A ratiometric fluorescent probe for hypoxanthine(Hx)detection was established based on the mimic enzyme and fluorescence characteristics of cobalt-doped graphite-phase carbon nitride(Co doped g-C_(3)N_(4)).In addition...A ratiometric fluorescent probe for hypoxanthine(Hx)detection was established based on the mimic enzyme and fluorescence characteristics of cobalt-doped graphite-phase carbon nitride(Co doped g-C_(3)N_(4)).In addition to emitting strong fluorescence,the peroxidase activity of Co doped g-C_(3)N_(4)can catalyze the reaction of O-phenylenediamine and H_(2)O_(2)to produce diallyl phthalate which can emit yellow fluorescence at 570 nm.Through the decomposition of Hx by xanthine oxidase,Hx can be indirectly detected by the generating hydrogen peroxide based on the measurement of fluorescent ratio I(F_(570)/F_(370)).The linear range was 1.7-272.2 mg/kg(R^(2)=0.997),and the detection limit was 1.52 mg/kg(3σ/K,n=9).The established method was applied to Hx detection in bass,grass carp,and shrimp,and the data were verified by HPLC.The result shows that the established probe is sensitive,accurate,and reliable,and can be used for Hx detection in aquatic products.展开更多
The activation of H_(2)O is a key step of the COS hydrolysis,which may be tuned by oxygen vacancy defects in the catalysts.Herein,we have introduced Cu into Co_(3)O_(4) to regulate the oxygen vacancy defect content of...The activation of H_(2)O is a key step of the COS hydrolysis,which may be tuned by oxygen vacancy defects in the catalysts.Herein,we have introduced Cu into Co_(3)O_(4) to regulate the oxygen vacancy defect content of the catalysts.In situ DRIFTS and XPS spectra reveal that COS and H_(2)O are adsorbed and activated by oxygen vacancy.The 10 at%Cu doped Co_(3)O_(4) sample(10Cu-Co_(3)O_(4))exhibits the optimal activity,100%of COS conversion at 70℃.The improved oxygen vacancies of CueCo_(3)O_(4) accelerate the activation of H_(2)O to form active -OH.COS binds with hydroxyl to form the intermediate HSCO^(-)_(2),and then the activated-OH on the oxygen vacancy reacts with HSCO^(-)_(2) to form HCO^(-)_(3).Meanwhile,the catalyst exhibits high catalytic stability because copper species(Cu+/Cu^(2+))redox cycle mitigate the sulfation of Co_(3)O_(4)(Co^(2+)/Co^(3+)).Our work offers a promising approach for the rational design of cobalt-related catalysts in the highly efficient hydrolysis COS process.展开更多
Sn doping is an effective way to improve the response rate of Ga_(2)O_(3) film based solar-blind detectors. In this paper,Sn-doped Ga_(2)O_(3) films were prepared on a sapphire substrate by radio frequency magnetron s...Sn doping is an effective way to improve the response rate of Ga_(2)O_(3) film based solar-blind detectors. In this paper,Sn-doped Ga_(2)O_(3) films were prepared on a sapphire substrate by radio frequency magnetron sputtering. The films were characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy and ultraviolet visible spectroscopy, and the effect of annealing atmosphere on the properties of films was studied. The Ga_(2)O_(3) films changed from amorphous to β-Ga_(2)O_(3) after annealing at 900 °C. The films were composed of micro crystalline particles with a diameter of about 5–20 nm.The β-Ga_(2)O_(3) had high transmittance for wavelengths above 300 nm, and obvious absorption for solar-blind signals at 200–280 nm.The metal semiconductor metal type solar-blind detectors were prepared. The detector based on Sn-doped β-Ga_(2)O_(3) thin film annealed in N_2 has the best response performance to 254 nm light. The photo-current is 10 μA at 20 V, the dark-current is 5.76 pA,the photo dark current ratio is 1.7 × 10~6, the response rate is 12.47 A/W, the external quantum efficiency is 6.09 × 10~3%, the specific detection rate is 2.61 × 10~(12) Jones, the response time and recovery time are 378 and 90 ms, respectively.展开更多
