Peridotites from the southern Mariana forearc were sampled on the landward trench slope of the Izu-Bonin-Mariana (IBM) subduction zone by dredging.These mantle wedge peridotites underwent hydration by fluid derived fr...Peridotites from the southern Mariana forearc were sampled on the landward trench slope of the Izu-Bonin-Mariana (IBM) subduction zone by dredging.These mantle wedge peridotites underwent hydration by fluid derived from a dehydrated descending slab,and later interacted with seawater after emplacement at or near the seafloor.This study investigates how these two different rock-fluid interaction processes influenced trace element distribution in the southern Mariana forearc peridotites.We measured trace element concentrations of peridotites from the southern Mariana forearc.The southern Mariana forearc peridotites are characterized by a distinct seawater-like REE pattern with an obvious negative Ce anomaly,and La shows good correlation with other REEs (except Ce).In addition,there is a great enrichment of U,Pb,Sr and Li elements,which show a distinct positive anomaly relative to adjacent elements in the multi-element diagram.For the seawater-like REE pattern,we infer that REEs are mainly influenced by seawater during peridotite-seawater interactions after their emplacement at or near the seafloor,by serpentinization or by marine weathering.Furthermore,the anomalous behavior of Ce,compared with other rare earth elements in these samples,may indicate that they have undergone reactions involving Ce (IV) when the peridotites interacted with seawater.Positive U,Pb,Sr and Li anomalies are inferred to be related to seawater and/or fluids released during dehydration of the subducting slab.展开更多
The distribution and anomalies of rare earth elements(REEs) of granitic regolith were studied in Inner Mongolia and Hainan Island, China. One profile showed slight REE enrichment of an upper layer and no obvious light...The distribution and anomalies of rare earth elements(REEs) of granitic regolith were studied in Inner Mongolia and Hainan Island, China. One profile showed slight REE enrichment of an upper layer and no obvious light REE/heavy REE(LREE/HREE) fractionation(La_N/Yb_N of 0.9). The second profile was significantly enriched in REEs and enriched in LREEs in the upper portion(La_N/Yb_N>1.8). Eu, Ce, and Gd anomalies of the two profiles are different. Slightly negative Eu, Ce, and Gd anomalies in NMG-3-1 indicate slow dissolution of primary minerals and little secondary products; in contrast, a positive Eu anomaly in HN-2 suggests the vegetation cycle may contribute to soil. The Ce anomaly of HN-2 reflects oxidation of Ce and coprecipitation by Fe-and Mn-oxides and organic matter. Correlation between Ce and Gd anomalies in HN-2 suggests Ce and Gd are both influenced by redoxreduction.展开更多
Resource-saving（PrNdCe）_2Fe_（14）B sintered magnets with nominal composition（PrNd）_（15-x）Ce_xFe_（77）B_8（x=0–10）were prepared using a dual alloy method by mixing（PrNd）_5Ce_（10）Fe_（77）B_8 with（PrNd）_...Resource-saving（PrNdCe）_2Fe_（14）B sintered magnets with nominal composition（PrNd）_（15-x）Ce_xFe_（77）B_8（x=0–10）were prepared using a dual alloy method by mixing（PrNd）_5Ce_（10）Fe_（77）B_8 with（PrNd）_（15）Fe_（77）B_8 powders. For Ce atomic percent of 1% and 2%, coercivity decreases dramatically. With further increase of Ce atomic percent, the coercivity increases, peaks at 6.38 kOe in（PrNd）_（11）Ce_4Fe_（77）B_8, and then declines gradually. The abnormal dependence of coercivity is likely related to the inhomogeneity of rare earth chemical composition in the intergranular phase, where Pr Nd concentration is strongly dependent on the additive amount of（PrNd）_5Ce_（10）Fe_（77）B_8 powders. In addition, for Ce atomic percent of 8%,7%, and 6% the coercivity is higher than that of magnets prepared by the conventional method, which shows the advantage of the dual alloy method in preparing high abundant rare earth magnets.展开更多
