K_(0.5)Na_(0.5)NbO_(3)-SrTiO_(3)(KNN-STO)thin films of different compositions were prepared by the chemical solution deposition method.While structural investigations confirmed the formation of perovskite solid soluti...K_(0.5)Na_(0.5)NbO_(3)-SrTiO_(3)(KNN-STO)thin films of different compositions were prepared by the chemical solution deposition method.While structural investigations confirmed the formation of perovskite solid solution in all developed films,dieletric experiments revealed a relaxor broad dispersive maximum in the sample with 15 mol%of STO,exhibiting for a thin film high ε′~330 at~210K.The history-dependent effects of this relaxor sample were compared to those of KNN STO ceramics and,furthermore,shown to be much weaker than in widely used lead-based ferroelectric and relaxor(Pb,L a)(Zr,Ti)O_(3) ceramics:While fatigue endurance results revealed a slight drop in polarization after 3 × 10^(5) switching cycles,the results of aging of the dielectric constant revealed no notable decrease in its values after 10^(6)s.展开更多
基金This project was financially supported by Slovenian Research Agency under programs P1-0125 and P2-0105 and projects PR-02908,J2-1227,and PR-03099by Ministry of Education,Science and Sport of Republic of Slovenia under Project PR-05648.
文摘K_(0.5)Na_(0.5)NbO_(3)-SrTiO_(3)(KNN-STO)thin films of different compositions were prepared by the chemical solution deposition method.While structural investigations confirmed the formation of perovskite solid solution in all developed films,dieletric experiments revealed a relaxor broad dispersive maximum in the sample with 15 mol%of STO,exhibiting for a thin film high ε′~330 at~210K.The history-dependent effects of this relaxor sample were compared to those of KNN STO ceramics and,furthermore,shown to be much weaker than in widely used lead-based ferroelectric and relaxor(Pb,L a)(Zr,Ti)O_(3) ceramics:While fatigue endurance results revealed a slight drop in polarization after 3 × 10^(5) switching cycles,the results of aging of the dielectric constant revealed no notable decrease in its values after 10^(6)s.
