Several precursors of organic conductors based on metal-(dmit)2 anion complex withcarbonium as counter cations were first synthesize Some of them exhibit greatly increased conductivities upon iodine doping.
The structure and energy of the carbonium ions formed upon protonation of butane were studied by the DFT methods. Four stable structures are identified for the protonated form of n-butane, the energy increases in the ...The structure and energy of the carbonium ions formed upon protonation of butane were studied by the DFT methods. Four stable structures are identified for the protonated form of n-butane, the energy increases in the following order： C2HC3〈C1HC2〈C2HH〈C1HH, and the stability decreases in the following order C2HC3〉C1HC2〉C2HH〉C1HH. The stability of the penta-coordinated carbonium ions may be explained by the electron distribution in the three-center-two-electron bonds. The delocalization of the penta-coordinated carbonium ion CHC with three-center-two-electron bonds on positive charges was stronger than that of the penta-coordinated earbonium ion CHH with three-center-two-electron bonds and its stability was higher than that of the penta-coordinated carbonium ion CHH with three-center-two-electron bonds.展开更多
The major products of carbonium cyclization of 1 are 2 and 3;2 is unstable and undergoes aerial oxidation to give 4.A similar product(6)from 5 is somehow stabilized by the extra ben- zoyloxy group(or OH)and can be sto...The major products of carbonium cyclization of 1 are 2 and 3;2 is unstable and undergoes aerial oxidation to give 4.A similar product(6)from 5 is somehow stabilized by the extra ben- zoyloxy group(or OH)and can be stored without deterioration.展开更多
Schisandrin(1)under the Ritter reaction conditions (conc.H_2SO_4/CH_3CN)gave trace amounts of the expected acetamido derivatives(2a,2b).The main product is 5a,from intramolecular car- bonium cyclization.
The reaction of schisandrin(1)under Ritter reaction conditions(conc.sulfuric acid/aceto- nitrile)was studied.Besides trace amounts of normal products(7α-and 7β-acetamido derivatives 2a and 2b),the main product was a...The reaction of schisandrin(1)under Ritter reaction conditions(conc.sulfuric acid/aceto- nitrile)was studied.Besides trace amounts of normal products(7α-and 7β-acetamido derivatives 2a and 2b),the main product was a carbonium cyclization compound(3a).展开更多
In order to discuss the role and influence of water during the generation of natural gas,the participation mechanism of water during the evolution of organic matter and its influences were summarized.In addition,we ca...In order to discuss the role and influence of water during the generation of natural gas,the participation mechanism of water during the evolution of organic matter and its influences were summarized.In addition,we carried out an anhydrous cracking experiment of oil extracted from the Feixianguan Formation source rock in a closed system,which led to the establishment of the kinetic models for describing carbon and hydrogen isotopic fractionation during gas generation from organic matter.The models were calibrated and then applied to the northeastern Sichuan Basin.By combining a series of gas generation experiments from octadecane pyrolysis without water or with distilled water in varying mass proportions,several results were proved:(1) the hydrogen isotopic composition of natural gas becomes lighter with the participation of formation water;(2) we can quantitatively study the hydrogen isotopic fractionation with the kinetic model for describing carbon isotopic fractionation; (3) more abundant and reliable geological information can be obtained through the combined application of carbon and hydrogen isotopic indices.展开更多
文摘Several precursors of organic conductors based on metal-(dmit)2 anion complex withcarbonium as counter cations were first synthesize Some of them exhibit greatly increased conductivities upon iodine doping.
文摘The structure and energy of the carbonium ions formed upon protonation of butane were studied by the DFT methods. Four stable structures are identified for the protonated form of n-butane, the energy increases in the following order： C2HC3〈C1HC2〈C2HH〈C1HH, and the stability decreases in the following order C2HC3〉C1HC2〉C2HH〉C1HH. The stability of the penta-coordinated carbonium ions may be explained by the electron distribution in the three-center-two-electron bonds. The delocalization of the penta-coordinated carbonium ion CHC with three-center-two-electron bonds on positive charges was stronger than that of the penta-coordinated earbonium ion CHH with three-center-two-electron bonds and its stability was higher than that of the penta-coordinated carbonium ion CHH with three-center-two-electron bonds.
文摘The major products of carbonium cyclization of 1 are 2 and 3;2 is unstable and undergoes aerial oxidation to give 4.A similar product(6)from 5 is somehow stabilized by the extra ben- zoyloxy group(or OH)and can be stored without deterioration.
文摘Schisandrin(1)under the Ritter reaction conditions (conc.H_2SO_4/CH_3CN)gave trace amounts of the expected acetamido derivatives(2a,2b).The main product is 5a,from intramolecular car- bonium cyclization.
文摘The reaction of schisandrin(1)under Ritter reaction conditions(conc.sulfuric acid/aceto- nitrile)was studied.Besides trace amounts of normal products(7α-and 7β-acetamido derivatives 2a and 2b),the main product was a carbonium cyclization compound(3a).
基金financially aided by the National Natural Science Foundation of China(No.41002044)the Specialized Research Fund for the Doctoral Program of Higher Education of China(No.20102322120003)the Foundation for University Key Teacher of Heilongjiang Province of China(No.1251G003)
文摘In order to discuss the role and influence of water during the generation of natural gas,the participation mechanism of water during the evolution of organic matter and its influences were summarized.In addition,we carried out an anhydrous cracking experiment of oil extracted from the Feixianguan Formation source rock in a closed system,which led to the establishment of the kinetic models for describing carbon and hydrogen isotopic fractionation during gas generation from organic matter.The models were calibrated and then applied to the northeastern Sichuan Basin.By combining a series of gas generation experiments from octadecane pyrolysis without water or with distilled water in varying mass proportions,several results were proved:(1) the hydrogen isotopic composition of natural gas becomes lighter with the participation of formation water;(2) we can quantitatively study the hydrogen isotopic fractionation with the kinetic model for describing carbon isotopic fractionation; (3) more abundant and reliable geological information can be obtained through the combined application of carbon and hydrogen isotopic indices.
