In isothermal spheroidizing process,the spheroidization and growth of the carbide formed in hot-deformed high-carbon chromium cast steel at high temperature were investigated.The results showed that the spheroidizing ...In isothermal spheroidizing process,the spheroidization and growth of the carbide formed in hot-deformed high-carbon chromium cast steel at high temperature were investigated.The results showed that the spheroidizing growth of carbide proceeds in such a way that the bigger carbide particles swallow the smaller ones,and the short rhabdoid carbides dissolve and are spheroidized by itself.When the samples were held at 720℃ for more than 3 h,the spheroidization is not obvious.The feature of the process is the size increment and the amount decrement of carbide particles.The empirical equation for growth rate of carbides was obtained.The volume fraction of carbides keeps constant.The growth process agrees well with Ostwald Ripening Law.展开更多
In this study, high chromium white iron (HC-Wi) alloy and the Hadfield steel were studied. The microstructure of this high-chromium iron was studied using Metallurgical optical microscopy (OM) and compared to the Hadf...In this study, high chromium white iron (HC-Wi) alloy and the Hadfield steel were studied. The microstructure of this high-chromium iron was studied using Metallurgical optical microscopy (OM) and compared to the Hadfield steel. The hardness and unnotched charpy impact strength of the HC-Wi alloy and Hadfield steel were examined at ambient temperature in the as-cast and heat-treated conditions. A pin-on-disc test at linear speed of 1.18 m/s and a 10 N normal load was employed to evaluate the wear behavior of both steel samples. Microstructural results showed that varying the carbon level in HC-Wi alloys can affect the chromium carbide morphology and its distribution in the austenite matrix which leads to considerable changes of the mechanical properties. Abrasion test showed that HC-Wi alloys have superior wear resistance, about three times of the Hadfield steel.展开更多
The microstructure and properties of high carbonic-chromium cast steel subjected to different hot deformation ratios were studied.The experimental results show that the microstructure and properties of high carbonic-c...The microstructure and properties of high carbonic-chromium cast steel subjected to different hot deformation ratios were studied.The experimental results show that the microstructure and properties of high carbonic-chromium cast steel are obviously improved after hot deformation,and the best mechanical properties of the cast steel can be obtained under hot deformation ratio of 40 %-50 %,which leads to the morphology change of eutectic carbide and the precipitation of granular carbides.展开更多
The layer structure of low-carbon steel containing RE by high-temperature (T>1200 ℃) carburizing of liquid cast-iron was studied and the diffusion activation energy of carbon was calculated by metallographic micr...The layer structure of low-carbon steel containing RE by high-temperature (T>1200 ℃) carburizing of liquid cast-iron was studied and the diffusion activation energy of carbon was calculated by metallographic microscpe, chemical analysis etc. The result shows that the technology of carburizing in liquid cast-iron can expedite caburization distinctly and changes the carburizing layer structure. The carburizing rate is 60～80 times of that of the traditional technology, and there is about 43% decrease in the activation energy compared with gas-carburization. In outer structure layer, cementite is formed simultaneously both on the crystal boundary reticularly and inside the crystal grains stripedly. In inner carburizing layer, there is undissolved blocky ferrite in reticular cementite. Besides, rare earth element can expedite carburization process.展开更多
In this paper, the carburizing kinetics of low-carbon steel at high-temperature and short-term in liquid cast-iron were studied by metallographic microscope, chemical analysis and so on, and the microstructure of carb...In this paper, the carburizing kinetics of low-carbon steel at high-temperature and short-term in liquid cast-iron were studied by metallographic microscope, chemical analysis and so on, and the microstructure of carburized layer was also analyzed. The results show that the carburizing rate of low-carbon steel at high-temperature and short-term is so fast, and the microstructure of carburized layer possess higher carbon content, and cementite, pearlite and ferrite exist in carburized layer structure simultaneously. Besides, the kinetic equations of permeating layer forming have been presented, and the carburizing mechanism was preliminary discussed also.展开更多
Wear properties of two different crushers used for grinding raw materials of cement industry are compared using pin-on-disk wear test.The wear test was carried out with different loads on a pin.Abrasive wear behavior ...Wear properties of two different crushers used for grinding raw materials of cement industry are compared using pin-on-disk wear test.The wear test was carried out with different loads on a pin.Abrasive wear behavior of two alloys was evaluated by comparing mass loss,wear resistance,microhardness and friction coefficient.The microstructure of the specimens was detected using optical microscope.The results showed that abrasive wear of high chromium cast iron is lower than that of Hadfield steel.Due to the presence of M7C3 carbides on the high chromium cast iron matrix,impact crushers exhibited higher friction coefficient展开更多
High-carbon chromium bearing steels with different rare earth (RE) contents were prepared to investigate the effects of RE on inclusions and impact toughness by different techniques. The results showed that RE additio...High-carbon chromium bearing steels with different rare earth (RE) contents were prepared to investigate the effects of RE on inclusions and impact toughness by different techniques. The results showed that RE addition could modify irregular Al2O3 and MnS into regular RE inclusions. With the increase of RE content, the reaction sequence of RE and potential inclusion forming elements should be O, S, As, P and C successively. RE inclusions containing C might precipitate in molten steel and solid state, but the precipitation tem perature was significantly higher than that of carbides in high-carbon chromium bearing steel. For experim ental bearing steels, the volume fraction of inclusions increased steadily with the increase of RE content, but smaller and more dispersed inclusions could be obtained by 0.018% RE content compared with bearing steel without RE, whereas the continuous increase of RE content led to an increasing trend for inclusion size and a gradual deterioration for inclusion distribution. RE addition could improve the transverse impact toughness and isotropy of bearing steel, and for modified highcarbon chrom ium bearing steel by RE alloying, the increase of RE content continuously increased both transverse and longitudinal im pact toughness until excessive RE addition.展开更多
基金Item Sponsored by Guiding Programme of Science and Technology Research of Hebei of China(94122123)
文摘In isothermal spheroidizing process,the spheroidization and growth of the carbide formed in hot-deformed high-carbon chromium cast steel at high temperature were investigated.The results showed that the spheroidizing growth of carbide proceeds in such a way that the bigger carbide particles swallow the smaller ones,and the short rhabdoid carbides dissolve and are spheroidized by itself.When the samples were held at 720℃ for more than 3 h,the spheroidization is not obvious.The feature of the process is the size increment and the amount decrement of carbide particles.The empirical equation for growth rate of carbides was obtained.The volume fraction of carbides keeps constant.The growth process agrees well with Ostwald Ripening Law.
