Green-photoluminescence material Zn4B6O13: Ce3+, Tb3+ was first synthesized by spread method of high temperature and solid state reaction, which is cubic crystal system with lattice parameters: a(0) = 0.7472 nm, V = 0...Green-photoluminescence material Zn4B6O13: Ce3+, Tb3+ was first synthesized by spread method of high temperature and solid state reaction, which is cubic crystal system with lattice parameters: a(0) = 0.7472 nm, V = 0.4172 nm(3), and structural properties are investigated by XRD. The excitation and emission band of Ce3+ ion single-doped in Zn4B6O13 transfer longer spectra 2.38 similar to 4.94 kk than in other matrices. Emission band of Ce3+ ion better overlaps with the F-7(6)-->(5)G(2),D-5(1),H-5(7) absorption band of Tb3+. It shows that emission of Tb3+ ion is sensitized by Ce3+. In Zn4B6O13:Ce3+, Tb3+, it is due to the energy transfer mechanism, resonance transfer of electric multipolar interaction of the dipole-dipole between Ce3+-->Ce3+ and Ce3+-->Tb3+. The color coordinates of Zn4B6O13: X 0.281, gamma = 0.619. The mean diameter of the particles is 0.23 mum.展开更多
A series of Ce, H3PW12O40 co-doped TiO2 hollow fibers photocatalysts have been prepared by sol-gel method using ammonium ceric nitrate, H3PW12O40 and tetrabutyltitanate as precursors and cotton fibers as template, fol...A series of Ce, H3PW12O40 co-doped TiO2 hollow fibers photocatalysts have been prepared by sol-gel method using ammonium ceric nitrate, H3PW12O40 and tetrabutyltitanate as precursors and cotton fibers as template, followed by calcination at 500 ℃ in N2 atmosphere for 2 h. Scanning electron microscopy, X-ray diffraction, nitrogen adsorption-desorption mea- surements, and UV-Vis spectroscopy are employed to characterize the morphology, crystal structure, surface structure, and optical absorption properties of the samples. The photo- catalytic performance of the samples has been studied by photodegradation phenol in water under UV and visible light irradiation. The results show that the TiO2 fiber materials have hollow structures, and the co-doped TiO2 hollow fibers exhibit higher photocatalytic activities for the degradation of phenol than un-doped, single-doped TiO2 hollow fibers under UV and visible light. In addition, the recyclability of co-doped TiO2 fibers is also confirmed that the TiO2 fiber retains ca. 90% of its activity after being used four times. It is shown that the co-doped TiO2 fibers can be activated by visible light and may be potentially applied to the treatment of water contaminated by organic pollutants. The synergistic effect of Ce and H3PW12O40 co-doping plays an important role in improving the photocatalytic activity.展开更多
In this work, ZnO, Ce<sup>3+</sup> doped ZnO (ZnO/Ce<sup>3+</sup>) and Cu<sup>2+</sup> + Ce<sup>3+</sup> co-doped ZnO (ZnO/Cu<sup>2+</sup> + Ce<sup>3+&...In this work, ZnO, Ce<sup>3+</sup> doped ZnO (ZnO/Ce<sup>3+</sup>) and Cu<sup>2+</sup> + Ce<sup>3+</sup> co-doped ZnO (ZnO/Cu<sup>2+</sup> + Ce<sup>3+</sup> ) solid solutions powders were synthesized by a solution combustion method maintaining the Ce<sup>3+</sup> ion concentration constant in 3%Wt while the Cu<sup>2+</sup> ion concentration was varied in 1, 2, 3, 10 and 20%Wt. After its synthesis, all the samples were annealed at 900?C by 24 h. The ZnO, ZnO/Ce<sup>3+</sup> and ZnO/Cu<sup>2+</sup> + Ce<sup>3+</sup> powders were structurally characterized using X-ray diffraction (XRD) technique, and the XRD patterns showed that for pure ZnO, Cu<sup>2+</sup> undoped ZnO/Ce<sup>3</sup><sup>+</sup> and ZnO/Ce<sup>3+</sup> doped with the Cu<sup>2+</sup> ion, the three samples exhibited the hexagonal wurtzite ZnO crystalline structure. However, the morphology and particle size of both samples were observed by means of a scanning electron microscopy (SEM);from SEM image, it is observed that the crystallites of both samples are agglomerated forming bigger amorphous particles with an approximate average size of 1 μm. In addition, the photoluminescence of the ZnO, Ce<sup>3+</sup> doped ZnO and Cu<sup>2+</sup> + Ce<sup>3+</sup> doped ZnO samples was measurement under an illumination of 209 nm wavelength (UV region): for the ZnO/Ce<sup>3+</sup> sample, your emission spectrum is in the visible region from blue color until red color;the UV band of the ZnO is suppressed. The multicolor emission visible is attributed to the Ce<sup>3+</sup> ion photoluminescence, while for the ZnO/Cu<sup>2+</sup> + Ce<sup>3+</sup>, its emission PL spectrum is quenching by the Cu<sup>2+</sup> ion, present in the ZnO crystalline.展开更多
文摘Green-photoluminescence material Zn4B6O13: Ce3+, Tb3+ was first synthesized by spread method of high temperature and solid state reaction, which is cubic crystal system with lattice parameters: a(0) = 0.7472 nm, V = 0.4172 nm(3), and structural properties are investigated by XRD. The excitation and emission band of Ce3+ ion single-doped in Zn4B6O13 transfer longer spectra 2.38 similar to 4.94 kk than in other matrices. Emission band of Ce3+ ion better overlaps with the F-7(6)-->(5)G(2),D-5(1),H-5(7) absorption band of Tb3+. It shows that emission of Tb3+ ion is sensitized by Ce3+. In Zn4B6O13:Ce3+, Tb3+, it is due to the energy transfer mechanism, resonance transfer of electric multipolar interaction of the dipole-dipole between Ce3+-->Ce3+ and Ce3+-->Tb3+. The color coordinates of Zn4B6O13: X 0.281, gamma = 0.619. The mean diameter of the particles is 0.23 mum.