Near-infrared to visible upconversion luminescence was observed in a multicomponent silicate (BK7) glass containing Ce^3 + ions under focused infrared femtosecond laser irradiation. The emission spectra show that t...Near-infrared to visible upconversion luminescence was observed in a multicomponent silicate (BK7) glass containing Ce^3 + ions under focused infrared femtosecond laser irradiation. The emission spectra show that the upconversion luminescence comes from the 4f-5d transition of the Ce^3 + ions. The relationship between the intensity of the Ce^3 + emission and the pump power reveals that a three-photon absorption predominates in the conversion process from the near-infrared into the blue luminescence. The analysis of the upconversion mechanism suggests that the upconversion luminescence may come from a three-photon simultaneous absorption that leads to a population of the 5d level in which the characteristic luminescence occurs.展开更多
Sr2Al2SiO7:Ce^3+, Tb^3+ white emitting phosphors were fabricated using the sol-gel method. X-Ray Powder Diffraction (XRD) analysis confirmed the formation of Sr2Al2SiO7:Ce^3+, Tb^3+. Scanning Electron Microsco...Sr2Al2SiO7:Ce^3+, Tb^3+ white emitting phosphors were fabricated using the sol-gel method. X-Ray Powder Diffraction (XRD) analysis confirmed the formation of Sr2Al2SiO7:Ce^3+, Tb^3+. Scanning Electron Microscopy (SEM) observation indicated that the microstructure of the phosphor consisted of regular fine grains with an average size of about 0.5-1 μm. Luminescence properties were analyzed by measuring the photoluminescence spectra. The Ce^3+, Tb^3+-codoped Sr2Al2SiO7 phosphors showed four main emission peaks: one at 414 nm for Ce^3+ and three at 482, 543, and 588 nm for Tb^3+. The emission spectra of the samples with different doping concentrations showed that the Tb^3+ emission was dominant because of the persistent energy transfer from Ce^3+. The decay characteristic was better than that prepared by the solid-state process in the comparable condition. The codoped phosphor displayed long persistent white phosphorescence.展开更多
The electronic structures of LiYF4:Ce^3+ and LiYF4 crystal simulated by an embedded (in a microcrystal containing 1938 ions) cluster CeY4Li8F24, and Y5LisF24 respectively, were computed by the ab initio self-consi...The electronic structures of LiYF4:Ce^3+ and LiYF4 crystal simulated by an embedded (in a microcrystal containing 1938 ions) cluster CeY4Li8F24, and Y5LisF24 respectively, were computed by the ab initio self-consistent relativistic DV-Xa (discrete variational Xa) method. The ground-state calculation showed that only the lowest 5d level Ed of Ce^3+ ion lies around the BCB (bottom of the conduction band) while the lowest 4f levels is 2.5 eV lower than BCB. The CB states consist of 4d of Y mixed with 5d of Ce, even for the wavefunctions (WFS) with energy Ed under BCB there are still 24% of Y-4d and 9% of F-2p as components. So, they are not pure crystal-field states at all. Furthermore, transition state (TS) calculation was performed to obtain the 4f→5d transition energies Efd, to improve the previous calculation performed by Andriessen et al, in which a small CeF8 cluster embedded in an array of point charge was used and the results of ground-state calculation were roughly used to compare with the observed 4f→5 d transition energies. The ionic radius of Ce^3+ is larger than that of y^3+ , so we had also modeled approximately the lattice relaxation. As results, the CeY4Li8F24 cluster with 4.56 % outward relaxation (of the nearest-neighbor and next nearest-neighbor eight fluorines) has the lowest total energy and gave satisfactory 4f→5d energies Efd, but the ground-state calculated Ed is 0.68 eV higher than BCB. For another cluster with 7.36% outward relaxation the Ed is 0.43 eV lower than BCB, which makes the observation of fine structure (including zero-phonon line) of the lowest 5 d band understandable easier, but the splits between the transition energies Efd were not as good as the former. Therefore, we consider the relaxation is some how around 4. 56% -7.36% outward, not as large as 10% proposed by Andriessen et al.展开更多
