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Determination of Trace Manganese (Ⅱ) by Its Catalytic De-colourizing Reaction On the Aerial Oxidation of 1.5-his (2-hydroxy-5-chlorophenyl)-3-cyanoformazan and Its Kinetic Reaction Mechanism
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作者 Shao Min LIU Jiao Mat PAN (Department of Analytical Chemistry. Hefei Institute of Economics and Teehnology.Hefei 230052.Departmenl of chemistry. Easl China Normal University. Shanghai 200062) 《Chinese Chemical Letters》 SCIE CAS CSCD 1999年第5期403-406,共4页
A kinetie method is described for the determination of trace amounts of mangancsc (Ⅱ)based on its catalylic effect on the aerial oxidation of 1.5-bis (2-hydroxy-5-chlorophenyl)-3-cyanofrmazan. The reaction is followe... A kinetie method is described for the determination of trace amounts of mangancsc (Ⅱ)based on its catalylic effect on the aerial oxidation of 1.5-bis (2-hydroxy-5-chlorophenyl)-3-cyanofrmazan. The reaction is followed spectrophotometrically by measurin the rate of change in absorbance at 580nm. The calibration curve (rate constant vs. manganese concentration) is linearin the range of 10~200ng in 25ml solutions. Kinetic parameters of the reaction are reported. Thereare few Interferences. 展开更多
关键词 catalytic-spectrophotonletry manganese 1.5-bis (2-hydroxy-5-chlorophenyl)-3-cyanofrmazan
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