It is necessary to synthesize new material for the advancements of the technology. In this study, new and novel poly(2-anisidine)@zirconium tungstate(P2A/ZrW_2O_8) was synthesized by simple so-gel method. Physicochemi...It is necessary to synthesize new material for the advancements of the technology. In this study, new and novel poly(2-anisidine)@zirconium tungstate(P2A/ZrW_2O_8) was synthesized by simple so-gel method. Physicochemical characterization of P2A/ZrW_2O_8 was done by thermogravimetric analysis(TGA), scanning electron microscopy(SEM), X-ray powder diffraction(XRD), Fourier transform infrared spectroscopy(FTIR), ion exchange and simultaneous four probe dc conductivity studies. The conductivity study revealed its highly semiconducting nature, in the range of 10^(-1)–10^(-2) S·cm^(-1). Ion-exchange capabilities of the composite make it applicable for cation-exchange studies. The result of distribution studies(Kd) revealed its selectivity towards Cd^(2+) compared to other metal ions. This property of the composite was utilized for designing Cd^(2+) selective membrane electrode. Several important physical parameters of the ion-selective electrode were determined, such as Nernstian slope(32.32 mV·decade^(-1)), working pH range was 2.0–4.0 and response time was found ～ 17 s.The analytical utility of this wave like composite membrane electrode was as, indicator electrode in various potentiometric titrations.展开更多
A new ion selective electrode for salicylate based on N,N＇-（aminoethyl）ethylenediamide bis（2-salicylideneimine） binuclear copper（Ⅱ） complex [Cu（Ⅱ）2-AEBS] as an ionophore was developed. The electrode has a l...A new ion selective electrode for salicylate based on N,N＇-（aminoethyl）ethylenediamide bis（2-salicylideneimine） binuclear copper（Ⅱ） complex [Cu（Ⅱ）2-AEBS] as an ionophore was developed. The electrode has a linear range from 1.0 × 10^-1 to 5.0 ×10^-7 mol·L^- 1 with a near-Nemstian slope of （ - 55 ±1 ） mV/decade and a detection limit of 2.0 × 10-7 mol·L^-1 in phosphorate buffer solution of pH 5.0 at 25 ℃. It shows good selectivity for Sal^- and displays anti-Hofmeister selectivity sequence： Sal^-〉SCN^-〉 ClO4^- 〉I^-〉 NO2^- 〉Br^-〉 NO3^- 〉Cl^-〉 SO3^2- 〉 SO4^2- The proposed sensor based on binuclear copper（Ⅱ）complex has a fast response time of 5-10 s and can be used for at least 2 months without any major deviation. The response mechanism is discussed in view of the alternating current （AC） impedance technique and the UV-vis spectroscopy technique. The effect of the electrode membrane compositions and the experimental conditions were studied. The electrode has been successfully used for the determination of salicylate ion in drug pharmaceutical preparations.展开更多
随着对海水、地热水资源越来越多的开发利用,测定其中的K+、Na+、Ca2+、Cl-含量的需求也随之增加。研究建立了一种双管线流动注射串联离子选择电极自动方法(FI-ISE-S),能用于海水、地热水中K+、Na+、Ca2+、Cl-同时、快速、自动测定。在...随着对海水、地热水资源越来越多的开发利用,测定其中的K+、Na+、Ca2+、Cl-含量的需求也随之增加。研究建立了一种双管线流动注射串联离子选择电极自动方法(FI-ISE-S),能用于海水、地热水中K+、Na+、Ca2+、Cl-同时、快速、自动测定。在研究过程中,对FI-ISE-S系统的各种影响因素,如系统流量、进样体积、混合盘管长度、干扰物质、总离子强度调节缓冲液的酸度及离子浓度等进行了考察和优化。在最优条件下,得到的分析速度为100样h 1,每次测定的样品用量仅为160μL,相对标准偏差小于1.96%(n=11),标准添加回收率为91.9%~109.6%,测定范围分别为1.0~8.0 mmol L 1K+、50~290 mmol L 1Na+、3.2~16.0 mmol L-1Ca2+、70~430 mmol L -1Cl-。该方法已成功应用于实际海水及地热水样品的测定。展开更多
A new highly selective salicylate electrode based on N,N’-bis(3-nitrosalicylidene)-2,6-Pyridinediamine manganese(Ⅱ) complex[Mn(Ⅱ)-BNSPD]as neutral carrier is studied first,which displays an excellent electric poten...A new highly selective salicylate electrode based on N,N’-bis(3-nitrosalicylidene)-2,6-Pyridinediamine manganese(Ⅱ) complex[Mn(Ⅱ)-BNSPD]as neutral carrier is studied first,which displays an excellent electric potential response and an anti-Hofmeister selectivity sequence which is:Sal->SCN-> ClO4-> I-> Br-> NO3-> Cl-> NO2-> SO32-> SO42-.The electrode exhibits Nernstian potential linear range to salicylate from 1.0×10-1 to 6.0×10-6 mol·dm-3 with a detection limit 2.0×10-6 mol·dm-3 and a slope of 58.5 mV/dec in pH 5.0 of phosphorate buffer solution at 28℃.The electrode response mechanism is studied with the UV spectroscopy technology.The electrode is designed to be applied in medicine analysis with a satisfactory result worked out.展开更多