The electronic structures of LiYF4:Ce^3+ and LiYF4 crystal simulated by an embedded (in a microcrystal containing 1938 ions) cluster CeY4Li8F24, and Y5LisF24 respectively, were computed by the ab initio self-consi...The electronic structures of LiYF4:Ce^3+ and LiYF4 crystal simulated by an embedded (in a microcrystal containing 1938 ions) cluster CeY4Li8F24, and Y5LisF24 respectively, were computed by the ab initio self-consistent relativistic DV-Xa (discrete variational Xa) method. The ground-state calculation showed that only the lowest 5d level Ed of Ce^3+ ion lies around the BCB (bottom of the conduction band) while the lowest 4f levels is 2.5 eV lower than BCB. The CB states consist of 4d of Y mixed with 5d of Ce, even for the wavefunctions (WFS) with energy Ed under BCB there are still 24% of Y-4d and 9% of F-2p as components. So, they are not pure crystal-field states at all. Furthermore, transition state (TS) calculation was performed to obtain the 4f→5d transition energies Efd, to improve the previous calculation performed by Andriessen et al, in which a small CeF8 cluster embedded in an array of point charge was used and the results of ground-state calculation were roughly used to compare with the observed 4f→5 d transition energies. The ionic radius of Ce^3+ is larger than that of y^3+ , so we had also modeled approximately the lattice relaxation. As results, the CeY4Li8F24 cluster with 4.56 % outward relaxation (of the nearest-neighbor and next nearest-neighbor eight fluorines) has the lowest total energy and gave satisfactory 4f→5d energies Efd, but the ground-state calculated Ed is 0.68 eV higher than BCB. For another cluster with 7.36% outward relaxation the Ed is 0.43 eV lower than BCB, which makes the observation of fine structure (including zero-phonon line) of the lowest 5 d band understandable easier, but the splits between the transition energies Efd were not as good as the former. Therefore, we consider the relaxation is some how around 4. 56% -7.36% outward, not as large as 10% proposed by Andriessen et al.展开更多
The Ce^3+ and Eu^2+ ions codoped calcium zinc chlorosilicate Ca_8Zn(SiO_4)_4Cl_2 phosphors have been synthesized for the first time. The diffuse reflection, excitation and emission spectra of Ca_8Zn(SiO_4)_4Cl_2∶Ce^3...The Ce^3+ and Eu^2+ ions codoped calcium zinc chlorosilicate Ca_8Zn(SiO_4)_4Cl_2 phosphors have been synthesized for the first time. The diffuse reflection, excitation and emission spectra of Ca_8Zn(SiO_4)_4Cl_2∶Ce^3+, Eu^2+ have been measured at room temperature. The luminescence sensitizaiton of Eu^2+ by Ce^3+ inCa_8Zn(SiO_4)_4Cl_2∶Ce^3+, Eu^2+ has been expounded under the excitation of ultraviolet light and the efficient nonradiative energy transfer from Ce^3+ to Eu^2+ in this system is confirmed.展开更多
Ce3+-doped yttrium lanthanum oxide (Y0.9La0.1)2O3 transparent ceramics is fabricated with nanopowders and sintered in H2 atmosphere. The spectral properties of Ce:(Y0.9La0.1)2O3 transparent ceramics are investig...Ce3+-doped yttrium lanthanum oxide (Y0.9La0.1)2O3 transparent ceramics is fabricated with nanopowders and sintered in H2 atmosphere. The spectral properties of Ce:(Y0.9La0.1)2O3 transparent ceramics are investigated. There appear two characteristic absorption peaks of Ce3+ ions at 230~nm and 400~nm, separately. It is found that Ce3+ ions can efficiently produce emission at 384~nm from (Y0.9La0.1)2O3 transparent ceramic host, while the emission is completely quenched in Re2O3 (Re=Y, Lu, La) host materials.展开更多
