itate sizes are corresponding with Weibull distribution. The stability of the sample aged for 35 rain is worse than that aged for 1800 min and 18000 min. The precipi- tate is Cu-rich phase in the early aging process, and Cu content increases with the prolonging aging time. Before aging peak, the precipitation of Cu-rich phase plays a dominant role in strengthening. The growth and the change in crystal structure of the precipitate particles are the main factors leading to the decrease in strengthening after the aging peak.
