实现高发光效率、高亮度和良好的热稳定性是固态照明的迫切要求。因此,用于高功率发光二极管或激光二极管(LED/LD)的高性能荧光转换材料具有重要的研究意义。在这项工作中,通过将Lu^(3+)离子引入YAG∶Ce荧光陶瓷中方法作为有效策略来改...实现高发光效率、高亮度和良好的热稳定性是固态照明的迫切要求。因此,用于高功率发光二极管或激光二极管(LED/LD)的高性能荧光转换材料具有重要的研究意义。在这项工作中,通过将Lu^(3+)离子引入YAG∶Ce荧光陶瓷中方法作为有效策略来改善YAG∶Ce荧光材料的发光性能。采用固相反应和真空烧结法制Article ID:1000-7032(2023)06-0964^(-1)1收稿日期:2022^(-1)2-31;修订日期:2023-01-30基金项目:中国科学院战略性先导科技专项(XDA22010301)Supported by The Strategic Priority Research Program of The Chinese Academy of Sciences(XDA22010301)第6 HUANG Xinyou期,et al.:LuYAG∶Ce Transparent Ceramic Phosphors for High-brightness Solid-state…备了不同Lu^(3+)含量的(Lu,Y)_(3)Al_(5)O_(12)∶Ce荧光陶瓷(LuYAG∶Ce荧光陶瓷)。随着Lu^(3+)含量的增加,LuYAG∶Ce荧光陶瓷中的Y^(3+)位点被Lu^(3+)位点取代,Ce^(3+)的发射峰呈现从573 nm到563 nm的蓝移现象。当Lu^(3+)含量为60%时,通过将LuYAG∶Ce荧光陶瓷与蓝光LED组合,其发光强度达到最大值,流明效率达到114 lm∙W^(-1)。使用450 nm激光源与LuYAG∶Ce荧光陶瓷构建了透射模式下的激光驱动照明装置。随着功率密度从2.2 W·mm^(-2)增加到39 W·mm^(-2),Lu^(3+)含量为60%的荧光陶瓷光通量从128 lm增加到1874 lm,且没有发光饱和的迹象,最佳发光效率达到128 lm·W^(-1)。因此,LuYAG∶Ce荧光陶瓷有望成为高功率LED/LD照明的潜在荧光转换材料。展开更多
The effects of Ce, Y and Gd additions on the as-cast microstructure and mechanical properties of Mg-3Sn-2Sr alloy were investigated and compared by scanning electron microscopy, X-ray diffraction, differential scannin...The effects of Ce, Y and Gd additions on the as-cast microstructure and mechanical properties of Mg-3Sn-2Sr alloy were investigated and compared by scanning electron microscopy, X-ray diffraction, differential scanning calorimetry analysis, tensile and creep tests. The results indicate that the Mg-3Sn-2Sr ternary alloy is mainly composed ofα-Mg, primary and eutectic SrMgSn, and Mg2Sn phases. After the additions of 1.0%Ce, 1.0%Y and 1.0%Gd to the Mg-3Sn-2Sr alloy, the Mg12Ce, YMgSn, GdMgSn and/or Mg17Sr2 phases are formed, respectively. At the same time, the formation of the primary SrMgSn phase is suppressed and the coarse needle-like primary SrMgSn phase is modified and refined. In addition, the additions of 1.0% Ce, 1.0% Y and 1.0% Gd to the Mg-3Sn-2Sr alloy can simultaneously improve the tensile and creep properties of the alloy. Among the Ce-, Y-and Gd-containing alloys, the tensile properties of the Ce-containing alloy are relatively higher than those of the Y-and Gd-containing alloys.展开更多
采用各种分析手段研究Y和Ce元素在镁中的存在形式和热力学行为,以及稀土元素对镁合金组织的影响。结果表明,镁合金的晶界处先形成Mg12Ce相,继而生成Mg24Y5相。镁合金经过固溶和时效处理后,在晶界和晶粒内分别析出Mg12Ce和Mg24Y5相;随时...采用各种分析手段研究Y和Ce元素在镁中的存在形式和热力学行为,以及稀土元素对镁合金组织的影响。结果表明,镁合金的晶界处先形成Mg12Ce相,继而生成Mg24Y5相。镁合金经过固溶和时效处理后,在晶界和晶粒内分别析出Mg12Ce和Mg24Y5相;随时效时间延长,晶粒内逐渐出现更稳定的呈点状分布的相,它由Mg24Y5、Mg2Y及Mg Y 3种化合物组成,晶界上也出现了由多种镁铈金属间化合物组成的相,镁合金硬度随时效时间先升高后降低再升高。展开更多