Thispaperisconcerned withthe preparation ofcerium doped yttrium iron garnet which areknown to be an oxide withlarge magneto opticaleffect. Usingtheimproved flux method wesuccessfully grew the bulksinglecrystalsofiron...Thispaperisconcerned withthe preparation ofcerium doped yttrium iron garnet which areknown to be an oxide withlarge magneto opticaleffect. Usingtheimproved flux method wesuccessfully grew the bulksinglecrystalsofiron garnet doped by Ce 3 + ions with maximum substitution upto0 349. Here weinvestigatedthedifferentcomposition ofsolution for maxi mum Ce3 + substitution. Thespectra ofthe Faraday rotation andtheoptical absorption were measured inthenearinfrared region fordifferentCe3 + ionsdopediron garnets. The Cesub stitution prominentlyenhancesthe Faradayeffect,andthe Yb and Euionssubstitutefor Yinthe dodecahedralsitesof YIGcanincreasetheconcentration of Ce3 + ions, depresstheforma tion of nonmagnetic Ce4 + ionsbythechargecompensation.展开更多
基金supported by the National Natural Science Foundation of China(21804050)the National Key R and D Program of China(2018YFD0901003)+2 种基金the Science and Technology Planning Project of Xiamen,China(3502Z20183031)the Fujian Provincial Fund Project(2018J01432)the Xiamen Science and Technology Planning Project,China(3502Z20183031)。
文摘A ratiometric fluorescent probe for hypoxanthine(Hx)detection was established based on the mimic enzyme and fluorescence characteristics of cobalt-doped graphite-phase carbon nitride(Co doped g-C_(3)N_(4)).In addition to emitting strong fluorescence,the peroxidase activity of Co doped g-C_(3)N_(4)can catalyze the reaction of O-phenylenediamine and H_(2)O_(2)to produce diallyl phthalate which can emit yellow fluorescence at 570 nm.Through the decomposition of Hx by xanthine oxidase,Hx can be indirectly detected by the generating hydrogen peroxide based on the measurement of fluorescent ratio I(F_(570)/F_(370)).The linear range was 1.7-272.2 mg/kg(R^(2)=0.997),and the detection limit was 1.52 mg/kg(3σ/K,n=9).The established method was applied to Hx detection in bass,grass carp,and shrimp,and the data were verified by HPLC.The result shows that the established probe is sensitive,accurate,and reliable,and can be used for Hx detection in aquatic products.
基金the National Natural Science Foundation of China (92034301,22078063 and 22022804)Major Program of Qingyuan Innovation Laboratory (00121003)the Natural Science Foundation of Fujian Province (2020H6007)。
文摘The activation of H_(2)O is a key step of the COS hydrolysis,which may be tuned by oxygen vacancy defects in the catalysts.Herein,we have introduced Cu into Co_(3)O_(4) to regulate the oxygen vacancy defect content of the catalysts.In situ DRIFTS and XPS spectra reveal that COS and H_(2)O are adsorbed and activated by oxygen vacancy.The 10 at%Cu doped Co_(3)O_(4) sample(10Cu-Co_(3)O_(4))exhibits the optimal activity,100%of COS conversion at 70℃.The improved oxygen vacancies of CueCo_(3)O_(4) accelerate the activation of H_(2)O to form active -OH.COS binds with hydroxyl to form the intermediate HSCO^(-)_(2),and then the activated-OH on the oxygen vacancy reacts with HSCO^(-)_(2) to form HCO^(-)_(3).Meanwhile,the catalyst exhibits high catalytic stability because copper species(Cu+/Cu^(2+))redox cycle mitigate the sulfation of Co_(3)O_(4)(Co^(2+)/Co^(3+)).Our work offers a promising approach for the rational design of cobalt-related catalysts in the highly efficient hydrolysis COS process.
