A series of Cd1-xZnxS/K2La2Ti3O10 composites were synthesized via a simple co-precipitation method. The prepared samples were characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM), X-ray energy di...A series of Cd1-xZnxS/K2La2Ti3O10 composites were synthesized via a simple co-precipitation method. The prepared samples were characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM), X-ray energy dispersive spectroscopy(EDX), ultraviolet-visible diffuse reflection(UV-Vis), X-ray photoelectron spectroscopy(XPS) and photoluminescence(PL) measurements. The composite structures consisted of Cd1-xZnxS nanoparticles evenly distributed on the surface of K2La2Ti3O10. The absorption edge of K2La2Ti3O10 shifted to the visible light region upon introduction of the Cd1-xZnxS nanoparticles. The photocatalytic activities of the catalysts were evaluated by hydrogen production under visible light irradiation. The prepared Cd0.8Zn0.2S(30wt%)/K2La2Ti3O10 exhibited higher photocatalytic activity, evolving 6.92 mmol/g H2 under visible light irradiation for 3 h. The promoted photocatalytic activity of the composites was attributed to the synergistic effect between Cd1-xZnxS and K2La2Ti3O10, which resulted in enhanced separation of photogenerated electrons and holes.展开更多
A novel 3D hetero-nuclear framework,namely [K_2Cd_5(Hbptc)_4(H_2O)_(12)·12H_2O]_n(1,H4 bptc = biphenyl-2,3,3?,5?-tetracarboxylic acid),was obtained by hydrothermal reaction. X-ray singlecrystal structur...A novel 3D hetero-nuclear framework,namely [K_2Cd_5(Hbptc)_4(H_2O)_(12)·12H_2O]_n(1,H4 bptc = biphenyl-2,3,3?,5?-tetracarboxylic acid),was obtained by hydrothermal reaction. X-ray singlecrystal structure analysis reveals that polymer 1 crystallizes in orthorhombic,space group Pbcn with a = 26.6152(13),b = 11.7449(5),c = 29.5923(14) ?,V = 9250.3(7) ?~3,C_(64)H_(76)Cd_5K_2O_(56),Mr = 2381.44,Dc = 1.710 g/cm^3,μ(MoK α) = 1.323 mm^(-1),F(000) = 4744,Z = 4,the final R = 0.0668 and wR = 0.1135 for 10613 observed reflections(I 〉 2σ(I)). Polymer 1 displays a 3D network that is built on the unprecedented heterobimetallic [Cd_3Cd_2K] molecular building block with a(3,4)-connected(6·8·8)2(6·6·82·82·126·126) topology which represents a rare 2-fold interpenetrating 3D framework topology network. The luminescence analyses reveal that polymer 1 shows obvious emission at room temperature in the solid state. In addition,it was also characterized by elemental,IR spectra and TG analyses.展开更多
基金Funded by the National Natural Science Foundation of China(Nos.51202056,51372068)Hebei Natural Science Funds for Distinguished Young Scholar(No.B2014209304)+1 种基金Hebei Provincial Foundation for International Cooperation(No.15391403D)Hebei Natural Science Funds for the Joint Research of Iron and Steel(No.B2014209314)
文摘A series of Cd1-xZnxS/K2La2Ti3O10 composites were synthesized via a simple co-precipitation method. The prepared samples were characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM), X-ray energy dispersive spectroscopy(EDX), ultraviolet-visible diffuse reflection(UV-Vis), X-ray photoelectron spectroscopy(XPS) and photoluminescence(PL) measurements. The composite structures consisted of Cd1-xZnxS nanoparticles evenly distributed on the surface of K2La2Ti3O10. The absorption edge of K2La2Ti3O10 shifted to the visible light region upon introduction of the Cd1-xZnxS nanoparticles. The photocatalytic activities of the catalysts were evaluated by hydrogen production under visible light irradiation. The prepared Cd0.8Zn0.2S(30wt%)/K2La2Ti3O10 exhibited higher photocatalytic activity, evolving 6.92 mmol/g H2 under visible light irradiation for 3 h. The promoted photocatalytic activity of the composites was attributed to the synergistic effect between Cd1-xZnxS and K2La2Ti3O10, which resulted in enhanced separation of photogenerated electrons and holes.
基金supported by the National Natural Science Foundation of China(No.21273101 and 21302082)the Program for Science&Technology Innovation Talents in Universities of Henan Province(2014HASTIT014,14IRTSTHN008 and 164100510012)the Tackle Key Problem of Science and Technology Project of Henan Province(No.142102310483)
文摘A novel 3D hetero-nuclear framework,namely [K_2Cd_5(Hbptc)_4(H_2O)_(12)·12H_2O]_n(1,H4 bptc = biphenyl-2,3,3?,5?-tetracarboxylic acid),was obtained by hydrothermal reaction. X-ray singlecrystal structure analysis reveals that polymer 1 crystallizes in orthorhombic,space group Pbcn with a = 26.6152(13),b = 11.7449(5),c = 29.5923(14) ?,V = 9250.3(7) ?~3,C_(64)H_(76)Cd_5K_2O_(56),Mr = 2381.44,Dc = 1.710 g/cm^3,μ(MoK α) = 1.323 mm^(-1),F(000) = 4744,Z = 4,the final R = 0.0668 and wR = 0.1135 for 10613 observed reflections(I 〉 2σ(I)). Polymer 1 displays a 3D network that is built on the unprecedented heterobimetallic [Cd_3Cd_2K] molecular building block with a(3,4)-connected(6·8·8)2(6·6·82·82·126·126) topology which represents a rare 2-fold interpenetrating 3D framework topology network. The luminescence analyses reveal that polymer 1 shows obvious emission at room temperature in the solid state. In addition,it was also characterized by elemental,IR spectra and TG analyses.