制备了以N-（苯并〔1-3〕二噁茂-5-亚甲基）-1H-苯并咪唑-2-甲酰肼为载体的PVC膜电极.结果表明：该电极对铬（Ⅲ）离子在10-1~10-6mol/L的浓度范围内有良好的响应性能,响应斜率为22.9 m V/decade,检测下限为4.6×10-7mol/L.电极具...制备了以N-（苯并〔1-3〕二噁茂-5-亚甲基）-1H-苯并咪唑-2-甲酰肼为载体的PVC膜电极.结果表明：该电极对铬（Ⅲ）离子在10-1~10-6mol/L的浓度范围内有良好的响应性能,响应斜率为22.9 m V/decade,检测下限为4.6×10-7mol/L.电极具有较好的抗干扰性、重现性和稳定性,能在p H值为1.13~6.15的范围内和体积分数小于20%的乙醇溶液中使用.可用于水样品中铬含量的直接测定和电位滴定Cr3＋的指示电极.展开更多
文摘It is necessary to synthesize new material for the advancements of the technology. In this study, new and novel poly(2-anisidine)@zirconium tungstate(P2A/ZrW_2O_8) was synthesized by simple so-gel method. Physicochemical characterization of P2A/ZrW_2O_8 was done by thermogravimetric analysis(TGA), scanning electron microscopy(SEM), X-ray powder diffraction(XRD), Fourier transform infrared spectroscopy(FTIR), ion exchange and simultaneous four probe dc conductivity studies. The conductivity study revealed its highly semiconducting nature, in the range of 10^(-1)–10^(-2) S·cm^(-1). Ion-exchange capabilities of the composite make it applicable for cation-exchange studies. The result of distribution studies(Kd) revealed its selectivity towards Cd^(2+) compared to other metal ions. This property of the composite was utilized for designing Cd^(2+) selective membrane electrode. Several important physical parameters of the ion-selective electrode were determined, such as Nernstian slope(32.32 mV·decade^(-1)), working pH range was 2.0–4.0 and response time was found ～ 17 s.The analytical utility of this wave like composite membrane electrode was as, indicator electrode in various potentiometric titrations.
基金Project supported by the National Natural Science Foundation of China （No. 29705001） and the Natural Science Foundation of Chongqing City （Nos. CSTC-2004BB4149 and CSTC-2005BB4100）.
文摘A new ion selective electrode for salicylate based on N,N＇-（aminoethyl）ethylenediamide bis（2-salicylideneimine） binuclear copper（Ⅱ） complex [Cu（Ⅱ）2-AEBS] as an ionophore was developed. The electrode has a linear range from 1.0 × 10^-1 to 5.0 ×10^-7 mol·L^- 1 with a near-Nemstian slope of （ - 55 ±1 ） mV/decade and a detection limit of 2.0 × 10-7 mol·L^-1 in phosphorate buffer solution of pH 5.0 at 25 ℃. It shows good selectivity for Sal^- and displays anti-Hofmeister selectivity sequence： Sal^-〉SCN^-〉 ClO4^- 〉I^-〉 NO2^- 〉Br^-〉 NO3^- 〉Cl^-〉 SO3^2- 〉 SO4^2- The proposed sensor based on binuclear copper（Ⅱ）complex has a fast response time of 5-10 s and can be used for at least 2 months without any major deviation. The response mechanism is discussed in view of the alternating current （AC） impedance technique and the UV-vis spectroscopy technique. The effect of the electrode membrane compositions and the experimental conditions were studied. The electrode has been successfully used for the determination of salicylate ion in drug pharmaceutical preparations.
文摘随着对海水、地热水资源越来越多的开发利用,测定其中的K+、Na+、Ca2+、Cl-含量的需求也随之增加。研究建立了一种双管线流动注射串联离子选择电极自动方法(FI-ISE-S),能用于海水、地热水中K+、Na+、Ca2+、Cl-同时、快速、自动测定。在研究过程中,对FI-ISE-S系统的各种影响因素,如系统流量、进样体积、混合盘管长度、干扰物质、总离子强度调节缓冲液的酸度及离子浓度等进行了考察和优化。在最优条件下,得到的分析速度为100样h 1,每次测定的样品用量仅为160μL,相对标准偏差小于1.96%(n=11),标准添加回收率为91.9%~109.6%,测定范围分别为1.0~8.0 mmol L 1K+、50~290 mmol L 1Na+、3.2~16.0 mmol L-1Ca2+、70~430 mmol L -1Cl-。该方法已成功应用于实际海水及地热水样品的测定。
文摘A new highly selective salicylate electrode based on N,N’-bis(3-nitrosalicylidene)-2,6-Pyridinediamine manganese(Ⅱ) complex[Mn(Ⅱ)-BNSPD]as neutral carrier is studied first,which displays an excellent electric potential response and an anti-Hofmeister selectivity sequence which is:Sal->SCN-> ClO4-> I-> Br-> NO3-> Cl-> NO2-> SO32-> SO42-.The electrode exhibits Nernstian potential linear range to salicylate from 1.0×10-1 to 6.0×10-6 mol·dm-3 with a detection limit 2.0×10-6 mol·dm-3 and a slope of 58.5 mV/dec in pH 5.0 of phosphorate buffer solution at 28℃.The electrode response mechanism is studied with the UV spectroscopy technology.The electrode is designed to be applied in medicine analysis with a satisfactory result worked out.
文摘制备了以N-（苯并〔1-3〕二噁茂-5-亚甲基）-1H-苯并咪唑-2-甲酰肼为载体的PVC膜电极.结果表明：该电极对铬（Ⅲ）离子在10-1~10-6mol/L的浓度范围内有良好的响应性能,响应斜率为22.9 m V/decade,检测下限为4.6×10-7mol/L.电极具有较好的抗干扰性、重现性和稳定性,能在p H值为1.13~6.15的范围内和体积分数小于20%的乙醇溶液中使用.可用于水样品中铬含量的直接测定和电位滴定Cr3＋的指示电极.