基金supported by the National Natural Science Foundation of China (Grant No. 62204203)the Shaanxi Natural Science Basic Research Program (Grant No. 2022JQ-701)。
文摘Sn doping is an effective way to improve the response rate of Ga_(2)O_(3) film based solar-blind detectors. In this paper,Sn-doped Ga_(2)O_(3) films were prepared on a sapphire substrate by radio frequency magnetron sputtering. The films were characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy and ultraviolet visible spectroscopy, and the effect of annealing atmosphere on the properties of films was studied. The Ga_(2)O_(3) films changed from amorphous to β-Ga_(2)O_(3) after annealing at 900 °C. The films were composed of micro crystalline particles with a diameter of about 5–20 nm.The β-Ga_(2)O_(3) had high transmittance for wavelengths above 300 nm, and obvious absorption for solar-blind signals at 200–280 nm.The metal semiconductor metal type solar-blind detectors were prepared. The detector based on Sn-doped β-Ga_(2)O_(3) thin film annealed in N_2 has the best response performance to 254 nm light. The photo-current is 10 μA at 20 V, the dark-current is 5.76 pA,the photo dark current ratio is 1.7 × 10~6, the response rate is 12.47 A/W, the external quantum efficiency is 6.09 × 10~3%, the specific detection rate is 2.61 × 10~(12) Jones, the response time and recovery time are 378 and 90 ms, respectively.
基金Project supported bythe National Natural Science Foundation of China (50125258 and 60377040)
文摘Near-infrared to visible upconversion luminescence was observed in a multicomponent silicate (BK7) glass containing Ce^3 + ions under focused infrared femtosecond laser irradiation. The emission spectra show that the upconversion luminescence comes from the 4f-5d transition of the Ce^3 + ions. The relationship between the intensity of the Ce^3 + emission and the pump power reveals that a three-photon absorption predominates in the conversion process from the near-infrared into the blue luminescence. The analysis of the upconversion mechanism suggests that the upconversion luminescence may come from a three-photon simultaneous absorption that leads to a population of the 5d level in which the characteristic luminescence occurs.
基金the National Natural Science Foundation of China (20376009)the Liaoning Natural Science Foundation (20032129) of China
文摘Sr2Al2SiO7:Ce^3+, Tb^3+ white emitting phosphors were fabricated using the sol-gel method. X-Ray Powder Diffraction (XRD) analysis confirmed the formation of Sr2Al2SiO7:Ce^3+, Tb^3+. Scanning Electron Microscopy (SEM) observation indicated that the microstructure of the phosphor consisted of regular fine grains with an average size of about 0.5-1 μm. Luminescence properties were analyzed by measuring the photoluminescence spectra. The Ce^3+, Tb^3+-codoped Sr2Al2SiO7 phosphors showed four main emission peaks: one at 414 nm for Ce^3+ and three at 482, 543, and 588 nm for Tb^3+. The emission spectra of the samples with different doping concentrations showed that the Tb^3+ emission was dominant because of the persistent energy transfer from Ce^3+. The decay characteristic was better than that prepared by the solid-state process in the comparable condition. The codoped phosphor displayed long persistent white phosphorescence.
文摘The electronic structures of LiYF4:Ce^3+ and LiYF4 crystal simulated by an embedded (in a microcrystal containing 1938 ions) cluster CeY4Li8F24, and Y5LisF24 respectively, were computed by the ab initio self-consistent relativistic DV-Xa (discrete variational Xa) method. The ground-state calculation showed that only the lowest 5d level Ed of Ce^3+ ion lies around the BCB (bottom of the conduction band) while the lowest 4f levels is 2.5 eV lower than BCB. The CB states consist of 4d of Y mixed with 5d of Ce, even for the wavefunctions (WFS) with energy Ed under BCB there are still 24% of Y-4d and 9% of F-2p as components. So, they are not pure crystal-field states at all. Furthermore, transition state (TS) calculation was performed to obtain the 4f→5d transition energies Efd, to improve the previous calculation performed by Andriessen et al, in which a small CeF8 cluster embedded in an array of point charge was used and the results of ground-state calculation were roughly used to compare with the observed 4f→5 d transition energies. The ionic radius of Ce^3+ is larger than that of y^3+ , so we had also modeled approximately the lattice relaxation. As results, the CeY4Li8F24 cluster with 4.56 % outward relaxation (of the nearest-neighbor and next nearest-neighbor eight fluorines) has the lowest total energy and gave satisfactory 4f→5d energies Efd, but the ground-state calculated Ed is 0.68 eV higher than BCB. For another cluster with 7.36% outward relaxation the Ed is 0.43 eV lower than BCB, which makes the observation of fine structure (including zero-phonon line) of the lowest 5 d band understandable easier, but the splits between the transition energies Efd were not as good as the former. Therefore, we consider the relaxation is some how around 4. 56% -7.36% outward, not as large as 10% proposed by Andriessen et al.