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China (No.41373127) and Liaon- ing Provincial Natural Science Foundation of China (No.2013020121).
文摘A series of Ce, H3PW12O40 co-doped TiO2 hollow fibers photocatalysts have been prepared by sol-gel method using ammonium ceric nitrate, H3PW12O40 and tetrabutyltitanate as precursors and cotton fibers as template, followed by calcination at 500 ℃ in N2 atmosphere for 2 h. Scanning electron microscopy, X-ray diffraction, nitrogen adsorption-desorption mea- surements, and UV-Vis spectroscopy are employed to characterize the morphology, crystal structure, surface structure, and optical absorption properties of the samples. The photo- catalytic performance of the samples has been studied by photodegradation phenol in water under UV and visible light irradiation. The results show that the TiO2 fiber materials have hollow structures, and the co-doped TiO2 hollow fibers exhibit higher photocatalytic activities for the degradation of phenol than un-doped, single-doped TiO2 hollow fibers under UV and visible light. In addition, the recyclability of co-doped TiO2 fibers is also confirmed that the TiO2 fiber retains ca. 90% of its activity after being used four times. It is shown that the co-doped TiO2 fibers can be activated by visible light and may be potentially applied to the treatment of water contaminated by organic pollutants. The synergistic effect of Ce and H3PW12O40 co-doping plays an important role in improving the photocatalytic activity.
文摘In this work, ZnO, Ce<sup>3+</sup> doped ZnO (ZnO/Ce<sup>3+</sup>) and Cu<sup>2+</sup> + Ce<sup>3+</sup> co-doped ZnO (ZnO/Cu<sup>2+</sup> + Ce<sup>3+</sup> ) solid solutions powders were synthesized by a solution combustion method maintaining the Ce<sup>3+</sup> ion concentration constant in 3%Wt while the Cu<sup>2+</sup> ion concentration was varied in 1, 2, 3, 10 and 20%Wt. After its synthesis, all the samples were annealed at 900?C by 24 h. The ZnO, ZnO/Ce<sup>3+</sup> and ZnO/Cu<sup>2+</sup> + Ce<sup>3+</sup> powders were structurally characterized using X-ray diffraction (XRD) technique, and the XRD patterns showed that for pure ZnO, Cu<sup>2+</sup> undoped ZnO/Ce<sup>3</sup><sup>+</sup> and ZnO/Ce<sup>3+</sup> doped with the Cu<sup>2+</sup> ion, the three samples exhibited the hexagonal wurtzite ZnO crystalline structure. However, the morphology and particle size of both samples were observed by means of a scanning electron microscopy (SEM);from SEM image, it is observed that the crystallites of both samples are agglomerated forming bigger amorphous particles with an approximate average size of 1 μm. In addition, the photoluminescence of the ZnO, Ce<sup>3+</sup> doped ZnO and Cu<sup>2+</sup> + Ce<sup>3+</sup> doped ZnO samples was measurement under an illumination of 209 nm wavelength (UV region): for the ZnO/Ce<sup>3+</sup> sample, your emission spectrum is in the visible region from blue color until red color;the UV band of the ZnO is suppressed. The multicolor emission visible is attributed to the Ce<sup>3+</sup> ion photoluminescence, while for the ZnO/Cu<sup>2+</sup> + Ce<sup>3+</sup>, its emission PL spectrum is quenching by the Cu<sup>2+</sup> ion, present in the ZnO crystalline.