基金Supported by the Pilot Project of Knowledge Innovation Project,Chinese Academy of Sciences (Nos.KZCX2-YW-211, KZCX3-SW-223)the National Natural Science Foundation of China (No.40830849)the Special Foundation for the Eleventh Five-Year Plan of COMRA (No.DYXM-115-02-1-03)
文摘Peridotites from the southern Mariana forearc were sampled on the landward trench slope of the Izu-Bonin-Mariana (IBM) subduction zone by dredging.These mantle wedge peridotites underwent hydration by fluid derived from a dehydrated descending slab,and later interacted with seawater after emplacement at or near the seafloor.This study investigates how these two different rock-fluid interaction processes influenced trace element distribution in the southern Mariana forearc peridotites.We measured trace element concentrations of peridotites from the southern Mariana forearc.The southern Mariana forearc peridotites are characterized by a distinct seawater-like REE pattern with an obvious negative Ce anomaly,and La shows good correlation with other REEs (except Ce).In addition,there is a great enrichment of U,Pb,Sr and Li elements,which show a distinct positive anomaly relative to adjacent elements in the multi-element diagram.For the seawater-like REE pattern,we infer that REEs are mainly influenced by seawater during peridotite-seawater interactions after their emplacement at or near the seafloor,by serpentinization or by marine weathering.Furthermore,the anomalous behavior of Ce,compared with other rare earth elements in these samples,may indicate that they have undergone reactions involving Ce (IV) when the peridotites interacted with seawater.Positive U,Pb,Sr and Li anomalies are inferred to be related to seawater and/or fluids released during dehydration of the subducting slab.
基金supported by the National Natural Science Foundation of China(Grant No.4121000441661144042)National Basic Research Program(973 project)of China(2013CB956401)
文摘The distribution and anomalies of rare earth elements(REEs) of granitic regolith were studied in Inner Mongolia and Hainan Island, China. One profile showed slight REE enrichment of an upper layer and no obvious light REE/heavy REE(LREE/HREE) fractionation(La_N/Yb_N of 0.9). The second profile was significantly enriched in REEs and enriched in LREEs in the upper portion(La_N/Yb_N>1.8). Eu, Ce, and Gd anomalies of the two profiles are different. Slightly negative Eu, Ce, and Gd anomalies in NMG-3-1 indicate slow dissolution of primary minerals and little secondary products; in contrast, a positive Eu anomaly in HN-2 suggests the vegetation cycle may contribute to soil. The Ce anomaly of HN-2 reflects oxidation of Ce and coprecipitation by Fe-and Mn-oxides and organic matter. Correlation between Ce and Gd anomalies in HN-2 suggests Ce and Gd are both influenced by redoxreduction.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51461033,51571126,51541105,and 11547032)the Natural Science Foundation of Inner Mongolia,China(Grant No.2013MS0110)the Inner Mongolia University of Science and Technology Innovation Fund,China
文摘Resource-saving（PrNdCe）_2Fe_（14）B sintered magnets with nominal composition（PrNd）_（15-x）Ce_xFe_（77）B_8（x=0–10）were prepared using a dual alloy method by mixing（PrNd）_5Ce_（10）Fe_（77）B_8 with（PrNd）_（15）Fe_（77）B_8 powders. For Ce atomic percent of 1% and 2%, coercivity decreases dramatically. With further increase of Ce atomic percent, the coercivity increases, peaks at 6.38 kOe in（PrNd）_（11）Ce_4Fe_（77）B_8, and then declines gradually. The abnormal dependence of coercivity is likely related to the inhomogeneity of rare earth chemical composition in the intergranular phase, where Pr Nd concentration is strongly dependent on the additive amount of（PrNd）_5Ce_（10）Fe_（77）B_8 powders. In addition, for Ce atomic percent of 8%,7%, and 6% the coercivity is higher than that of magnets prepared by the conventional method, which shows the advantage of the dual alloy method in preparing high abundant rare earth magnets.