文摘The electronic structures of LiYF4:Ce^3+ and LiYF4 crystal simulated by an embedded (in a microcrystal containing 1938 ions) cluster CeY4Li8F24, and Y5LisF24 respectively, were computed by the ab initio self-consistent relativistic DV-Xa (discrete variational Xa) method. The ground-state calculation showed that only the lowest 5d level Ed of Ce^3+ ion lies around the BCB (bottom of the conduction band) while the lowest 4f levels is 2.5 eV lower than BCB. The CB states consist of 4d of Y mixed with 5d of Ce, even for the wavefunctions (WFS) with energy Ed under BCB there are still 24% of Y-4d and 9% of F-2p as components. So, they are not pure crystal-field states at all. Furthermore, transition state (TS) calculation was performed to obtain the 4f→5d transition energies Efd, to improve the previous calculation performed by Andriessen et al, in which a small CeF8 cluster embedded in an array of point charge was used and the results of ground-state calculation were roughly used to compare with the observed 4f→5 d transition energies. The ionic radius of Ce^3+ is larger than that of y^3+ , so we had also modeled approximately the lattice relaxation. As results, the CeY4Li8F24 cluster with 4.56 % outward relaxation (of the nearest-neighbor and next nearest-neighbor eight fluorines) has the lowest total energy and gave satisfactory 4f→5d energies Efd, but the ground-state calculated Ed is 0.68 eV higher than BCB. For another cluster with 7.36% outward relaxation the Ed is 0.43 eV lower than BCB, which makes the observation of fine structure (including zero-phonon line) of the lowest 5 d band understandable easier, but the splits between the transition energies Efd were not as good as the former. Therefore, we consider the relaxation is some how around 4. 56% -7.36% outward, not as large as 10% proposed by Andriessen et al.
文摘The Ce^3+ and Eu^2+ ions codoped calcium zinc chlorosilicate Ca_8Zn(SiO_4)_4Cl_2 phosphors have been synthesized for the first time. The diffuse reflection, excitation and emission spectra of Ca_8Zn(SiO_4)_4Cl_2∶Ce^3+, Eu^2+ have been measured at room temperature. The luminescence sensitizaiton of Eu^2+ by Ce^3+ inCa_8Zn(SiO_4)_4Cl_2∶Ce^3+, Eu^2+ has been expounded under the excitation of ultraviolet light and the efficient nonradiative energy transfer from Ce^3+ to Eu^2+ in this system is confirmed.
基金supported by the National Natural Science Foundation of China (Grant No. 60578041)the Shanghai Leading Academic Disciplines (Grant No. S30107)
文摘Ce3+-doped yttrium lanthanum oxide (Y0.9La0.1)2O3 transparent ceramics is fabricated with nanopowders and sintered in H2 atmosphere. The spectral properties of Ce:(Y0.9La0.1)2O3 transparent ceramics are investigated. There appear two characteristic absorption peaks of Ce3+ ions at 230~nm and 400~nm, separately. It is found that Ce3+ ions can efficiently produce emission at 384~nm from (Y0.9La0.1)2O3 transparent ceramic host, while the emission is completely quenched in Re2O3 (Re=Y, Lu, La) host materials.
文摘Thispaperisconcerned withthe preparation ofcerium doped yttrium iron garnet which areknown to be an oxide withlarge magneto opticaleffect. Usingtheimproved flux method wesuccessfully grew the bulksinglecrystalsofiron garnet doped by Ce 3 + ions with maximum substitution upto0 349. Here weinvestigatedthedifferentcomposition ofsolution for maxi mum Ce3 + substitution. Thespectra ofthe Faraday rotation andtheoptical absorption were measured inthenearinfrared region fordifferentCe3 + ionsdopediron garnets. The Cesub stitution prominentlyenhancesthe Faradayeffect,andthe Yb and Euionssubstitutefor Yinthe dodecahedralsitesof YIGcanincreasetheconcentration of Ce3 + ions, depresstheforma tion of nonmagnetic Ce4 + ionsbythechargecompensation.