文摘实现高发光效率、高亮度和良好的热稳定性是固态照明的迫切要求。因此,用于高功率发光二极管或激光二极管(LED/LD)的高性能荧光转换材料具有重要的研究意义。在这项工作中,通过将Lu^(3+)离子引入YAG∶Ce荧光陶瓷中方法作为有效策略来改善YAG∶Ce荧光材料的发光性能。采用固相反应和真空烧结法制Article ID:1000-7032(2023)06-0964^(-1)1收稿日期:2022^(-1)2-31;修订日期:2023-01-30基金项目:中国科学院战略性先导科技专项(XDA22010301)Supported by The Strategic Priority Research Program of The Chinese Academy of Sciences(XDA22010301)第6 HUANG Xinyou期,et al.:LuYAG∶Ce Transparent Ceramic Phosphors for High-brightness Solid-state…备了不同Lu^(3+)含量的(Lu,Y)_(3)Al_(5)O_(12)∶Ce荧光陶瓷(LuYAG∶Ce荧光陶瓷)。随着Lu^(3+)含量的增加,LuYAG∶Ce荧光陶瓷中的Y^(3+)位点被Lu^(3+)位点取代,Ce^(3+)的发射峰呈现从573 nm到563 nm的蓝移现象。当Lu^(3+)含量为60%时,通过将LuYAG∶Ce荧光陶瓷与蓝光LED组合,其发光强度达到最大值,流明效率达到114 lm∙W^(-1)。使用450 nm激光源与LuYAG∶Ce荧光陶瓷构建了透射模式下的激光驱动照明装置。随着功率密度从2.2 W·mm^(-2)增加到39 W·mm^(-2),Lu^(3+)含量为60%的荧光陶瓷光通量从128 lm增加到1874 lm,且没有发光饱和的迹象,最佳发光效率达到128 lm·W^(-1)。因此,LuYAG∶Ce荧光陶瓷有望成为高功率LED/LD照明的潜在荧光转换材料。
基金Project(CSTC2013jcyjC60001)supported by the Chongqing Science and Technology Commission of ChinaProject(KJ120834)supported by the Chongqing Education Commission of ChinaProject(CQUT1205)supported by the Open Funds from Key Laboratory of Manufacture and Test Techniques for Automobile Parts,Ministry of Education,Chongqing University of Technology,China
文摘The effects of Ce, Y and Gd additions on the as-cast microstructure and mechanical properties of Mg-3Sn-2Sr alloy were investigated and compared by scanning electron microscopy, X-ray diffraction, differential scanning calorimetry analysis, tensile and creep tests. The results indicate that the Mg-3Sn-2Sr ternary alloy is mainly composed ofα-Mg, primary and eutectic SrMgSn, and Mg2Sn phases. After the additions of 1.0%Ce, 1.0%Y and 1.0%Gd to the Mg-3Sn-2Sr alloy, the Mg12Ce, YMgSn, GdMgSn and/or Mg17Sr2 phases are formed, respectively. At the same time, the formation of the primary SrMgSn phase is suppressed and the coarse needle-like primary SrMgSn phase is modified and refined. In addition, the additions of 1.0% Ce, 1.0% Y and 1.0% Gd to the Mg-3Sn-2Sr alloy can simultaneously improve the tensile and creep properties of the alloy. Among the Ce-, Y-and Gd-containing alloys, the tensile properties of the Ce-containing alloy are relatively higher than those of the Y-and Gd-containing alloys.
文摘采用各种分析手段研究Y和Ce元素在镁中的存在形式和热力学行为,以及稀土元素对镁合金组织的影响。结果表明,镁合金的晶界处先形成Mg12Ce相,继而生成Mg24Y5相。镁合金经过固溶和时效处理后,在晶界和晶粒内分别析出Mg12Ce和Mg24Y5相;随时效时间延长,晶粒内逐渐出现更稳定的呈点状分布的相,它由Mg24Y5、Mg2Y及Mg Y 3种化合物组成,晶界上也出现了由多种镁铈金属间化合物组成的相,镁合金硬度随时效时间先升高后降低再升高。
