The world’s production of cocoa highly has grown since 1960.In West Africa,the production reached about 3,000,000 tons in 2012.More than 50%of the world’s production of cocoa comes nowadays from Côte d’Ivoire ...The world’s production of cocoa highly has grown since 1960.In West Africa,the production reached about 3,000,000 tons in 2012.More than 50%of the world’s production of cocoa comes nowadays from Côte d’Ivoire and Ghana and Côte d’Ivoire is the biggest producer.After harvesting,the empty shells,considered as non-useful wastes,are abandoned in the fields where they become a source of pollution.That yields millions of tons of biomass that can be converted into charcoal,instead of being sources of pollution.In the present work,the drying kinetics of the empty wet shells were studied.Then,charcoal production by pyrolysis of those empty shells of cocoa pods was performed,using a carbonisation stove fitted with a chimney.The study showed that the empty shells have a high moisture content.The different phases of the drying were observed.The study compared the drying rates and the diffusion coefficients of a small sample and a big sample.Two experiences of carbonisation of the empty shells were successfully carried out.For the first experiment,the pyrolysis temperatures were recorded and the charcoal mass efficiency calculated.For the second experiment,the temperatures were higher and the result was colored charcoals.The colorations disappeared after some hours.展开更多
We report the synthesis, characterisation and catalytic performance of two nature-inspired biomassderived electro-catalysts for the oxygen reduction reaction in fuel cells. The catalysts were prepared via pyrolysis of...We report the synthesis, characterisation and catalytic performance of two nature-inspired biomassderived electro-catalysts for the oxygen reduction reaction in fuel cells. The catalysts were prepared via pyrolysis of a real food waste（lobster shells） or by mimicking the composition of lobster shells using chitin and CaCO3 particles followed by acid washing. The simplified model of artificial lobster was prepared for better reproducibility. The calcium carbonate in both samples acts as a pore agent, creating increased surface area and pore volume, though considerably higher in artificial lobster samples due to the better homogeneity of the components. Various characterisation techniques revealed the presence of a considerable amount of hydroxyapatite left in the real lobster samples after acid washing and a low content of carbon（23%）, nitrogen and sulphur（〈1%）, limiting the surface area to 23 m^2/g, and consequently resulting in rather poor catalytic activity. However, artificial lobster samples, with a surface area of ≈200 m^2/g and a nitrogen doping of 2%, showed a promising onset potential, very similar to a commercially available platinum catalyst, with better methanol tolerance, though with lower stability in long time testing over 10,000 s.展开更多
基金ASCAD(l’Académie des Sciences,des Cultures,des Arts d’Afrique et de ses Diasporas)for its support to his renewable energy program。
文摘The world’s production of cocoa highly has grown since 1960.In West Africa,the production reached about 3,000,000 tons in 2012.More than 50%of the world’s production of cocoa comes nowadays from Côte d’Ivoire and Ghana and Côte d’Ivoire is the biggest producer.After harvesting,the empty shells,considered as non-useful wastes,are abandoned in the fields where they become a source of pollution.That yields millions of tons of biomass that can be converted into charcoal,instead of being sources of pollution.In the present work,the drying kinetics of the empty wet shells were studied.Then,charcoal production by pyrolysis of those empty shells of cocoa pods was performed,using a carbonisation stove fitted with a chimney.The study showed that the empty shells have a high moisture content.The different phases of the drying were observed.The study compared the drying rates and the diffusion coefficients of a small sample and a big sample.Two experiences of carbonisation of the empty shells were successfully carried out.For the first experiment,the pyrolysis temperatures were recorded and the charcoal mass efficiency calculated.For the second experiment,the temperatures were higher and the result was colored charcoals.The colorations disappeared after some hours.
基金the EU for the Intra European Marie Curie Research Fellowship (PIEFGA-2013-623227)
文摘We report the synthesis, characterisation and catalytic performance of two nature-inspired biomassderived electro-catalysts for the oxygen reduction reaction in fuel cells. The catalysts were prepared via pyrolysis of a real food waste（lobster shells） or by mimicking the composition of lobster shells using chitin and CaCO3 particles followed by acid washing. The simplified model of artificial lobster was prepared for better reproducibility. The calcium carbonate in both samples acts as a pore agent, creating increased surface area and pore volume, though considerably higher in artificial lobster samples due to the better homogeneity of the components. Various characterisation techniques revealed the presence of a considerable amount of hydroxyapatite left in the real lobster samples after acid washing and a low content of carbon（23%）, nitrogen and sulphur（〈1%）, limiting the surface area to 23 m^2/g, and consequently resulting in rather poor catalytic activity. However, artificial lobster samples, with a surface area of ≈200 m^2/g and a nitrogen doping of 2%, showed a promising onset potential, very similar to a commercially available platinum catalyst, with better methanol tolerance, though with lower stability in long time testing over 10,000 s.