文摘In this study, high chromium white iron (HC-Wi) alloy and the Hadfield steel were studied. The microstructure of this high-chromium iron was studied using Metallurgical optical microscopy (OM) and compared to the Hadfield steel. The hardness and unnotched charpy impact strength of the HC-Wi alloy and Hadfield steel were examined at ambient temperature in the as-cast and heat-treated conditions. A pin-on-disc test at linear speed of 1.18 m/s and a 10 N normal load was employed to evaluate the wear behavior of both steel samples. Microstructural results showed that varying the carbon level in HC-Wi alloys can affect the chromium carbide morphology and its distribution in the austenite matrix which leads to considerable changes of the mechanical properties. Abrasion test showed that HC-Wi alloys have superior wear resistance, about three times of the Hadfield steel.
基金Item Sponsored by Guiding Program of Science and Technology Research of Hebei Province of China(94122123)
文摘The microstructure and properties of high carbonic-chromium cast steel subjected to different hot deformation ratios were studied.The experimental results show that the microstructure and properties of high carbonic-chromium cast steel are obviously improved after hot deformation,and the best mechanical properties of the cast steel can be obtained under hot deformation ratio of 40 %-50 %,which leads to the morphology change of eutectic carbide and the precipitation of granular carbides.
文摘The layer structure of low-carbon steel containing RE by high-temperature (T>1200 ℃) carburizing of liquid cast-iron was studied and the diffusion activation energy of carbon was calculated by metallographic microscpe, chemical analysis etc. The result shows that the technology of carburizing in liquid cast-iron can expedite caburization distinctly and changes the carburizing layer structure. The carburizing rate is 60～80 times of that of the traditional technology, and there is about 43% decrease in the activation energy compared with gas-carburization. In outer structure layer, cementite is formed simultaneously both on the crystal boundary reticularly and inside the crystal grains stripedly. In inner carburizing layer, there is undissolved blocky ferrite in reticular cementite. Besides, rare earth element can expedite carburization process.
文摘In this paper, the carburizing kinetics of low-carbon steel at high-temperature and short-term in liquid cast-iron were studied by metallographic microscope, chemical analysis and so on, and the microstructure of carburized layer was also analyzed. The results show that the carburizing rate of low-carbon steel at high-temperature and short-term is so fast, and the microstructure of carburized layer possess higher carbon content, and cementite, pearlite and ferrite exist in carburized layer structure simultaneously. Besides, the kinetic equations of permeating layer forming have been presented, and the carburizing mechanism was preliminary discussed also.
文摘Wear properties of two different crushers used for grinding raw materials of cement industry are compared using pin-on-disk wear test.The wear test was carried out with different loads on a pin.Abrasive wear behavior of two alloys was evaluated by comparing mass loss,wear resistance,microhardness and friction coefficient.The microstructure of the specimens was detected using optical microscope.The results showed that abrasive wear of high chromium cast iron is lower than that of Hadfield steel.Due to the presence of M7C3 carbides on the high chromium cast iron matrix,impact crushers exhibited higher friction coefficient
基金financially supported by the National Natural Science Foundation of China (Nos. U1508215 and U1708252)the National Key Research and Development Program (No. 2016YFB0300401)
文摘High-carbon chromium bearing steels with different rare earth (RE) contents were prepared to investigate the effects of RE on inclusions and impact toughness by different techniques. The results showed that RE addition could modify irregular Al2O3 and MnS into regular RE inclusions. With the increase of RE content, the reaction sequence of RE and potential inclusion forming elements should be O, S, As, P and C successively. RE inclusions containing C might precipitate in molten steel and solid state, but the precipitation tem perature was significantly higher than that of carbides in high-carbon chromium bearing steel. For experim ental bearing steels, the volume fraction of inclusions increased steadily with the increase of RE content, but smaller and more dispersed inclusions could be obtained by 0.018% RE content compared with bearing steel without RE, whereas the continuous increase of RE content led to an increasing trend for inclusion size and a gradual deterioration for inclusion distribution. RE addition could improve the transverse impact toughness and isotropy of bearing steel, and for modified highcarbon chrom ium bearing steel by RE alloying, the increase of RE content continuously increased both transverse and longitudinal im pact toughness until excessive RE addition.
